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Studies on the Electrochemical Parameters of Potentiodynamic Electrocopolymerization of Aniline
Corresponding Author(s) : Apoorv Saraswat
Asian Journal of Chemistry,
Vol. 32 No. 11 (2020): Vol 32 Issue 11
Abstract
To know more understanding on the parameters effecting electrocopolymerization of aniline, a theoretical study of electrochemical behaviour had been performed through cyclic voltammetry at the platinum electrode through controlled potential electrocopolymerization (CPE) in 0.01 M LiClO4 solution at a scan rate of 50 mV s-1. It is observed that parameters in the presence of additive (perchloric acid) and selective solvent-electrolyte pair parameters affect the morphology, stability and solubility of the copolymer matrix. The morphological structure analysis exhibits nano-structured polydispersity characterized by a scanning electron microscope.
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- D.E. Stilwell and S.-M. Park, J. Electrochem. Soc., 135, 2254 (1988); https://doi.org/10.1149/1.2096248
- D. Kumar, Eur. Polym. J., 35, 1919 (1999); https://doi.org/10.1016/S0014-3057(98)00178-5
- J.J. Langer, Synth. Met., 36, 35 (1990); https://doi.org/10.1016/0379-6779(90)90231-9
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- J. Lei, Z. Cai and C.R. Martin, Synth. Met., 46, 53 (1992); https://doi.org/10.1016/0379-6779(92)90318-D
- F. Lux, Polymer, 35, 2915 (1994); https://doi.org/10.1016/0032-3861(94)90402-2
- E. L. Kupila and J. Kankare, Synth. Met., 55, 1402 (1993); https://doi.org/10.1016/0379-6779(93)90258-X
- M. Leclerc, J. Guay and L.H. Dao, Macromolecules, 22, 649 (1989); https://doi.org/10.1021/ma00192a024
- Y. Cao and P. Smith, Polymer, 34, 3139 (1993); https://doi.org/10.1016/0032-3861(93)90381-J
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- C.V. Avadhani and S.P. Venaker, Polym. Bull., 24, 487 (1990); https://doi.org/10.1007/BF00395569
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- T. Lindfors and A. Ivaska, J. Electroanal. Chem., 531, 43 (2002); http://doi.org/10.1016/s0022-0724(02)01005-7
- T-H Le, Y. Kim and H. Yoon, Polymers, 9, 150 (2017); http://doi.org/10.3390/polym9040150
- L.K. Sharma, S. Kumar, S. Singh and R.K.P. Singh, Russ. J. Electrochem., 46, 34 (2010); https://doi.org/10.1134/S1023193510010040
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- L.K. Sharma, S. Singh and R.K.P. Singh, Indian J. Chem., 88, 155 (2011).
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- A. Saraswat, L.K. Sharma and R.K.P. Singh, J. Indian Chem. Soc., 89, 111 (2012).
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- A. Bagheri, M.R. Nateghi and A. Massoumi, Synth. Met., 97, 85 (1998); https://doi.org/10.1016/S0379-6779(98)00090-3
- N.T.K. Thanh, N. Maclean and S. Mahiddine, Chem. Rev., 114, 7610 (2014); http://doi.org/10.1021/cr400544s
References
D.E. Stilwell and S.-M. Park, J. Electrochem. Soc., 135, 2254 (1988); https://doi.org/10.1149/1.2096248
D. Kumar, Eur. Polym. J., 35, 1919 (1999); https://doi.org/10.1016/S0014-3057(98)00178-5
J.J. Langer, Synth. Met., 36, 35 (1990); https://doi.org/10.1016/0379-6779(90)90231-9
M.K. Ram, M. Joshi, M. Mehrotra, S.K. Dhawan and S. Chandra, Thin Solid Films, 304, 65 (1997); https://doi.org/10.1016/S0040-6090(97)00186-7
J. Lei, Z. Cai and C.R. Martin, Synth. Met., 46, 53 (1992); https://doi.org/10.1016/0379-6779(92)90318-D
F. Lux, Polymer, 35, 2915 (1994); https://doi.org/10.1016/0032-3861(94)90402-2
E. L. Kupila and J. Kankare, Synth. Met., 55, 1402 (1993); https://doi.org/10.1016/0379-6779(93)90258-X
M. Leclerc, J. Guay and L.H. Dao, Macromolecules, 22, 649 (1989); https://doi.org/10.1021/ma00192a024
Y. Cao and P. Smith, Polymer, 34, 3139 (1993); https://doi.org/10.1016/0032-3861(93)90381-J
A.G. MacDiarmid and R. Kaner, ed.: T. Skotheim, Handbook of Conducting Polymers, Marcel Dekker: New York, p. 689 (1986).
C.V. Avadhani and S.P. Venaker, Polym. Bull., 24, 487 (1990); https://doi.org/10.1007/BF00395569
S.B. Rhee, J. Park, W.B.S. Moon and J.Y. Chang, Macromolecules, 26, 404 (1993); https://doi.org/10.1021/ma00054a024
T. Lindfors and A. Ivaska, J. Electroanal. Chem., 531, 43 (2002); http://doi.org/10.1016/s0022-0724(02)01005-7
T-H Le, Y. Kim and H. Yoon, Polymers, 9, 150 (2017); http://doi.org/10.3390/polym9040150
L.K. Sharma, S. Kumar, S. Singh and R.K.P. Singh, Russ. J. Electrochem., 46, 34 (2010); https://doi.org/10.1134/S1023193510010040
M.K. Srivastava, A. Saraswat, L.K. Sharma and R.K.P. Singh, J. Indian Chem. Soc., 87, 1131 (2011).
L.K. Sharma, S. Singh and R.K.P. Singh, Indian J. Chem., 88, 155 (2011).
L.K. Sharma, A. Saraswat, M.K. Srivastava, H. Kumar and R.K.P. Singh, J. Indian Chem. Soc., 88, 727 (2011).
A. Saraswat, L.K. Sharma and R.K.P. Singh, J. Indian Chem. Soc., 89, 111 (2012).
A. Saraswat, L. Kant Sharma, M.K. Srivastava, I.R. Siddiqui and R.K.P. Singh, J. Appl. Polym. Sci., 123, 1479 (2012); https://doi.org/10.1002/app.34621
A. Bagheri, M.R. Nateghi and A. Massoumi, Synth. Met., 97, 85 (1998); https://doi.org/10.1016/S0379-6779(98)00090-3
N.T.K. Thanh, N. Maclean and S. Mahiddine, Chem. Rev., 114, 7610 (2014); http://doi.org/10.1021/cr400544s