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This work is licensed under a Creative Commons Attribution 4.0 International License.
Ultrasonication Assisted Development of New Greener Method for Extraction of Cypermethrin and Transfluthrin from Various Samples: A Forensic Approach
Corresponding Author(s) : D.S. Bhagat
Asian Journal of Chemistry,
Vol. 30 No. 4 (2018): Vol 30 Issue 4
Abstract
In present work, we developed an extraction method of two pyrethroids viz., cypermethrin and transfluthrin from soil, cloth pieces and household insecticides by using ultrasonicator. Extractions were done in xylene and ethanol solvents. Confirmation of pyrethroids was performed using thin layer chromatography (TLC), UV-visible, FT-IR spectroscopy and LC-MS.
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- U.S. Department of Health and Human Services, Toxicological Profile for Pyrethrins and Pyrethroids.Updated 9/2003. http://www.atsdr.cdc.gov/toxprofiles/tp155.pdf.
- S.M. Bradberry, S.A. Cage, A.T. Proudfoot and J.A. Vale, Toxicol. Rev., 24, 93 (2005); https://doi.org/10.2165/00139709-200524020-00003.
- F. Cantalamessa, Arch. Toxicol., 67, 510 (1993); https://doi.org/10.1007/BF01969923.
- T. Narahashi, Bull. World Health Organ., 44, 337 (1971).
- D. Mueller-Beilschmidt, J. Pestic. Reform, 10, 32 (1990).
- T. Narahashi, K.S. Ginsburg, K. Nagata, J.H. Song and H. Tatebayashi, Neurotoxicology, 19, 581 (1998).
- W.N. Aldridge, Toxicology, 21, 89 (1990);
- D.N. Bateman, J. Toxicol. Clin. Toxicol., 38, 107 (2000); https://doi.org/10.1081/CLT-100100924.
- A. Anadón, M.R. Martinez-Larrañaga, M.J. Diaz and P. Bringas, Toxicol. Appl. Pharmacol., 110, 1 (1991); https://doi.org/10.1016/0041-008X(91)90284-L.
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- M.J. Crawford, A. Croucher and D.H. Hutson, Pestic. Sci., 12, 399 (1981); https://doi.org/10.1002/ps.2780120406.
- D.B. Barr, A.O. Olsson, L.-Y. Wong, S. Udunka, S.E. Baker, R.D. Whitehead Jr., M.S. Magsumbol, B.L. Williams and L.L. Needham, Environ. Health Perspect, 118, 742 (2010); https://doi.org/10.1289/ehp.0901275.
- B. Kolmodin-Hedman, Swensson and M. Kerblom, Arch. Toxicol., 50, 27 (1982); https://doi.org/10.1007/BF00569234.
- F. He, S. Wang, L. Liu, S. Chen, Z. Zhang and J. Sun, Arch. Toxicol., 63, 54 (1989); https://doi.org/10.1007/BF00334635.
- P.Y. Yang, J.L. Lin, A.H. Hall, T.C. Tsao and M.S. Chern, J. Toxicol. Clin. Toxicol., 40, 107 (2002); https://doi.org/10.1081/CLT-120004397.
- A.A. Ramadan, N.M. Bakry, A.S.M. Marei, A.T. Eldefrawi and M.E. Eldefrawi, Pestic. Biochem. Physiol., 32, 97 (1988); https://doi.org/10.1016/0048-3575(88)90002-8.
- A. Sapiets, H. Swaine and M.J. Tandy, eds.: G. Zweig and J. Sherma, Cypermethrin, In: Synthetic Pyrethroids and Other Pesticides, Academic Press. vol. 13, 33 (1984).
- L. Poulos, S. Athanaselis and A. Coutselinis, J. Toxicol. Clin. Toxicol., 19, 519 (1982); https://doi.org/10.3109/15563658208992509.
- C. Nasuti, R. Gabbianelli, M.L. Falcioni, A. Di Stefano, P. Sozio and F. Cantalamessa, Toxicology, 229, 194 (2007); https://doi.org/10.1016/j.tox.2006.10.015.
- A.K. Singh, M.N. Tiwari, O. Prakash and M.P. Singh, Curr. Neuropharmacol., 10, 64 (2012); https://doi.org/10.2174/157015912799362779.
- Y. Shukla, A. Yadav and A. Arora, Cancer Lett., 182, 33 (2002); https://doi.org/10.1016/S0304-3835(02)00077-0.
- U. Undeger and N. Basaran, Arch. Toxicol., 79, 169 (2005); https://doi.org/10.1007/s00204-004-0616-6.
- L. Ahmad, A. Khan, M.Z. Khan, I. Hussain, F. Mahmood, M.K. Sleemi, L.A. Lodhi and I. Abdullah, Pestic. Biochem. Physiol., 103, 194 (2012); https://doi.org/10.1016/j.pestbp.2012.05.004.
- A. Elbetieha, S.I. Daas, W. Khamas and H. Darmani, Arch. Environ. Contam. Toxicol., 41, 522 (2001); https://doi.org/10.1007/s002440010280.
- J. Pauluhn and K. Ozaki, Regul. Toxicol. Pharmacol., 71, 78 (2015); https://doi.org/10.1016/j.yrtph.2014.11.003.
- S. Babic, M. Petrovic and M. Kastelan-Macan, J. Chromatogr. A, 823, 3 (1998); https://doi.org/10.1016/S0021-9673(98)00301-X.
- A.M. Nguyen, P.J. Marriott and J. Hughes, J. Biochem. Biophys. Methods, 43, 411 (2000); https://doi.org/10.1016/S0165-022X(00)00054-3.
- S.P. Merchant, R.S. Bhise and S.S. Carpenter, J. Indian Soc. Toxicol., 7, 1 (2011).
- S. Vaishya, R.S. Chandel and R. Singh, J. Indian Soc. Toxicol., 6, 11 (2010).
- N. Shahzadi, M. Imran, M. Sarwar, A.S. Hashmi and M. Wasim, J. Agroaliment. Proc. Technol., 19, 167 (2013).
- I. Rezic, A.J.M. Horvat, S. Babic and M. Kastelan-Macan, Ultrason. Sonochem., 12, 477 (2005); https://doi.org/10.1016/j.ultsonch.2004.07.004.
- Z. Sharif, Y.B.C. Man, N.S.A. Hamid and C.C. Keat, J. Chromatogr. A, 1127, 254 (2006); https://doi.org/10.1016/j.chroma.2006.06.007.
- M.L. Feo, E. Eljarrat and D. Barceló, J. Chromatogr. A, 1217, 2248 (2010); https://doi.org/10.1016/j.chroma.2010.02.018.
- G. Suresh, T.V. Rao and A. Ramesh, J. Pharmacy Chem., 9, 19 (2015).
- R. Yadav, A Toxo-Analytical Study of Some Synthetic Pyrethroids, Chap. 2, pp. 31-51 (2002).
References
U.S. Department of Health and Human Services, Toxicological Profile for Pyrethrins and Pyrethroids.Updated 9/2003. http://www.atsdr.cdc.gov/toxprofiles/tp155.pdf.
S.M. Bradberry, S.A. Cage, A.T. Proudfoot and J.A. Vale, Toxicol. Rev., 24, 93 (2005); https://doi.org/10.2165/00139709-200524020-00003.
F. Cantalamessa, Arch. Toxicol., 67, 510 (1993); https://doi.org/10.1007/BF01969923.
T. Narahashi, Bull. World Health Organ., 44, 337 (1971).
D. Mueller-Beilschmidt, J. Pestic. Reform, 10, 32 (1990).
T. Narahashi, K.S. Ginsburg, K. Nagata, J.H. Song and H. Tatebayashi, Neurotoxicology, 19, 581 (1998).
W.N. Aldridge, Toxicology, 21, 89 (1990);
D.N. Bateman, J. Toxicol. Clin. Toxicol., 38, 107 (2000); https://doi.org/10.1081/CLT-100100924.
A. Anadón, M.R. Martinez-Larrañaga, M.J. Diaz and P. Bringas, Toxicol. Appl. Pharmacol., 110, 1 (1991); https://doi.org/10.1016/0041-008X(91)90284-L.
D.M. Soderlund, J.M. Clark, L.P. Sheets, L.S. Mullin, V.J. Piccirillo, D. Sargent, J.T. Stevens and M.L. Weiner, Toxicology, 171, 3 (2002); https://doi.org/10.1016/S0300-483X(01)00569-8.
M.J. Crawford, A. Croucher and D.H. Hutson, Pestic. Sci., 12, 399 (1981); https://doi.org/10.1002/ps.2780120406.
D.B. Barr, A.O. Olsson, L.-Y. Wong, S. Udunka, S.E. Baker, R.D. Whitehead Jr., M.S. Magsumbol, B.L. Williams and L.L. Needham, Environ. Health Perspect, 118, 742 (2010); https://doi.org/10.1289/ehp.0901275.
B. Kolmodin-Hedman, Swensson and M. Kerblom, Arch. Toxicol., 50, 27 (1982); https://doi.org/10.1007/BF00569234.
F. He, S. Wang, L. Liu, S. Chen, Z. Zhang and J. Sun, Arch. Toxicol., 63, 54 (1989); https://doi.org/10.1007/BF00334635.
P.Y. Yang, J.L. Lin, A.H. Hall, T.C. Tsao and M.S. Chern, J. Toxicol. Clin. Toxicol., 40, 107 (2002); https://doi.org/10.1081/CLT-120004397.
A.A. Ramadan, N.M. Bakry, A.S.M. Marei, A.T. Eldefrawi and M.E. Eldefrawi, Pestic. Biochem. Physiol., 32, 97 (1988); https://doi.org/10.1016/0048-3575(88)90002-8.
A. Sapiets, H. Swaine and M.J. Tandy, eds.: G. Zweig and J. Sherma, Cypermethrin, In: Synthetic Pyrethroids and Other Pesticides, Academic Press. vol. 13, 33 (1984).
L. Poulos, S. Athanaselis and A. Coutselinis, J. Toxicol. Clin. Toxicol., 19, 519 (1982); https://doi.org/10.3109/15563658208992509.
C. Nasuti, R. Gabbianelli, M.L. Falcioni, A. Di Stefano, P. Sozio and F. Cantalamessa, Toxicology, 229, 194 (2007); https://doi.org/10.1016/j.tox.2006.10.015.
A.K. Singh, M.N. Tiwari, O. Prakash and M.P. Singh, Curr. Neuropharmacol., 10, 64 (2012); https://doi.org/10.2174/157015912799362779.
Y. Shukla, A. Yadav and A. Arora, Cancer Lett., 182, 33 (2002); https://doi.org/10.1016/S0304-3835(02)00077-0.
U. Undeger and N. Basaran, Arch. Toxicol., 79, 169 (2005); https://doi.org/10.1007/s00204-004-0616-6.
L. Ahmad, A. Khan, M.Z. Khan, I. Hussain, F. Mahmood, M.K. Sleemi, L.A. Lodhi and I. Abdullah, Pestic. Biochem. Physiol., 103, 194 (2012); https://doi.org/10.1016/j.pestbp.2012.05.004.
A. Elbetieha, S.I. Daas, W. Khamas and H. Darmani, Arch. Environ. Contam. Toxicol., 41, 522 (2001); https://doi.org/10.1007/s002440010280.
J. Pauluhn and K. Ozaki, Regul. Toxicol. Pharmacol., 71, 78 (2015); https://doi.org/10.1016/j.yrtph.2014.11.003.
S. Babic, M. Petrovic and M. Kastelan-Macan, J. Chromatogr. A, 823, 3 (1998); https://doi.org/10.1016/S0021-9673(98)00301-X.
A.M. Nguyen, P.J. Marriott and J. Hughes, J. Biochem. Biophys. Methods, 43, 411 (2000); https://doi.org/10.1016/S0165-022X(00)00054-3.
S.P. Merchant, R.S. Bhise and S.S. Carpenter, J. Indian Soc. Toxicol., 7, 1 (2011).
S. Vaishya, R.S. Chandel and R. Singh, J. Indian Soc. Toxicol., 6, 11 (2010).
N. Shahzadi, M. Imran, M. Sarwar, A.S. Hashmi and M. Wasim, J. Agroaliment. Proc. Technol., 19, 167 (2013).
I. Rezic, A.J.M. Horvat, S. Babic and M. Kastelan-Macan, Ultrason. Sonochem., 12, 477 (2005); https://doi.org/10.1016/j.ultsonch.2004.07.004.
Z. Sharif, Y.B.C. Man, N.S.A. Hamid and C.C. Keat, J. Chromatogr. A, 1127, 254 (2006); https://doi.org/10.1016/j.chroma.2006.06.007.
M.L. Feo, E. Eljarrat and D. Barceló, J. Chromatogr. A, 1217, 2248 (2010); https://doi.org/10.1016/j.chroma.2010.02.018.
G. Suresh, T.V. Rao and A. Ramesh, J. Pharmacy Chem., 9, 19 (2015).
R. Yadav, A Toxo-Analytical Study of Some Synthetic Pyrethroids, Chap. 2, pp. 31-51 (2002).