Copyright (c) 2020 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Behaviour of ortho-N-Glycoside as Green Corrosion Inhibitors for Tin in 0.5 M Citric Acid
Corresponding Author(s) : Mervate Mohamed Mohamed
Asian Journal of Chemistry,
Vol. 32 No. 9 (2020): Vol 32 Issue 9, 2020
Abstract
A bio-nondegradable functional glycoside derivative, viz. ortho-N-glycoside, was extracted from natural cabbage plants and its corrosion inhibition behavior was evaluated in relation to tin in a 0.5 M citric solution. An electrochemical study, using potentiodynamic polarization and scanning electrochemical microscopy (SEM), was conducted to determine corrosion inhibition. The results indicate that ortho-N-glycoside possesses a corrosion inhibition efficiency of 75.83% at a concentration of 0.5 mol L-1. The results of adsorption over the tin surface obeys Langmuir isotherm. The surface and the electrochemical reactivity of the tin samples in the citric acid solutions were examined using the SEM technique. This enable the corrosion type to be demonstrated. The results of the surface analysis be obtained using scanning electron microscopy (SEM).
Keywords
Download Citation
Endnote/Zotero/Mendeley (RIS)BibTeX
- A. Rustandi and M.A. Barrinaya, Appl. Mech. Mater., 842, 24 (2016); https://doi.org/10.4028/www.scientific.net/AMM.842.24
- G.H. Koch, Corrosion Costs and Preventive Strategies in the United States, US: NACE International (2002).
- B.F. Giannetti, P.T.A. Sumodjo, T. Rabockai, A.M. Souza and J. Barboza, Electrochim. Acta, 37, 143 (1992); https://doi.org/10.1016/0013-4686(92)80023-F
- V.K. Gouda, E.N. Rizkalla, S. Abd El Wahab and E.M. Ibrahim, Corros. Sci., 21, 1 (1981); https://doi.org/10.1016/0010-938X(81)90058-5
- N.A.-G. Abdel-Rahman, J. Global Biosci., 4, 2966 (2015).
- S.S. Abdel Rehim, S.M. Sayyah and M.M. El Deeb, Mater. Chem. Phys., 80, 696 (2003); https://doi.org/10.1016/S0254-0584(03)00128-7
- G. McKay, S.J. Allen, I.F. McConvey and M.S. Otterburn, J. Colloid Interface Sci., 80, 323 (1981); https://doi.org/10.1016/0021-9797(81)90192-2
- P.K. Malik, Dyes Pigments, 56, 239 (2003); https://doi.org/10.1016/S0143-7208(02)00159-6
- A. S. Afolabi, A. C. Muhirwa, A. S Abdulkareem and E. Muzenda, Int. J. Electrochem. Sci., 9, 5895 (2014).
- K.O. Orubite and N.C. Oforka, Mater. Lett., 58, 1768 (2004); https://doi.org/10.1016/j.matlet.2003.11.030
- N.J.N. Nnaji, C.O.B. Okoye, N.O. Obi-Egbedi, M.A. Ezeokonkwo and J.U. Ani, Int. J. Electrochem. Sci., 8, 1735 (2013).
- S.S. Abd El Rehim, A.M. Zaky and N.F. Mohamed, J. Alloys Compd., 424, 88 (2006); https://doi.org/10.1016/j.jallcom.2005.12.080
- S.S. Abd El Rehim, H.H. Hassan and N.F. Mohamed, Corros. Sci., 46, 1071 (2004); https://doi.org/10.1016/S0010-938X(03)00134-3
- C.M.V.B. Almeida, T. Rabóczkay and B.F. Giannetti, J. Appl. Electrochem., 29, 123 (1999); https://doi.org/10.1023/A:1003468731553
- A. El-Sayed, F. Assaf and S.S. Abd El-Rehim, Hung. J. Ind. Chem., 19, 207 (1991).
- N.F. El Boraei and S.S. Abd El Rehim, Mater. Chem. Phys., 215, 332 (2018); https://doi.org/10.1016/j.matchemphys.2018.05.040
- R.M. El Sherif and W.A. Badawy, Int. J. Electrochem. Sci., 6, 6469 (2011).
- M. Elboujdaini, E. Ghali, R.G. Barradas and M. Girgis, Corros. Sci., 30, 855 (1990); https://doi.org/10.1016/0010-938X(90)90009-T
- H. Do Duc and P. Tissot, Corros. Sci., 19, 179 (1979); https://doi.org/10.1016/0010-938X(79)90016-7
- E.A. Noor and A.H. Al-Moubaraki, Mater. Chem. Phys., 110, 145 (2008); https://doi.org/10.1016/j.matchemphys.2008.01.028
- G. Avci, Colloids Surf. A Physicochem. Eng. Asp., 317, 730 (2008); https://doi.org/10.1016/j.colsurfa.2007.12.009
- E.A. Noor, Int. J. Electrochem. Sci., 2, 996 (2007)
- S.A. Abd El-Maksoud, Int. J. Electrochem. Sci., 3, 528 (2008).
- I.B. Obot, N.O. Obi-Egbedi and S.A. Umoren, Int. J. Electrochem. Sci., 4, 863 (2009).
- I. Langmuir, J. Am. Chem. Soc., 38, 2221 (1916); https://doi.org/10.1021/ja02268a002
- A.K. Mishra and R. Balasubramaniam, Mater. Chem. Phys., 103, 385 (2007); https://doi.org/10.1016/j.matchemphys.2007.02.079
- P.C. Okafor, U.J. Ekpe, E. Ebenso, E. Oguzie, N. Umo and A.R. Etor, Trans. SAEST, 41, 82 (2006).
- N.J.N. Nnaji, N.O. Obi-Egbedi and J.U. Ani, J. Sci. Ind. Stud., 9, 26 (2011).
- N.O. Obi-Egbedi, K.E. Essien, and I.B. Obot, J. Comput. Method Mol. Design, 1, 26 (2011).
References
A. Rustandi and M.A. Barrinaya, Appl. Mech. Mater., 842, 24 (2016); https://doi.org/10.4028/www.scientific.net/AMM.842.24
G.H. Koch, Corrosion Costs and Preventive Strategies in the United States, US: NACE International (2002).
B.F. Giannetti, P.T.A. Sumodjo, T. Rabockai, A.M. Souza and J. Barboza, Electrochim. Acta, 37, 143 (1992); https://doi.org/10.1016/0013-4686(92)80023-F
V.K. Gouda, E.N. Rizkalla, S. Abd El Wahab and E.M. Ibrahim, Corros. Sci., 21, 1 (1981); https://doi.org/10.1016/0010-938X(81)90058-5
N.A.-G. Abdel-Rahman, J. Global Biosci., 4, 2966 (2015).
S.S. Abdel Rehim, S.M. Sayyah and M.M. El Deeb, Mater. Chem. Phys., 80, 696 (2003); https://doi.org/10.1016/S0254-0584(03)00128-7
G. McKay, S.J. Allen, I.F. McConvey and M.S. Otterburn, J. Colloid Interface Sci., 80, 323 (1981); https://doi.org/10.1016/0021-9797(81)90192-2
P.K. Malik, Dyes Pigments, 56, 239 (2003); https://doi.org/10.1016/S0143-7208(02)00159-6
A. S. Afolabi, A. C. Muhirwa, A. S Abdulkareem and E. Muzenda, Int. J. Electrochem. Sci., 9, 5895 (2014).
K.O. Orubite and N.C. Oforka, Mater. Lett., 58, 1768 (2004); https://doi.org/10.1016/j.matlet.2003.11.030
N.J.N. Nnaji, C.O.B. Okoye, N.O. Obi-Egbedi, M.A. Ezeokonkwo and J.U. Ani, Int. J. Electrochem. Sci., 8, 1735 (2013).
S.S. Abd El Rehim, A.M. Zaky and N.F. Mohamed, J. Alloys Compd., 424, 88 (2006); https://doi.org/10.1016/j.jallcom.2005.12.080
S.S. Abd El Rehim, H.H. Hassan and N.F. Mohamed, Corros. Sci., 46, 1071 (2004); https://doi.org/10.1016/S0010-938X(03)00134-3
C.M.V.B. Almeida, T. Rabóczkay and B.F. Giannetti, J. Appl. Electrochem., 29, 123 (1999); https://doi.org/10.1023/A:1003468731553
A. El-Sayed, F. Assaf and S.S. Abd El-Rehim, Hung. J. Ind. Chem., 19, 207 (1991).
N.F. El Boraei and S.S. Abd El Rehim, Mater. Chem. Phys., 215, 332 (2018); https://doi.org/10.1016/j.matchemphys.2018.05.040
R.M. El Sherif and W.A. Badawy, Int. J. Electrochem. Sci., 6, 6469 (2011).
M. Elboujdaini, E. Ghali, R.G. Barradas and M. Girgis, Corros. Sci., 30, 855 (1990); https://doi.org/10.1016/0010-938X(90)90009-T
H. Do Duc and P. Tissot, Corros. Sci., 19, 179 (1979); https://doi.org/10.1016/0010-938X(79)90016-7
E.A. Noor and A.H. Al-Moubaraki, Mater. Chem. Phys., 110, 145 (2008); https://doi.org/10.1016/j.matchemphys.2008.01.028
G. Avci, Colloids Surf. A Physicochem. Eng. Asp., 317, 730 (2008); https://doi.org/10.1016/j.colsurfa.2007.12.009
E.A. Noor, Int. J. Electrochem. Sci., 2, 996 (2007)
S.A. Abd El-Maksoud, Int. J. Electrochem. Sci., 3, 528 (2008).
I.B. Obot, N.O. Obi-Egbedi and S.A. Umoren, Int. J. Electrochem. Sci., 4, 863 (2009).
I. Langmuir, J. Am. Chem. Soc., 38, 2221 (1916); https://doi.org/10.1021/ja02268a002
A.K. Mishra and R. Balasubramaniam, Mater. Chem. Phys., 103, 385 (2007); https://doi.org/10.1016/j.matchemphys.2007.02.079
P.C. Okafor, U.J. Ekpe, E. Ebenso, E. Oguzie, N. Umo and A.R. Etor, Trans. SAEST, 41, 82 (2006).
N.J.N. Nnaji, N.O. Obi-Egbedi and J.U. Ani, J. Sci. Ind. Stud., 9, 26 (2011).
N.O. Obi-Egbedi, K.E. Essien, and I.B. Obot, J. Comput. Method Mol. Design, 1, 26 (2011).