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Synthesis and Catalytic Properties of Ruthenium and Iron Nanoparticles/Mesoporous Carbon Composites
Corresponding Author(s) : Yanmin Hou
Asian Journal of Chemistry,
Vol. 32 No. 11 (2020): Vol 32 Issue 11
Abstract
The mesoporous carbon material of Fe-MC loaded iron nanoparticles was obtained by pyrolysis of Fe-MIL-88A under nitrogen and reducing gas atmosphere. Addition of Ru(III) in the liquid phase, Ru(III) was reduced to ruthenium nanoparticles (RuNPs) by iron nanoparticles (FeNPs), led to the formation of mesoporous carbon composite of Ru@Fe-MC, where 0.77 wt% of Ru was completely wrapped on the surface of iron nanoparticles. The hydrolysis performance of Ru@Fe-MC to aminoborane was studied and the results showed a good catalytic performance, where the conversion frequency (TOF) was found to be 234.3 mol H2 min-1 (mol Ru)-1, and the activation energy was 33.6 kJ/mol. The reusbility catalyst performance of Ru@Fe-MC remained highly active after ten experiments.
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Z. Wu, Y. Duan, S. Ge, A.C.K. Yip, F. Yang, Y. Li and T. Dou, Catal. Commun., 91, 10 (2017); https://doi.org/10.1016/j.catcom.2016.12.007
M. Navlani-García, K. Mori, A. Nozaki, Y. Kuwahara and H. Yamashita, Appl. Catal. A Gen., 527, 45 (2016); https://doi.org/10.1016/j.apcata.2016.08.018
X. Xiong, L. Zhou, G. Yu, K. Yang, M. Ye and Q. Xia, Int. J. Hydrogen Energy, 40, 15521 (2015); https://doi.org/10.1016/j.ijhydene.2015.09.095
Z. Novotny, F.P. Netzer and Z. Dohnálek, Surf. Sci., 652, 230 (2016); https://doi.org/10.1016/j.susc.2016.03.020
K. Mori, K. Miyawaki and H. Yamashita, ACS Catal., 6, 3128 (2016); https://doi.org/10.1021/acscatal.6b00715
K. Yang, L. Zhou, G. Yu, X. Xiong, M. Ye, Y. Li, D. Lu, Y. Pan, M. Chen, L. Zhang, D. Gao, Z. Wang, H. Liu and Q. Xia, Int. J. Hydrogen Energy, 41, 6300 (2016); https://doi.org/10.1016/j.ijhydene.2016.02.104
H. Li, X. Li, Y. Hou and X. Zhao, Asian J. Chem., 29, 1447 (2017); https://doi.org/10.14233/ajchem.2017.20500
C. Du, J. Su, W. Luo and G. Cheng, J. Mol. Catal. Chem., 383-384, 38 (2014); https://doi.org/10.1016/j.molcata.2013.11.018
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