Evaluation of Ultrasonic Velocity Theories on Binary Liquid Mixtures of Propiophenone with Isomeric Xylenes at Temperatures (T = 303.15 to 318.15 K)

Nanduri Gayatri Devi; N.V.N.B. Srinivasa Rao; D. Ramachandran

doi:10.14233/ajchem.2020.22900

Issue

Vol. 32 No. 12 (2020): Vol 32 Issue 12, 2020

Issue Published : December 7, 2020

This work is licensed under a Creative Commons Attribution 4.0 International License.

Evaluation of Ultrasonic Velocity Theories on Binary Liquid Mixtures of Propiophenone with Isomeric Xylenes at Temperatures (T = 303.15 to 318.15 K)

https://doi.org/10.14233/ajchem.2020.22900

Nanduri Gayatri Devi

Department of Chemistry, Ch. S.D. St. Theresa’s College (A) for Women, Eluru-534003, India

N.V.N.B. Srinivasa Rao

Department of Chemistry, D.R. Goenka Government Degree College, Tadepalligudem-534166, India

D. Ramachandran

Department of Chemistry, Acharya Nagarjuna University, Nagarjuna Nagar, Guntur-522510, India

Corresponding Author(s) : D. Ramachandran

dittakavirc@gmail.com

Asian Journal of Chemistry, Vol. 32 No. 12 (2020): Vol 32 Issue 12, 2020
Article Published : December 7, 2020

Abstract

Densities (ρ), ultrasonic speeds of sound (u) of binary mixtures containing propiophenone with o-xylene, m-xylene and p-xylene were measured over the entire composition range at temperatures from 303.15-318.15 K and at atmospheric pressure 0.1 MPa. Experimental data of ultrasonic velocity was used to compute the theoretical velocities by using the various theories like Nomoto’s relation (U_NOM), impedance relation (U_IMP), Van Dael and Vangeel’s relation (U_VDV), Rao’s specific velocity relation (U_RAO), Jouyban-Acree’s (U_JOE) and Junjie’s theory (U_JUN). The results are in good agreement with the experimental data. The relative percentage error, chi square test for goodness of fit and the molecular interaction parameter (α) values for non-ideality in the binary mixtures were computed and analyzed in terms of intermolecular interactions between the molecules of the binary mixtures.

Keywords

Ultrasonic speed of sound Molecular interaction parameter Velocity theories Chi square test Relative percentage error

Gayatri Devi, N., Srinivasa Rao, N., & Ramachandran, D. (2020). Evaluation of Ultrasonic Velocity Theories on Binary Liquid Mixtures of Propiophenone with Isomeric Xylenes at Temperatures (T = 303.15 to 318.15 K). Asian Journal of Chemistry, 32(12), 3087–3092. https://doi.org/10.14233/ajchem.2020.22900

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References

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J.A. Al-Kandary, A.S. Al-Jimaz and A.H.M. Abdul-Latif, J. Chem. Thermodyn., 38, 1351 (2006); https://doi.org/10.1016/j.jct.2006.02.001

S. Singh, B.P.S. Sethi, R.C. Katyal and V.K. Rattan, J. Chem. Eng. Data, 50, 125 (2005); https://doi.org/10.1021/je049793l

G. Moumouzias, C. Ritzoulis and G. Ritzoulis, J. Chem. Eng. Data, 44, 1187 (1999); https://doi.org/10.1021/je990094w

J.A. Al-Kandary, A.S. Al-Jimaz and A.H.M. Abdul-Latif, J. Chem. Eng. Data, 51, 2074 (2006); https://doi.org/10.1021/je060170c

M. Habibullah, K.N. Das, I.M.M. Rahman, M.A. Uddin, K. Saifuddin, K. Iwakabe and H. Hasegawa, J. Chem. Eng. Data, 55, 5370 (2010); https://doi.org/10.1021/je100823t

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M. Indhumathi, G. Meenakshi, V.J. Priyadharshini, R. Kayalvizhi and S. Thiyagaraj, J. Chem. Pharm. Res., 4, 4245 (2012).

S.K. Bindhani, G.K. Roy, Y.K. Mohanty and T.R. Kubendran, Russ. J. Phys. Chem. A, 89, 1828 (2015); https://doi.org/10.1134/S0036024415100040

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J.A. Riddick, W.B. Bunger and T.K. Sakano, Organic Solvents: Physical Properties and Methods of Purification, Wiley-Interscience: New York, edn 4 (1986).

A. Weissberger, E.S. Proskauer, J.A. Riddick and E.E. Toops, Organic Solvents: Physical Properties and Methods of Purification, Wiley Interscience, edn 2 (1955).

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W. Vandeel, Experimental thermodynamics Butterworths & Co. Ltd: London, vol. IIB, Chap. XI (1975).

W. Schaaffs, Z. Phys., 114, 110 (1939); https://doi.org/10.1007/BF01340236

M.R. Rao, J. Chem. Phys., 9, 682 (1941); https://doi.org/10.1063/1.1750976

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A. Jouyban, M. Khoubnasabjafari, Z. Vaez-Gharamaleki, Z. Fekari and W.E.J. Acree, Chem. Pharm. Bull. (Tokyo), 53, 519 (2005); https://doi.org/10.1248/cpb.53.519

Issue

Vol. 32 No. 12 (2020): Vol 32 Issue 12, 2020

Evaluation of Ultrasonic Velocity Theories on Binary Liquid Mixtures of Propiophenone with Isomeric Xylenes at Temperatures (T = 303.15 to 318.15 K)

Corresponding Author(s) : D. Ramachandran

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