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Vol. 33 No. 2 (2021): Vol 33 Issue 2

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Synthesis, Characterization and Antimicrobial Properties of [Cu2(μ-O2CC9H19)4(4-CNpy)2]

https://doi.org/10.14233/ajchem.2021.23048
Nirupamjit Sarmah
Department of Chemistry, Gauhati University, Guwahati-781014, India
Sukanya Baruah
Department of Chemistry, Gauhati University, Guwahati-781014, India
Anup Malakar
Department of Chemistry, Gauhati University, Guwahati-781014, India; Department of Chemistry, Assam Engineering College, Guwahati-781013, India ; Permanent affiliation: Department of Chemistry, Royal Global University, Betkuchi, Guwahati-781035, India
Monideepa Chakrabortty
Department of Chemistry, Assam Engineering College, Guwahati-781013, India
Bhabatosh Banik
Department of Chemistry, Gauhati University, Guwahati-781014, India
Birinchi K. Das
Department of Chemistry, Gauhati University, Guwahati-781014, India ; Present affiliation: Department of Chemistry, Bhattadev University, Bajali, Pathsala-781325, India

Corresponding Author(s) : Bhabatosh Banik

bhabatosh.iisc@gmail.com

Asian Journal of Chemistry, Vol. 33 No. 2 (2021): Vol 33 Issue 2

Abstract

Reports on the isolation and crystallographic characterization of metal carboxylates having long alkyl chains are relatively rare. Herein, a dinuclear copper(II) tetracaprate (i.e. tetradecanoate) complex, [Cu2(μ-O2CC9H19)4(4-CNpy)2] (I), where 4-CNpy = 4-cyanopyridine is reported. The complex has been synthesized by a facile method and characterized by various physico-chemical techniques such as IR and UV-vis spectroscopy, magnetic susceptibility measurement and single crystal X-ray diffraction. The structure is dimeric with the familiar paddle-wheel geometry, which was originally observed in the structure of copper(II) acetate monohydrate. In the dimeric structure, both copper(II) centres display distorted square pyramidal geometry. The substituted pyridine ligands occupy the apical positions through the pyridyl nitrogen atoms. Complex I has been tested for antimicrobial behaviour against a few bacterial strains. Owing to the redox-active nature of copper, complex I shows considerable promise as an antimicrobial agent.

Keywords

Dicopper(II) tetracaprate 4-Cyanopyridine Antimicrobial activity Rhizobium leguminosarum Staphylococcus aureus
Sarmah, N., Baruah, S., Malakar, A., Chakrabortty, M., Banik, B., & K. Das, B. (2021). Synthesis, Characterization and Antimicrobial Properties of [Cu2(μ-O2CC9H19)4(4-CNpy)2]. Asian Journal of Chemistry, 33(2), 453–458. https://doi.org/10.14233/ajchem.2021.23048
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