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Temperature Dependence of Micellization Properties of Binary Mixtures of Sodium Decylsulphate with Sodium Dodecylsulphate in Water
Corresponding Author(s) : O.G. Singh
Asian Journal of Chemistry,
Vol. 32 No. 10 (2020): Vol 32 Issue 10
Abstract
Conductance measurement method has been used to determine the critical micelle concentration (CMC) and counterion binding constant values of binary mixtures of sodium decylsulphate (SDeS) with sodium dodecylsulphate (SDS) in water at four different temperatures ranging from 298 K to 313 K at 5 K intervals. Rubingh′s model has been used to calculate the mixed micellization properties viz. mixed micelle composition, activity coefficient of the components, and mutual interaction parameter between the components. Variation of these mixed micellization properties with temperature has been studied. The studied binary surfactant mixtures show attractive interaction between the components and it decreases with increase in temperature, which is an interesting trend. Thermodynamic parameters of mixed micellization have also been calculated. The enthalpy (ΔH°mic) and entropy (ΔS°mic) of micellization compensate each other.
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- Y. Moroi, N. Nishikido and R. Matuura, J. Colloid Interface Sci., 50, 344 (1975); https://doi.org/10.1016/0021-9797(75)90238-6
- S.P. Moulik, M.E. Haque, P.K. Jana and A.R. Das, J. Phys. Chem., 100, 701 (1996); https://doi.org/10.1021/jp9506494
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- M. Manabe, M. Funamoto, F. Kohgami, H. Kawamura and H. Katsuura, Colloid Polym. Sci., 281, 239 (2003); https://doi.org/10.1007/s00396-002-0764-2
- K. Motomura, M. Yamanaka and M. Aratono, Colloid Polym. Sci., 262, 948 (1984); https://doi.org/10.1007/BF01490027
- A.J. Prosser and E.I. Franses, J. Colloid Interface Sci., 263, 606 (2003); https://doi.org/10.1016/S0021-9797(03)00346-1
- H. Maeda, J. Colloid Interface Sci., 258, 390 (2003); https://doi.org/10.1016/S0021-9797(02)00128-5
- J.F. Rathman and J.F. Scamehorn, Langmuir, 2, 354 (1986); https://doi.org/10.1021/la00069a019
- P.C. Griffiths, A.Y.F. Cheung, G.J. Finney, C. Farley, A.R. Pitt, A.M. Howe, S.M. King, R.K. Heenan and B.L. Bales, Langmuir, 18, 1065 (2002); https://doi.org/10.1021/la011163j
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- O.G. Singh and K. Ismail, J. Surfactants Deterg., 11, 89 (2008); https://doi.org/10.1007/s11743-007-1058-y
- A. Maneedaeng, K.J. Haller, B.P. Grady and A.E. Flood, J. Colloid Interface Sci., 356, 598 (2011); https://doi.org/10.1016/j.jcis.2011.01.008
- O.G. Singh and K. Ismail, Colloids Surf. A Physicochem. Eng. Asp., 414, 209 (2012); https://doi.org/10.1016/j.colsurfa.2012.08.025
- Q. Zhang, S. Li, F. Zhang, X. Wei, M. Liu, J. Liu and D. Sun, J. Surfactants Deterg., 20, 1281 (2017); https://doi.org/10.1007/s11743-017-2018-9
- A. Pal and R. Punia, Colloid Polym. Sci., 297, 1541 (2019); https://doi.org/10.1007/s00396-019-04566-7
- H. Jiang, G. Beaucage, K. Vogtt and M. Weaver, J. Colloid Interface Sci., 509, 25 (2018); https://doi.org/10.1016/j.jcis.2017.08.090
- E.D. Goddard and G.C. Benson, Can. J. Chem., 35, 986 (1957); https://doi.org/10.1139/v57-134
- C.L. Mesa, J. Phys. Chem., 94, 323 (1990); https://doi.org/10.1021/j100364a054
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- J.A. Stead and H. Taylor, J. Colloid Interface Sci., 30, 482 (1969); https://doi.org/10.1016/0021-9797(69)90417-2
- P. Mukerjee and A. Ray, J. Phys. Chem., 70, 2150 (1966); https://doi.org/10.1021/j100879a014
- J.E. Adderson and H. Taylor, J. Colloid Sci., 19, 495 (1964); https://doi.org/10.1016/0095-8522(64)90065-0
- G.M. Musbally, G. Perron and J.E. Desnoyers, J. Colloid Interface Sci., 54, 80 (1976); https://doi.org/10.1016/0021-9797(76)90287-3
- B.D. Flockhart, J. Colloid Sci., 16, 484 (1961); https://doi.org/10.1016/0095-8522(61)90026-5
- Y. Moroi, N. Nishikido, H. Uehara and R. Matuura, J. Colloid Interface Sci., 50, 254 (1975); https://doi.org/10.1016/0021-9797(75)90228-3
- L.-J. Chen, S.-Y. Lin and C.-C. Huang, J. Phys. Chem. B, 102, 4350 (1998); https://doi.org/10.1021/jp9804345
- S.B. Sulthana, S.G.T. Bhat and A.K. Rakshit, Colloids Surf. A Physicochem. Eng. Asp., 111, 57 (1996); https://doi.org/10.1016/0927-7757(95)03491-9
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- J.P. Marcolongo and M. Mirenda, J. Chem. Educ., 88, 629 (2011); https://doi.org/10.1021/ed900019u
- O.G. Singh, Asian J. Chem., 29, 2605 (2017); https://doi.org/10.14233/ajchem.2017.20706
- K.J. Mysels and R.J. Otter, J. Colloid Sci., 16, 462 (1961); https://doi.org/10.1016/0095-8522(61)90023-X
- D.N. Rubingh, in ed.: K.L. Mittal, Mixed Micelle Solutions, In: Solution Chemistry of Surfactants. Plenum Press: New York, vol. 1, p. 337 (1979).
- P.M. Holland and D.N. Rubingh, J. Phys. Chem., 87, 1984 (1983); https://doi.org/10.1021/j100234a030
- J.H. Clint, J. Chem. Soc., Faraday Trans. I, 71, 1327 (1975); https://doi.org/10.1039/f19757101327
- D.F. Evans and P.J. Wightman, J. Colloid Interface Sci., 86, 515 (1982); https://doi.org/10.1016/0021-9797(82)90096-0
- J.R. Rodríguez, A. González-Pérez, J.L. Del Castillo and J. Czapkiewicz, J. Colloid Interface Sci., 250, 438 (2002); https://doi.org/10.1006/jcis.2002.8362
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- R. Lumry and S. Rajender, Biopolymers, 9, 1125 (1970); https://doi.org/10.1002/bip.1970.360091002
References
Y. Moroi, N. Nishikido and R. Matuura, J. Colloid Interface Sci., 50, 344 (1975); https://doi.org/10.1016/0021-9797(75)90238-6
S.P. Moulik, M.E. Haque, P.K. Jana and A.R. Das, J. Phys. Chem., 100, 701 (1996); https://doi.org/10.1021/jp9506494
T. Matsuda, Y. Asoh, M. Villeneuve, H. Matsubara, T. Takiue and M. Aratono, Colloid Polym. Sci., 282, 324 (2004); https://doi.org/10.1007/s00396-003-0931-0
M. Manabe, M. Funamoto, F. Kohgami, H. Kawamura and H. Katsuura, Colloid Polym. Sci., 281, 239 (2003); https://doi.org/10.1007/s00396-002-0764-2
K. Motomura, M. Yamanaka and M. Aratono, Colloid Polym. Sci., 262, 948 (1984); https://doi.org/10.1007/BF01490027
A.J. Prosser and E.I. Franses, J. Colloid Interface Sci., 263, 606 (2003); https://doi.org/10.1016/S0021-9797(03)00346-1
H. Maeda, J. Colloid Interface Sci., 258, 390 (2003); https://doi.org/10.1016/S0021-9797(02)00128-5
J.F. Rathman and J.F. Scamehorn, Langmuir, 2, 354 (1986); https://doi.org/10.1021/la00069a019
P.C. Griffiths, A.Y.F. Cheung, G.J. Finney, C. Farley, A.R. Pitt, A.M. Howe, S.M. King, R.K. Heenan and B.L. Bales, Langmuir, 18, 1065 (2002); https://doi.org/10.1021/la011163j
T. Chakraborty and S. Ghosh, Colloid Polym. Sci., 285, 1665 (2007); https://doi.org/10.1007/s00396-007-1738-1
O.G. Singh and K. Ismail, J. Surfactants Deterg., 11, 89 (2008); https://doi.org/10.1007/s11743-007-1058-y
A. Maneedaeng, K.J. Haller, B.P. Grady and A.E. Flood, J. Colloid Interface Sci., 356, 598 (2011); https://doi.org/10.1016/j.jcis.2011.01.008
O.G. Singh and K. Ismail, Colloids Surf. A Physicochem. Eng. Asp., 414, 209 (2012); https://doi.org/10.1016/j.colsurfa.2012.08.025
Q. Zhang, S. Li, F. Zhang, X. Wei, M. Liu, J. Liu and D. Sun, J. Surfactants Deterg., 20, 1281 (2017); https://doi.org/10.1007/s11743-017-2018-9
A. Pal and R. Punia, Colloid Polym. Sci., 297, 1541 (2019); https://doi.org/10.1007/s00396-019-04566-7
H. Jiang, G. Beaucage, K. Vogtt and M. Weaver, J. Colloid Interface Sci., 509, 25 (2018); https://doi.org/10.1016/j.jcis.2017.08.090
E.D. Goddard and G.C. Benson, Can. J. Chem., 35, 986 (1957); https://doi.org/10.1139/v57-134
C.L. Mesa, J. Phys. Chem., 94, 323 (1990); https://doi.org/10.1021/j100364a054
E.H. Crook, G.F. Trebbi and D.B. Fordyce, J. Phys. Chem., 68, 3592 (1964); https://doi.org/10.1021/j100794a026
J.A. Stead and H. Taylor, J. Colloid Interface Sci., 30, 482 (1969); https://doi.org/10.1016/0021-9797(69)90417-2
P. Mukerjee and A. Ray, J. Phys. Chem., 70, 2150 (1966); https://doi.org/10.1021/j100879a014
J.E. Adderson and H. Taylor, J. Colloid Sci., 19, 495 (1964); https://doi.org/10.1016/0095-8522(64)90065-0
G.M. Musbally, G. Perron and J.E. Desnoyers, J. Colloid Interface Sci., 54, 80 (1976); https://doi.org/10.1016/0021-9797(76)90287-3
B.D. Flockhart, J. Colloid Sci., 16, 484 (1961); https://doi.org/10.1016/0095-8522(61)90026-5
Y. Moroi, N. Nishikido, H. Uehara and R. Matuura, J. Colloid Interface Sci., 50, 254 (1975); https://doi.org/10.1016/0021-9797(75)90228-3
L.-J. Chen, S.-Y. Lin and C.-C. Huang, J. Phys. Chem. B, 102, 4350 (1998); https://doi.org/10.1021/jp9804345
S.B. Sulthana, S.G.T. Bhat and A.K. Rakshit, Colloids Surf. A Physicochem. Eng. Asp., 111, 57 (1996); https://doi.org/10.1016/0927-7757(95)03491-9
S.K. Mehta, K.K. Bhasin, R. Chauhan and S. Dham, Colloids Surf. A Physicochem. Eng. Asp., 255, 153 (2005); https://doi.org/10.1016/j.colsurfa.2004.12.038
J.P. Marcolongo and M. Mirenda, J. Chem. Educ., 88, 629 (2011); https://doi.org/10.1021/ed900019u
O.G. Singh, Asian J. Chem., 29, 2605 (2017); https://doi.org/10.14233/ajchem.2017.20706
K.J. Mysels and R.J. Otter, J. Colloid Sci., 16, 462 (1961); https://doi.org/10.1016/0095-8522(61)90023-X
D.N. Rubingh, in ed.: K.L. Mittal, Mixed Micelle Solutions, In: Solution Chemistry of Surfactants. Plenum Press: New York, vol. 1, p. 337 (1979).
P.M. Holland and D.N. Rubingh, J. Phys. Chem., 87, 1984 (1983); https://doi.org/10.1021/j100234a030
J.H. Clint, J. Chem. Soc., Faraday Trans. I, 71, 1327 (1975); https://doi.org/10.1039/f19757101327
D.F. Evans and P.J. Wightman, J. Colloid Interface Sci., 86, 515 (1982); https://doi.org/10.1016/0021-9797(82)90096-0
J.R. Rodríguez, A. González-Pérez, J.L. Del Castillo and J. Czapkiewicz, J. Colloid Interface Sci., 250, 438 (2002); https://doi.org/10.1006/jcis.2002.8362
G. Sugihara and M. Hisatomi, J. Colloid Interface Sci., 219, 31 (1999); https://doi.org/10.1006/jcis.1999.6378
R. Lumry and S. Rajender, Biopolymers, 9, 1125 (1970); https://doi.org/10.1002/bip.1970.360091002