Copyright (c) 2018 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Adsorption of Basic and Acid Dyes Using Alginate/Sericin Composite Beads
Corresponding Author(s) : Walaikorn Nitayaphat
Asian Journal of Chemistry,
Vol. 30 No. 4 (2018): Vol 30 Issue 4
Abstract
Alginate/sericin composite beads were prepared from a blend between sericin and alginate by the gelation process. The composite beads were used as the adsorbent for the removal of basic and acid dyes from an aqueous solution. The morphological structure of the beads was characterized by scanning electron microscopy (SEM). Adsorption experiments were conducted using contact time, concentration of sericin, pH and adsorbent dosage. The equilibrium adsorption data was achieved within 360 min at 5 % w/v of sericin. The Langmuir isotherm model showed the maximum monolayer adsorption capacity for basic dye (pH 8) and acid dye (pH 2) was 5.98 and 7.60 mg/g, respectively. The adsorption kinetics were described by the pseudo second-order model. The desorption experiment was demonstrated and repeated three times, all of which exhibited that it was regenerative and reusable. This study demonstrates that the alginate/sericin composite beads are effective adsorbent for the removal of dyes from aqueous solution.
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- A.A. Spagnoli, D.A. Giannakoudakis and S. Bashkova, J. Mol. Liq., 229, 465 (2017); https://doi.org/10.1016/j.molliq.2016.12.106.
- Q. Li, Y. Li, X. Ma, Q. Du, K. Sui, D. Wang, C. Wang, H. Li and Y. Xia, Chem. Eng. J., 316, 623 (2017); https://doi.org/10.1016/j.cej.2017.01.098.
- A. Hassani, A. Khataee, S. Karaca, M. Karaca and M. Kiransan, J. Environ. Chem. Eng., 3, 2738 (2015); https://doi.org/10.1016/j.jece.2015.09.014.
- N. Nikooe and E. Saljoughi, Appl. Surf. Sci., 413, 41 (2017); https://doi.org/10.1016/j.apsusc.2017.04.029.
- S.S. Moghaddam, M.R.A. Moghaddam and M. Arami, J. Hazard. Mater., 175, 651 (2010); https://doi.org/10.1016/j.jhazmat.2009.10.058.
- M.P. Kumar, G.A.S. Josephine and A. Sivasamy, J. Mol. Liq., 242, 789 (2017); https://doi.org/10.1016/j.molliq.2017.07.082.
- S.R. Vijayalakshmidevi and K. Muthukumar, Ecotoxicol. Environ. Saf., 114, 23 (2015); https://doi.org/10.1016/j.ecoenv.2014.09.039.
- F. Jiang, D.M. Dinh and Y.L. Hsieh, Carbohydr. Polym., 173, 286 (2017); https://doi.org/10.1016/j.carbpol.2017.05.097.
- J. Labanda, J. Sabate and J. Llorens, J. Membr. Sci., 340, 234 (2009); https://doi.org/10.1016/j.memsci.2009.05.036.
- V.K. Gupta and Suhas, J. Environ. Manage., 90, 2313 (2009); https://doi.org/10.1016/j.jenvman.2008.11.017.
- I.A. Aguayo-Villarreal, V. Hernández-Montoya, E.M. Ramírez-López, A. Bonilla-Petriciolet and M.A. Montes-Morán, Ecol. Eng., 95, 112 (2016); https://doi.org/10.1016/j.ecoleng.2016.06.056.
- Y. Guo and E. Du, Energy Procedia, 17, 444 (2012); https://doi.org/10.1016/j.egypro.2012.02.118.
- E.A. Moawed, M.A. El-Hagrasy and A.A.M. Farhat, J. Clean. Prod., 157, 232 (2017); https://doi.org/10.1016/j.jclepro.2017.04.145.
- W. Nitayaphat, Mater. Today, 4, 6274 (2017); https://doi.org/10.1016/j.matpr.2017.06.127.
- W. Nitayaphat and T. Jintakosol, J. Clean. Prod., 87, 850 (2015); https://doi.org/10.1016/j.jclepro.2014.10.003.
- F. Wang, T.T. Cao and Y.Q. Zhang, Mater. Sci. Eng. C, 55, 131 (2015); https://doi.org/10.1016/j.msec.2015.05.041.
- D. Gupta, A. Agrawal, H. Chaudhary, M. Gulrajani and C. Gupta, J. Clean. Prod., 52, 488 (2013); https://doi.org/10.1016/j.jclepro.2013.03.016.
- T.T. Cao and Y.Q. Zhang, Mater. Sci. Eng. C, 61, 940 (2016); https://doi.org/10.1016/j.msec.2015.12.082.
- B.H. Hameed, J. Hazard. Mater., 162, 344 (2009); https://doi.org/10.1016/j.jhazmat.2008.05.045.
- R. Zhao, Y. Wang, X. Li, B. Sun, Z. Jiang and C. Wang, Colloids Surf. B, 136, 375 (2015); https://doi.org/10.1016/j.colsurfb.2015.09.038.
- X.-M. Zheng, J.-F. Dou, M. Xia and A.-Z. Ding, Carbohydr. Polym., 167, 306 (2017); https://doi.org/10.1016/j.carbpol.2017.03.059.
- H-J. Hong, B-G. Kim, J. Hong, J. Ryu, T. Ryu, K-S. Chung, H. Kim and I-S. Park, Chem. Eng. J., 319, 163 (2017); https://doi.org/10.1016/j.cej.2017.02.132.
- T.L. da Silva, A.C.D. Silva Jr., M.G.A. Vieira, M.L. Gimenes and M.G.C. da Silva, J. Clean. Prod., 137, 1470 (2016); https://doi.org/10.1016/j.jclepro.2015.05.067.
- S.N. Pawar and K.J. Edgar, Biomater., 33, 3279 (2012); https://doi.org/10.1016/j.biomaterials.2012.01.007.
- W. Nitayaphat and T. Jintakosol, Asian J. Chem., 29, 683 (2017); https://doi.org/10.14233/ajchem.2017.20313.
- G.B. Oguntimein, J. Environ. Chem. Eng., 3, 2647 (2015); https://doi.org/10.1016/j.jece.2015.09.028.
- I. Langmuir, J. Am. Chem. Soc., 40, 1361 (1918); https://doi.org/10.1021/ja02242a004.
- H.M.F. Freundlich, Z. Phys. Chem., 57U, 385 (1907); https://doi.org/10.1515/zpch-1907-5723.
- W. Nitayaphat, T. Jintakosol, K. Engkaseth and Y. Wanrakakit, Chiang Mai. J. Sci., 42, 407 (2015).
- R.L. Tseng, F.C. Wu and R.-S. Juang, Carbon, 41, 487 (2003); https://doi.org/10.1016/S0008-6223(02)00367-6.
- C. Namasivayam, N. Kanchana and R.T. Yamuna, Waste Manag., 13, 89 (1993); https://doi.org/10.1016/0956-053X(93)90038-X.
- G. Annadurai, R.S. Juang and D.-J. Lee, J. Hazard. Mater., 92, 263 (2002); https://doi.org/10.1016/S0304-3894(02)00017-1.
- M.A. Abdel-Khalek, M.K. Abdel Rahman and A.A. Francis, J. Environ. Chem. Eng., 5, 319 (2017); https://doi.org/10.1016/j.jece.2016.11.043.
- C. Namasivayam, M.D. Kumar, K. Selvi, R.A. Begum, T. Vanathi and R.T. Yamuna, Biomass Bioenergy, 21, 477 (2001); https://doi.org/10.1016/S0961-9534(01)00052-6.
- C. Namasivayam, D. Prabha and M. Kumutha, Bioresour. Technol., 64, 77 (1998); https://doi.org/10.1016/S0960-8524(97)86722-3.
- R. Gong, Y. Ding, M. Li, C. Yang, H. Liu and Y. Sun, Dyes Pigments, 64, 187 (2005); https://doi.org/10.1016/j.dyepig.2004.05.005.
- R. Sivaraj, C. Namasivayam and K. Kadirvelu, Waste Manag., 21, 105 (2001); https://doi.org/10.1016/S0956-053X(00)00076-3.
- M.C. Somasekhara Reddy, V. Nirmala and C. Ashwini, Arab. J. Chem., 10, 2554 (2017); https://doi.org/10.1016/j.arabjc.2013.09.029.
- M. Zanetti, S. Lomakin and G. Camino, Macromol. Mater. Eng., 279, 1 (2000); https://doi.org/10.1002/1439-2054(20000601)279:1<1::AIDMAME1>3.0.CO;2-Q.
- H. Huo, H. Su and T. Tan, Chem. Eng. J., 150, 139 (2009); https://doi.org/10.1016/j.cej.2008.12.014.
References
A.A. Spagnoli, D.A. Giannakoudakis and S. Bashkova, J. Mol. Liq., 229, 465 (2017); https://doi.org/10.1016/j.molliq.2016.12.106.
Q. Li, Y. Li, X. Ma, Q. Du, K. Sui, D. Wang, C. Wang, H. Li and Y. Xia, Chem. Eng. J., 316, 623 (2017); https://doi.org/10.1016/j.cej.2017.01.098.
A. Hassani, A. Khataee, S. Karaca, M. Karaca and M. Kiransan, J. Environ. Chem. Eng., 3, 2738 (2015); https://doi.org/10.1016/j.jece.2015.09.014.
N. Nikooe and E. Saljoughi, Appl. Surf. Sci., 413, 41 (2017); https://doi.org/10.1016/j.apsusc.2017.04.029.
S.S. Moghaddam, M.R.A. Moghaddam and M. Arami, J. Hazard. Mater., 175, 651 (2010); https://doi.org/10.1016/j.jhazmat.2009.10.058.
M.P. Kumar, G.A.S. Josephine and A. Sivasamy, J. Mol. Liq., 242, 789 (2017); https://doi.org/10.1016/j.molliq.2017.07.082.
S.R. Vijayalakshmidevi and K. Muthukumar, Ecotoxicol. Environ. Saf., 114, 23 (2015); https://doi.org/10.1016/j.ecoenv.2014.09.039.
F. Jiang, D.M. Dinh and Y.L. Hsieh, Carbohydr. Polym., 173, 286 (2017); https://doi.org/10.1016/j.carbpol.2017.05.097.
J. Labanda, J. Sabate and J. Llorens, J. Membr. Sci., 340, 234 (2009); https://doi.org/10.1016/j.memsci.2009.05.036.
V.K. Gupta and Suhas, J. Environ. Manage., 90, 2313 (2009); https://doi.org/10.1016/j.jenvman.2008.11.017.
I.A. Aguayo-Villarreal, V. Hernández-Montoya, E.M. Ramírez-López, A. Bonilla-Petriciolet and M.A. Montes-Morán, Ecol. Eng., 95, 112 (2016); https://doi.org/10.1016/j.ecoleng.2016.06.056.
Y. Guo and E. Du, Energy Procedia, 17, 444 (2012); https://doi.org/10.1016/j.egypro.2012.02.118.
E.A. Moawed, M.A. El-Hagrasy and A.A.M. Farhat, J. Clean. Prod., 157, 232 (2017); https://doi.org/10.1016/j.jclepro.2017.04.145.
W. Nitayaphat, Mater. Today, 4, 6274 (2017); https://doi.org/10.1016/j.matpr.2017.06.127.
W. Nitayaphat and T. Jintakosol, J. Clean. Prod., 87, 850 (2015); https://doi.org/10.1016/j.jclepro.2014.10.003.
F. Wang, T.T. Cao and Y.Q. Zhang, Mater. Sci. Eng. C, 55, 131 (2015); https://doi.org/10.1016/j.msec.2015.05.041.
D. Gupta, A. Agrawal, H. Chaudhary, M. Gulrajani and C. Gupta, J. Clean. Prod., 52, 488 (2013); https://doi.org/10.1016/j.jclepro.2013.03.016.
T.T. Cao and Y.Q. Zhang, Mater. Sci. Eng. C, 61, 940 (2016); https://doi.org/10.1016/j.msec.2015.12.082.
B.H. Hameed, J. Hazard. Mater., 162, 344 (2009); https://doi.org/10.1016/j.jhazmat.2008.05.045.
R. Zhao, Y. Wang, X. Li, B. Sun, Z. Jiang and C. Wang, Colloids Surf. B, 136, 375 (2015); https://doi.org/10.1016/j.colsurfb.2015.09.038.
X.-M. Zheng, J.-F. Dou, M. Xia and A.-Z. Ding, Carbohydr. Polym., 167, 306 (2017); https://doi.org/10.1016/j.carbpol.2017.03.059.
H-J. Hong, B-G. Kim, J. Hong, J. Ryu, T. Ryu, K-S. Chung, H. Kim and I-S. Park, Chem. Eng. J., 319, 163 (2017); https://doi.org/10.1016/j.cej.2017.02.132.
T.L. da Silva, A.C.D. Silva Jr., M.G.A. Vieira, M.L. Gimenes and M.G.C. da Silva, J. Clean. Prod., 137, 1470 (2016); https://doi.org/10.1016/j.jclepro.2015.05.067.
S.N. Pawar and K.J. Edgar, Biomater., 33, 3279 (2012); https://doi.org/10.1016/j.biomaterials.2012.01.007.
W. Nitayaphat and T. Jintakosol, Asian J. Chem., 29, 683 (2017); https://doi.org/10.14233/ajchem.2017.20313.
G.B. Oguntimein, J. Environ. Chem. Eng., 3, 2647 (2015); https://doi.org/10.1016/j.jece.2015.09.028.
I. Langmuir, J. Am. Chem. Soc., 40, 1361 (1918); https://doi.org/10.1021/ja02242a004.
H.M.F. Freundlich, Z. Phys. Chem., 57U, 385 (1907); https://doi.org/10.1515/zpch-1907-5723.
W. Nitayaphat, T. Jintakosol, K. Engkaseth and Y. Wanrakakit, Chiang Mai. J. Sci., 42, 407 (2015).
R.L. Tseng, F.C. Wu and R.-S. Juang, Carbon, 41, 487 (2003); https://doi.org/10.1016/S0008-6223(02)00367-6.
C. Namasivayam, N. Kanchana and R.T. Yamuna, Waste Manag., 13, 89 (1993); https://doi.org/10.1016/0956-053X(93)90038-X.
G. Annadurai, R.S. Juang and D.-J. Lee, J. Hazard. Mater., 92, 263 (2002); https://doi.org/10.1016/S0304-3894(02)00017-1.
M.A. Abdel-Khalek, M.K. Abdel Rahman and A.A. Francis, J. Environ. Chem. Eng., 5, 319 (2017); https://doi.org/10.1016/j.jece.2016.11.043.
C. Namasivayam, M.D. Kumar, K. Selvi, R.A. Begum, T. Vanathi and R.T. Yamuna, Biomass Bioenergy, 21, 477 (2001); https://doi.org/10.1016/S0961-9534(01)00052-6.
C. Namasivayam, D. Prabha and M. Kumutha, Bioresour. Technol., 64, 77 (1998); https://doi.org/10.1016/S0960-8524(97)86722-3.
R. Gong, Y. Ding, M. Li, C. Yang, H. Liu and Y. Sun, Dyes Pigments, 64, 187 (2005); https://doi.org/10.1016/j.dyepig.2004.05.005.
R. Sivaraj, C. Namasivayam and K. Kadirvelu, Waste Manag., 21, 105 (2001); https://doi.org/10.1016/S0956-053X(00)00076-3.
M.C. Somasekhara Reddy, V. Nirmala and C. Ashwini, Arab. J. Chem., 10, 2554 (2017); https://doi.org/10.1016/j.arabjc.2013.09.029.
M. Zanetti, S. Lomakin and G. Camino, Macromol. Mater. Eng., 279, 1 (2000); https://doi.org/10.1002/1439-2054(20000601)279:1<1::AIDMAME1>3.0.CO;2-Q.
H. Huo, H. Su and T. Tan, Chem. Eng. J., 150, 139 (2009); https://doi.org/10.1016/j.cej.2008.12.014.