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This work is licensed under a Creative Commons Attribution 4.0 International License.
Comparative Studies of Fluoride Removal from Groundwater by Calcium Carbonate, Activated Alumina and Activated Punica granatum Ash
Corresponding Author(s) : Sudhanshu Kanaujia
Asian Journal of Chemistry,
Vol. 30 No. 4 (2018): Vol 30 Issue 4
Abstract
This study investigates the comparative feasibility of three low-cost adsorbents namely calcium carbonate, activated alumina and activated Punica granatum ash (APGA) for the removal of fluoride ions by adsorption from groundwater of Raebareli district of India. The effect of various process parameters like pH, contact time, adsorbent dose, etc. have been investigated by batch adsorption technique. Experimental results revealed that fluoride adsorption increases with increasing adsorbent dose. Fluoride adsorption increased with increasing contact time and reached equilibrium at 100 min for all the three adsorbents. The maximum fluoride adsorptions occurred at 4.7, 1.03 and 3.34 mg/g of calcium carbonate, activated alumina and activated Punica granatum ash, respectively. All the adsorption experimental data of calcium carbonate, activated alumina and activated Punica granatum ash were fitted well with the Langmuir isotherm and followed pseudo-second-order kinetics.
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WHO Guidelines for Drinking-Water Quality: Incorporating First Addendum, Recommendations, World Health Organization, vol. 3 (2006).
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P. Madhunare, D.Y. Sirsikarm, A.N. Tiwari, B. Ranjan and D.B. Maple, Curr. Sci., 92, 675 (2007).
A. Tor, J. Hazard. Mater., 141, 814 (2007); https://doi.org/10.1016/j.jhazmat.2006.07.043.
N.I. Chubar, V.F. Samanidou, V.S. Kouts, V.A. Kanibolotsky, G.G. Gallios, V.V. Strelko and I.Z. Zhuravlev, J. Colloid Interface Sci., 291, 67 (2005); https://doi.org/10.1016/j.jcis.2005.04.086.
S.V. Joshi, S.H. Mehta, A.P. Rao and A.V. Rao, Water Treat., 10, 307 (1992).
E. Ergun, A. Tor, Y. Cengeloglu and I. Kocak, Sep. Purif. Technol., 64, 147 (2008); https://doi.org/10.1016/j.seppur.2008.09.009.
A. Tor, N. Danaoglu, G. Arslan and Y. Cengeloglu, J. Hazard. Mater., 164, 271 (2009); https://doi.org/10.1016/j.jhazmat.2008.08.011.
S. Ghorai and K.K. Pant, Sep. Purif. Technol., 42, 265 (2005); https://doi.org/10.1016/j.seppur.2004.09.001.
E. Tchomgui-Kamga, V. Alonzo, C.P. Nanseu-Njiki, N. Audebrand, E. Ngameni and A. Darchen, Carbon, 48, 333 (2010); https://doi.org/10.1016/j.carbon.2009.09.034.
M.G. Sujana, R.S. Thakur and S.B. Rao, J. Colloid Interface Sci., 275, 355 (1998).
M. Yang, M. Hashimoto, N. Hoshi and H. Myoga, Water Res., 33, 3395 (1999); https://doi.org/10.1016/S0043-1354(99)00052-4.
N. Viswanathan and S. Meenakshi, J. Colloid Interface Sci., 322, 375 (2008); https://doi.org/10.1016/j.jcis.2008.03.007.
M.S. Onyango, Y. Kojima, O. Aoyi, E.C. Bernardo and H. Matsuda, J. Colloid Interface Sci., 279, 341 (2004); https://doi.org/10.1016/j.jcis.2004.06.038.
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M. Mahramanlioglu, I. Kizilcikli and I.O. Bicer, J. Fluor. Chem., 115, 41 (2002); https://doi.org/10.1016/S0022-1139(02)00003-9.
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J.S. Mattson and H.B. Mark Jr., Activated Carbon: Surface Chemistry and Adsorption from Solution, Marcel Dekker, New York (1971).
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N.K. Mondal, R. Bhaumik and J.K. Datta, Environ. Process., 3, 195 (2016); https://doi.org/10.1007/s40710-016-0130-x.
I. Hespanhol and A.M.E. Prost, Water Res., 28, 119 (1994); https://doi.org/10.1016/0043-1354(94)90125-2.
A.K. Susheela, Curr. Sci., 77, 1250 (1999).
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A.K. Tiwari and A.K. Singh, J. Geol. Soc. India, 83, 329 (2014); https://doi.org/10.1007/s12594-014-0045-y.
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J.H. Guglielmacci and B. Ealet, Mater. Sci. Eng. B, 40, 96 (1996); https://doi.org/10.1016/0921-5107(96)01609-1.
S. Kanaujia, B. Singh and S.K. Singh, J. Geosci. Environ. Prot., 3, 1 (2015); https://doi.org/10.4236/gep.2015.34001.
S. Sinha, K.P. Pandey, D. Mohan and K.P. Singh, Ind. Eng. Chem. Res., 42, 6911 (2003); https://doi.org/10.1021/ie030544k.
V. Ganvir and K. Das, J. Hazard. Mater., 185, 1287 (2011); https://doi.org/10.1016/j.jhazmat.2010.10.044.
A.A.M. Daifullah, S.M. Yakout and S.A. Elreefy, J. Hazard. Mater., 147, 633 (2007); https://doi.org/10.1016/j.jhazmat.2007.01.062.
N.K. Mondal, K.C. Pal and S. Kabi, Environmentalist, 32, 70 (2012); https://doi.org/10.1007/s10669-011-9374-1.
N.K. Mondal, R. Bhaumik, P. Roy, B. Das and J.K. Datta, J. Environ. Biol., 34, 1059 (2013).