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Vol. 29 No. 6 (2017): Vol 29 Issue 6

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Chemically Modified Carbon Paste Sensor Based on N1,N2-Bis(salicylidine)butane-1,4-diamine for Determination of Nd(III)

https://doi.org/10.14233/ajchem.2017.20473
Beena Saraswathyamma
Department of Chemistry, Amrita School of Arts and Sciences, Amritapuri, Amrita Vishwa Vidyapeetham, Amrita University, Kollam-690 525, India
Krishnapillai Girish Kumar
Department of Applied Chemistry, Cochin University of Science and Technology, Kochi-682 022, India
Shyama
Department of Chemistry, Amrita School of Arts and Sciences, Amritapuri, Amrita Vishwa Vidyapeetham, Amrita University, Kollam-690 525, India
Athira V. Sagar
Department of Chemistry, Amrita School of Arts and Sciences, Amritapuri, Amrita Vishwa Vidyapeetham, Amrita University, Kollam-690 525, India
S. Amritha
Department of Chemistry, Amrita School of Arts and Sciences, Amritapuri, Amrita Vishwa Vidyapeetham, Amrita University, Kollam-690 525, India
Haritha G. Krishnan
Department of Chemistry, Amrita School of Arts and Sciences, Amritapuri, Amrita Vishwa Vidyapeetham, Amrita University, Kollam-690 525, India

Corresponding Author(s) : Beena Saraswathyamma

beenasdec25@gmail.com

Asian Journal of Chemistry, Vol. 29 No. 6 (2017): Vol 29 Issue 6

Abstract

Fabrication of carbon paste sensor modified with N1,N2-bis(salicylidine)butane-1,4-diamine (SAB) for Nd(III) has been demonstrated. The sensor having the composition of 90 % graphite and 10 % SAB exhibited best performance in the concentration range of 1.0 × 10-6 to 1.0 × 10-2 M. Nernstian slope of the sensor was found to be 19.5 ± 0.3 mV/decade. The sensor displayed fast response time of 10 s in the pH range 3.5 to 8.0. The detection limit is found to be 4.7 × 10-7 M. The proposed sensor can be used over a period of 5 weeks without any significant changes in its Nerstian behaviour. The sensor showed good selectivity for neodymium in presence of other metal ions such as Na+, K+, Mg2+, Ca2+, Pb2+, Ag+, Pr3+, Sm3+, La3+ and Gd3+. The practical utility of the developed sensor was investigated in the determination of neodymium in binary mixtures. This electrode is also utilized as an indicator electrode in the potentiometric titration of Nd(III) ions with EDTA.

Keywords

Chemically modified carbon paste sensor Neodymium ions N1,N2-Bis(salicylidine)butane-1,4-diamine Potentiometry
Saraswathyamma, B., Kumar, K. G., Shyama, ., Sagar, A. V., Amritha, S., & Krishnan, H. G. (2017). Chemically Modified Carbon Paste Sensor Based on N1,N2-Bis(salicylidine)butane-1,4-diamine for Determination of Nd(III). Asian Journal of Chemistry, 29(6), 1296–1300. https://doi.org/10.14233/ajchem.2017.20473
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