SnCl2·2H2O and Ni(OAc)2·4H2O: Efficient Heterogeneous Inorganic Catalysts for the Chemoselective Synthesis of Geminal Diacetates (Acylal) Under Solvent-Free Conditions
Corresponding Author(s) : Ardeshir Khazaei
khazaei_1326@yahoo.com
Asian Journal of Chemistry,
Vol. 23 No. 2 (2011): Vol 23 Issue 2
Abstract
SnCl2·2H2O and Ni(OAc)2·4H2O were found to be efficient catalysts for preparation of 1,1- diacetates under solvent-free conditions at room temperature. Easy work-up and low cost are important features from the environmental and economical points of view, are distinct aspects of this research. Very good to exellent yields, short reaction times, non-toxicity and stability of the catalysts are noteworthy advantages of this method.
Keywords
Chemoselective
Efficient
Inorganic catalysts
Solvent-free
1,1-Diacetates
Khazaei, A., Amini Manesh, A., Ali Alavi-Nik, H., & Toodeh Roosta, Z. (2010). SnCl2·2H2O and Ni(OAc)2·4H2O: Efficient Heterogeneous Inorganic Catalysts for the Chemoselective Synthesis of Geminal Diacetates (Acylal) Under Solvent-Free Conditions. Asian Journal of Chemistry, 23(2), 627–630. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/15861
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