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Vol. 32 No. 10 (2020): Vol 32 Issue 10

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Synthesis and Properties of Two Fe(III) Coordination Polymers Based on 2-Amino-4-methylthiazole, 2-Mercaptobenzothiazole and Aromatic Polycarboxylate

https://doi.org/10.14233/ajchem.2020.22767
Maged S. Al-Fakeh
Chemistry Department, College of Science, Qassim University, Buraidah-51452, Saudi Arabia ; Taiz University, Taiz, Yemen
Nesrine Amiri
Laboratory of Physico-Chemistry of Materials, University of Monastir, Avenue of the Environment, 5019 Monastir, Tunisia
Ahmed N. Al-Hakemi
Chemistry Department, College of Science, Qassim University, Buraidah-51452, Saudi Arabia; Chemistry Department, College of Science, Ibb University, Yemen
Saeed El-Sayed Saeed
Chemistry Department, College of Science, Qassim University, Buraidah-51452, Saudi Arabia
Abuzar E.A.E. Albadri
Chemistry Department, College of Science, Qassim University, Buraidah-51452, Saudi Arabia

Corresponding Author(s) : Maged S. Al-Fakeh

m.alfakeh@qu.edu.sa

Asian Journal of Chemistry, Vol. 32 No. 10 (2020): Vol 32 Issue 10

Abstract

Two of coordination polymers of the general formula [Fe(BDC)(AMTZ)Cl]·2H2O and [Fe(BDC)(MBT)Cl]·H2O, BDC = 1,4-benzenedicarboxylic acid, AMTZ = 2-amino-4-methyl-thiazole and MBT = 2-mercaptobenzothiazole, have been synthesized and characterized. Structure of both coordination polymers has been evaluated on the basis of elemental analysis, thermal, FT-IR, UV-vis spectra and the charges been carried by the atoms, caused a dipole moment of 2.4346 debye and total energy -382 × 103 Kcal mol-1. Biological activity of the two synthesized complexes was tested against some fungal and bacterial strains.

Keywords

Coordination polymers Properties Iron(III) organic frameworks and biological activity
S. Al-Fakeh, M., Amiri, N., N. Al-Hakemi, A., El-Sayed Saeed, S., & E.A.E. Albadri, A. (2020). Synthesis and Properties of Two Fe(III) Coordination Polymers Based on 2-Amino-4-methylthiazole, 2-Mercaptobenzothiazole and Aromatic Polycarboxylate. Asian Journal of Chemistry, 32(10), 2502–2506. https://doi.org/10.14233/ajchem.2020.22767
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