Copyright (c) 2020 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Glittering ZnO/Ag/MnO Nano Superstructures for Photocatalytic Applications
Corresponding Author(s) : J.P. Shubha
Asian Journal of Chemistry,
Vol. 32 No. 10 (2020): Vol 32 Issue 10
Abstract
ZnO/Ag/MnO ternary heterostructure nanomaterials have been synthesized via cost effective green route using zinc nitrate, manganese acetate and silver nitrate as oxidizers and perished curd as a fuel. The obtained ZnO/Ag/MnO nanomaterials are analyzed using Powder X-ray diffraction (PXRD), Fourier transform infrared spectroscopy (FTIR), morphological studies by scanning electron microscopy (FESEM), internal structure by transmission electron microscopy (TEM). Both PXRD and FESEM techniques were used to confirm the formation of particles and flakes composition of ZnO/Ag/MnO nanomaterials. Photocatalytic activity of ZnO/Ag/MnO was assessed by varying light source, hydrogen ion concentration, amount of catalyst and amount of dye. The ZnO/Ag/MnO nanoparticles exhibited an enhanced photodegradation of methylene blue dye under visible light.
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- P. Pattnaik, G.S. Dangayach and A.K. Bhardwaj, Rev. Environ. Health, 33, 163 (2018); https://doi.org/10.1515/reveh-2018-0013
- R. Kant, Nat. Sci., 4, 22 (2012); https://doi.org/10.4236/ns.2012.41004
- Puttaswamy, J.P. Shubha and R.V. Jagadeesh, Transition Met. Chem, 32, 991 (2007); https://doi.org/10.1007/s11243-007-0271-x
- Puttaswamy, K.N. Vinod and K.N.N. Gowda, Dyes Pigments, 78, 131 (2008); https://doi.org/10.1016/j.dyepig.2007.11.002
- D. Depan and R.D.K. Misra, J. Biomed. Mater. Res. A, 102, 2934 (2014); https://doi.org/10.1002/jbm.a.34963
- K. Manjunath, T.N. Ravishankar, D. Kumar, K.P. Priyanka, T. Varghese, H.R. Naika, H. Nagabhushana, S.C. Sharma, J. Dupont, T. Ramakrishnappa and G. Nagaraju, Mater. Res. Bull., 57, 325 (2014); https://doi.org/10.1016/j.materresbull.2014.06.010
- N.S. Pavithra, K. Lingaraju, G.K. Raghu and G. Nagaraju, Spectrochim. Acta A Mol. Biomol. Spectrosc., 185, 11 (2017); https://doi.org/10.1016/j.saa.2017.05.032
- Udayabhanu, G. Nagaraju, H. Nagabhushana, D. Suresh, C. Anupama, G.K. Raghu and S.C. Sharma, Ceram. Int., 43, 11656 (2017); https://doi.org/10.1016/j.ceramint.2017.05.351
- D. Channei, B. Inceesungvorn, N. Wetchakun, S. Ukritnukun, A. Nattestad, J. Chen and S. Phanichphant, Sci. Rep., 4, 5757 (2014); https://doi.org/10.1038/srep05757
- G. Nagaraju, K. Manjunath, T.N. Ravishankar, B.S. Ravikumar, H. Nagabhushan, G. Ebeling and J. Dupont, J. Mater. Sci., 48, 8420 (2013); https://doi.org/10.1007/s10853-013-7654-5
- G. Nagaraju, J.P. Udayabhanu, J.P. Shubha, K. Manjunath and J. Dupont, Int. J. Hydrogen Energy, 43, 4028 (2018); https://doi.org/10.1016/j.ijhydene.2017.10.092
- K. Girija, S. Thirumalairajan, V.R. Mastelaro and D. Mangalaraj, J. Mater. Chem. A Mater. Energy Sustain., 3, 2617 (2015); https://doi.org/10.1039/C4TA05295A
- S. Safa, R. Azimirad, S. Safalou Moghaddam and M. Rabbani, Desal. Water Treat., 57, 6723 (2016); https://doi.org/10.1080/19443994.2015.1012561
- A. Phuruangrat, S. Siri, P. Wadbua, S. Thongtem and T. Thongtem, J. Phys. Chem. Solids, 126, 170 (2019); https://doi.org/10.1016/j.jpcs.2018.11.007
- E.E. Elemike, D.C. Onwudiwe, L. Wei, C. Lou and Z. Zhao, J. Environ. Chem. Eng., 7, 103190 (2019); https://doi.org/10.1016/j.jece.2019.103190
- A.A. Essawy, J. Cleaner Prod., 183, 1011 (2018); https://doi.org/10.1016/j.jclepro.2018.02.214
- T.K. Pathak, R.E. Kroon and H.C. Swart, Vacuum, 157, 508 (2018); https://doi.org/10.1016/j.vacuum.2018.09.020
- A. Khataee, R.D.C. Soltani, Y. Hanifehpour, M. Safarpour, H.G. Ranjbar and S.W. Joo, Ind. Eng. Chem. Res., 57, 1924 (2014); https://doi.org/10.1021/ie402743u
- M.A. Hernandez-Carrillo, R. Torres-Ricardez, M.F. Garcia-Mendoza, E. Ramirez-Morales, L. Rojas-Blanco and L.L. Diaz-Flores, G.E. Sepúlveda-Palacios, F. Paraguay-Delgado and G. Pérez-Hernández, Catal. Today, 349, 191 (2020); https://doi.org/10.1016/j.cattod.2018.04.060
- J.R. Torres-Hernández, E. Ramírez-Morales, L. Rojas-Blanco, J. PantojaEnriquez, G. Oskam, F. Paraguay-Delgado, B. Escobar-Morales, M. Acosta-Alejandro, L.L. Díaz-Flores and G. Pérez-Hernández, Mater. Sci. Semicond. Process., 37, 87 (2015); https://doi.org/10.1016/j.mssp.2015.02.009
- N. Morales-Flores, U. Pal and E. Sánchez Mora, Appl. Catal. A Gen., 394, 269 (2011); https://doi.org/10.1016/j.apcata.2011.01.011
- J. Liqiang, S. Xiaojun, X. Baifu, W. Baiqi, C. Weimin and F. Honggang, J. Solid State Chem., 177, 3375 (2004); https://doi.org/10.1016/j.jssc.2004.05.064
- N. Karimizadeh, M. Babamoradi, R. Azimirad and M. Khajeh, J. Electron. Mater., 47, 5452 (2018); https://doi.org/10.1007/s11664-018-6427-y
- P. Bharathi, S. Harish, J. Archana, M. Navaneethan, S. Ponnusamy, C. Muthamizhchelvan, M. Shimomura and Y. Hayakawa, Appl. Surf. Sci., 484, 884 (2019); https://doi.org/10.1016/j.apsusc.2019.03.131
- J. Li, F. Zhao, L. Zhang, M. Zhang, H. Jiang, S. Li and J. Li, RSC Adv., 83, 67610 (2015); https://doi.org/10.1039/C5RA08903D
- S. Chu, H. Li, Y. Wang, Q. Ma, H. Li, Q. Zhang and P. Yang, Mater. Lett., 252, 219 (2019); https://doi.org/10.1016/j.matlet.2019.05.145
- Y. Liu, G. Li, R. Mi, C. Deng and P. Gao, Sens. Actuators B Chem., 191, 537 (2014); https://doi.org/10.1016/j.snb.2013.10.068
- B.L. Martínez-Vargas, M. Cruz-Ramírez, J.A. Díaz-Real, J.L. Rodríguez-López, F.J. Bacame-Valenzuela, R. Ortega-Borges, Y. ReyesVidal and L. Ortiz- Frade, J. Photochem. Photobiol. Chem., 369, 85 (2019); https://doi.org/10.1016/j.jphotochem.2018.10.010
- P. Latha, K. Prakash and S. Karuthapandian, Adv. Powder Technol., 28, 2903 (2017); https://doi.org/10.1016/j.apt.2017.08.017
- S.B. Atla, W.-R. Lin, T.-C. Chien, M.-J. Tseng, J.-C. Shu, C.-C. Chen and C.-Y. Chen, Mater. Chem. Phys., 216, 380 (2018); https://doi.org/10.1016/j.matchemphys.2018.06.020
- E. Acayanka, D.S. kuete, G.Y. Kamgang, S. Nzali, S. Laminsi and P.T. Ndifon, Plasma Chem. Plasma Process., 36, 799 (2016); https://doi.org/10.1007/s11090-016-9699-0
- L. Wang, S. Liu, Z. Wang, Y. Zhou, Y. Qin and Z.L. Wang, ACS Nano, 10, 2636 (2016); https://doi.org/10.1021/acsnano.5b07678
- K. Manjunath, V.S. Souza, T. Ramakrishnappa, G. Nagaraju, J.D. Scholten and J. Dupont, J. Mater. Res. Exp., 3, 115904 (2016); https://doi.org/10.1088/2053-1591/3/11/115904
- Z. Zhang, Y. Ma, X. Bu, Q. Wu, Z. Hang, Z. Dong and X. Wu, Sci. Rep., 8, 10532 (2018); https://doi.org/10.1038/s41598-018-28832-w
- S.R. Lingampalli, U.K. Gautam and C.N.R. Rao, Energy Environ. Sci., 6, 3589 (2013); https://doi.org/10.1039/c3ee42623h
- H. Tedla, I. Díaz, T. Kebede and A.M. Taddesse, J. Environ. Chem.Eng., 3, 1586 (2015); https://doi.org/10.1016/j.jece.2015.05.012
- V. Hoseinpour and N. Ghaemi, Mater. Res. Express, 5, 085012 (2018); https://doi.org/10.1088/2053-1591/aad2c6
- J. Nagaraju and S. Pranesh, Curr. Nanomater., 5, 36 (2020); https://doi.org/10.2174/2405461504666191202105734
References
P. Pattnaik, G.S. Dangayach and A.K. Bhardwaj, Rev. Environ. Health, 33, 163 (2018); https://doi.org/10.1515/reveh-2018-0013
R. Kant, Nat. Sci., 4, 22 (2012); https://doi.org/10.4236/ns.2012.41004
Puttaswamy, J.P. Shubha and R.V. Jagadeesh, Transition Met. Chem, 32, 991 (2007); https://doi.org/10.1007/s11243-007-0271-x
Puttaswamy, K.N. Vinod and K.N.N. Gowda, Dyes Pigments, 78, 131 (2008); https://doi.org/10.1016/j.dyepig.2007.11.002
D. Depan and R.D.K. Misra, J. Biomed. Mater. Res. A, 102, 2934 (2014); https://doi.org/10.1002/jbm.a.34963
K. Manjunath, T.N. Ravishankar, D. Kumar, K.P. Priyanka, T. Varghese, H.R. Naika, H. Nagabhushana, S.C. Sharma, J. Dupont, T. Ramakrishnappa and G. Nagaraju, Mater. Res. Bull., 57, 325 (2014); https://doi.org/10.1016/j.materresbull.2014.06.010
N.S. Pavithra, K. Lingaraju, G.K. Raghu and G. Nagaraju, Spectrochim. Acta A Mol. Biomol. Spectrosc., 185, 11 (2017); https://doi.org/10.1016/j.saa.2017.05.032
Udayabhanu, G. Nagaraju, H. Nagabhushana, D. Suresh, C. Anupama, G.K. Raghu and S.C. Sharma, Ceram. Int., 43, 11656 (2017); https://doi.org/10.1016/j.ceramint.2017.05.351
D. Channei, B. Inceesungvorn, N. Wetchakun, S. Ukritnukun, A. Nattestad, J. Chen and S. Phanichphant, Sci. Rep., 4, 5757 (2014); https://doi.org/10.1038/srep05757
G. Nagaraju, K. Manjunath, T.N. Ravishankar, B.S. Ravikumar, H. Nagabhushan, G. Ebeling and J. Dupont, J. Mater. Sci., 48, 8420 (2013); https://doi.org/10.1007/s10853-013-7654-5
G. Nagaraju, J.P. Udayabhanu, J.P. Shubha, K. Manjunath and J. Dupont, Int. J. Hydrogen Energy, 43, 4028 (2018); https://doi.org/10.1016/j.ijhydene.2017.10.092
K. Girija, S. Thirumalairajan, V.R. Mastelaro and D. Mangalaraj, J. Mater. Chem. A Mater. Energy Sustain., 3, 2617 (2015); https://doi.org/10.1039/C4TA05295A
S. Safa, R. Azimirad, S. Safalou Moghaddam and M. Rabbani, Desal. Water Treat., 57, 6723 (2016); https://doi.org/10.1080/19443994.2015.1012561
A. Phuruangrat, S. Siri, P. Wadbua, S. Thongtem and T. Thongtem, J. Phys. Chem. Solids, 126, 170 (2019); https://doi.org/10.1016/j.jpcs.2018.11.007
E.E. Elemike, D.C. Onwudiwe, L. Wei, C. Lou and Z. Zhao, J. Environ. Chem. Eng., 7, 103190 (2019); https://doi.org/10.1016/j.jece.2019.103190
A.A. Essawy, J. Cleaner Prod., 183, 1011 (2018); https://doi.org/10.1016/j.jclepro.2018.02.214
T.K. Pathak, R.E. Kroon and H.C. Swart, Vacuum, 157, 508 (2018); https://doi.org/10.1016/j.vacuum.2018.09.020
A. Khataee, R.D.C. Soltani, Y. Hanifehpour, M. Safarpour, H.G. Ranjbar and S.W. Joo, Ind. Eng. Chem. Res., 57, 1924 (2014); https://doi.org/10.1021/ie402743u
M.A. Hernandez-Carrillo, R. Torres-Ricardez, M.F. Garcia-Mendoza, E. Ramirez-Morales, L. Rojas-Blanco and L.L. Diaz-Flores, G.E. Sepúlveda-Palacios, F. Paraguay-Delgado and G. Pérez-Hernández, Catal. Today, 349, 191 (2020); https://doi.org/10.1016/j.cattod.2018.04.060
J.R. Torres-Hernández, E. Ramírez-Morales, L. Rojas-Blanco, J. PantojaEnriquez, G. Oskam, F. Paraguay-Delgado, B. Escobar-Morales, M. Acosta-Alejandro, L.L. Díaz-Flores and G. Pérez-Hernández, Mater. Sci. Semicond. Process., 37, 87 (2015); https://doi.org/10.1016/j.mssp.2015.02.009
N. Morales-Flores, U. Pal and E. Sánchez Mora, Appl. Catal. A Gen., 394, 269 (2011); https://doi.org/10.1016/j.apcata.2011.01.011
J. Liqiang, S. Xiaojun, X. Baifu, W. Baiqi, C. Weimin and F. Honggang, J. Solid State Chem., 177, 3375 (2004); https://doi.org/10.1016/j.jssc.2004.05.064
N. Karimizadeh, M. Babamoradi, R. Azimirad and M. Khajeh, J. Electron. Mater., 47, 5452 (2018); https://doi.org/10.1007/s11664-018-6427-y
P. Bharathi, S. Harish, J. Archana, M. Navaneethan, S. Ponnusamy, C. Muthamizhchelvan, M. Shimomura and Y. Hayakawa, Appl. Surf. Sci., 484, 884 (2019); https://doi.org/10.1016/j.apsusc.2019.03.131
J. Li, F. Zhao, L. Zhang, M. Zhang, H. Jiang, S. Li and J. Li, RSC Adv., 83, 67610 (2015); https://doi.org/10.1039/C5RA08903D
S. Chu, H. Li, Y. Wang, Q. Ma, H. Li, Q. Zhang and P. Yang, Mater. Lett., 252, 219 (2019); https://doi.org/10.1016/j.matlet.2019.05.145
Y. Liu, G. Li, R. Mi, C. Deng and P. Gao, Sens. Actuators B Chem., 191, 537 (2014); https://doi.org/10.1016/j.snb.2013.10.068
B.L. Martínez-Vargas, M. Cruz-Ramírez, J.A. Díaz-Real, J.L. Rodríguez-López, F.J. Bacame-Valenzuela, R. Ortega-Borges, Y. ReyesVidal and L. Ortiz- Frade, J. Photochem. Photobiol. Chem., 369, 85 (2019); https://doi.org/10.1016/j.jphotochem.2018.10.010
P. Latha, K. Prakash and S. Karuthapandian, Adv. Powder Technol., 28, 2903 (2017); https://doi.org/10.1016/j.apt.2017.08.017
S.B. Atla, W.-R. Lin, T.-C. Chien, M.-J. Tseng, J.-C. Shu, C.-C. Chen and C.-Y. Chen, Mater. Chem. Phys., 216, 380 (2018); https://doi.org/10.1016/j.matchemphys.2018.06.020
E. Acayanka, D.S. kuete, G.Y. Kamgang, S. Nzali, S. Laminsi and P.T. Ndifon, Plasma Chem. Plasma Process., 36, 799 (2016); https://doi.org/10.1007/s11090-016-9699-0
L. Wang, S. Liu, Z. Wang, Y. Zhou, Y. Qin and Z.L. Wang, ACS Nano, 10, 2636 (2016); https://doi.org/10.1021/acsnano.5b07678
K. Manjunath, V.S. Souza, T. Ramakrishnappa, G. Nagaraju, J.D. Scholten and J. Dupont, J. Mater. Res. Exp., 3, 115904 (2016); https://doi.org/10.1088/2053-1591/3/11/115904
Z. Zhang, Y. Ma, X. Bu, Q. Wu, Z. Hang, Z. Dong and X. Wu, Sci. Rep., 8, 10532 (2018); https://doi.org/10.1038/s41598-018-28832-w
S.R. Lingampalli, U.K. Gautam and C.N.R. Rao, Energy Environ. Sci., 6, 3589 (2013); https://doi.org/10.1039/c3ee42623h
H. Tedla, I. Díaz, T. Kebede and A.M. Taddesse, J. Environ. Chem.Eng., 3, 1586 (2015); https://doi.org/10.1016/j.jece.2015.05.012
V. Hoseinpour and N. Ghaemi, Mater. Res. Express, 5, 085012 (2018); https://doi.org/10.1088/2053-1591/aad2c6
J. Nagaraju and S. Pranesh, Curr. Nanomater., 5, 36 (2020); https://doi.org/10.2174/2405461504666191202105734