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Vol. 32 No. 9 (2020): Vol 32 Issue 9, 2020

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Synthesis, Characterization and Biological Evaluation of Schiff Base Transition Metal Complexes Derived from 4-Nitrobenzene-1,2-diamine and 5-Chloroisatin

https://doi.org/10.14233/ajchem.2020.22724
Netra Pal Singh
Department of Chemistry, Deen Dayal Upadhyay Gorakhpur University, Gorakhpur-273009, India
Kaushal Kumar
Department of Chemistry, Meerut College, Meerut-250001, India
Gajendra Kumar
Department of Chemistry, Krishna College, Bijnor-246701, India
Anuroop Kumar
Department of Chemistry, Krishna College, Bijnor-246701, India

Corresponding Author(s) : Netra Pal Singh

npsmcm.in@gmail.com

Asian Journal of Chemistry, Vol. 32 No. 9 (2020): Vol 32 Issue 9, 2020

Abstract

A series of transition metal complexes of the type [MLX2], where M = Mn(II), Fe(II), Co(II), Ni(II), X = Cl–/CH3COO– and L = Schiff base derived from 4-nitrobenzene-1,2-diamine and 5-chloroisatin have been synthesized and characterized by elemental analysis, molar conductance, IR, UV-visible, magnetic moments measurement, 1H & 13C NMR and mass spectral studies. On the basis of physico-chemical studies and spectral evaluation, an octahedral geometry have been proposed for all metal(II) complexes. The antimicrobial activity of ligand and its metal complexes have been additionally screened against bacteria and fungi. Metal(II) complexes show good activity as compared to ligand towards studied microorganisms and also metal complexes checked for their catalytic properties for benzoylation of phenol.

Keywords

Schiff base Transition metal(II) complexes Antimicrobial activity 4-Nitrobenzene-1,2-diamine, 5-Chloroisatin
Pal Singh, N., Kumar, K., Kumar, G., & Kumar, A. (2020). Synthesis, Characterization and Biological Evaluation of Schiff Base Transition Metal Complexes Derived from 4-Nitrobenzene-1,2-diamine and 5-Chloroisatin. Asian Journal of Chemistry, 32(9), 2324–2328. https://doi.org/10.14233/ajchem.2020.22724
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