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Vol. 32 No. 12 (2020): Vol 32 Issue 12, 2020

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Spectroscopic, Thermal and Antimicrobial Study of Some Transition Metal(II) Complexes of β-Diketones

https://doi.org/10.14233/ajchem.2020.22911
Rekha Rani
University Department of Chemistry, Magadh University, Bodh Gaya-824234, India
Umesh Kumar
University Department of Chemistry, Magadh University, Bodh Gaya-824234, India
Deepak Kumar
University Department of Chemistry, Magadh University, Bodh Gaya-824234, India
Siteshwar Pd. Yadav
Department of Chemistry, R.L. College, Madhawnagar-854205, India
Arjun Kr. Sinha
University Department of Chemistry, Magadh University, Bodh Gaya-824234, India
S. Sharma
University Department of Chemistry, Magadh University, Bodh Gaya-824234, India

Corresponding Author(s) : S. Sharma

sharma.shivadhar@gmail.com

Asian Journal of Chemistry, Vol. 32 No. 12 (2020): Vol 32 Issue 12, 2020

Abstract

A novel heterocyclic based β-diketone has been synthesized by the condensation of pyrazole-1-acetylchloride and sodium acetophenone. The product 1-phenyl-4-(pyrazole-1-yl)butane-1,3-dione has been used for complexation with Mn(II), Fe(II) and Co(II) metal ions. The ligand β-diketone is found to exist in keto-enol tautomeric forms. The comparision of infrared spectra of complexes clearly indicates the coordination of the ligand from its enolic form. The magnetic moment and electronic spectra of all the metal complexes leads to the distorted octahedral symmetry around the metal ion. The ligand as well as its metal complexes has been screened for antimicrobial activity and antifungal activities. It is observed that the antimicrobial and antifungal activities get enhanced in complexes in respect to the free ligand.

Keywords

Pyrazole-1-acetylchloride Sodium acetophenone Transition metal(II) complexes Distorted octahedral β-Diketone
Rani, R., Kumar, U., Kumar, D., Pd. Yadav, S., Kr. Sinha, A., & Sharma, S. (2020). Spectroscopic, Thermal and Antimicrobial Study of Some Transition Metal(II) Complexes of β-Diketones. Asian Journal of Chemistry, 32(12), 3173–3178. https://doi.org/10.14233/ajchem.2020.22911
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