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Vol. 16 No. 2 (2004): Vol 16 Issue 2

Periodate Oxidation of p-Bromoaniline in Acetone-water medium: A Kinetic Mechanistic Study

R.D. Kaushik
Department of Chemistry, Gurukul Kangri University, Haridwar-249 404, India
Mukta Dubey
Department of Chemistry, Gurukul Kangri University, Haridwar-249 404, India
Raghvendra P. Singh
Department of Chemistry, Gurukul Kangri University, Haridwar-249 404, India
Amrita
Department of Chemistry, Gurukul Kangri University, Haridwar-249 404, India

Corresponding Author(s) : R.D. Kaushik

Asian Journal of Chemistry, Vol. 16 No. 2 (2004): Vol 16 Issue 2

Abstract

Results of kinetic study on the periodate oxidation of p-bromoaniline (PBA) in acetone-water medium have been presented and discussed. Rate law has been derived and mechanism suggested on the basis of various results like first order in each reactant, stoichiometry, thermodynamic parameters, main product identified as 4-bromo-1,2-benzoquinone and various factors influencing the reaction rate such as the effect of pH, dielectric constant, ionic strength and free radical scavengers.

Keywords

Kinetics Periodate oxidation p-Bromoaniline 4-Bromo-1,2-benzoquinone
Kaushik, R., Dubey, M., P. Singh, R., & Amrita, . (2016). Periodate Oxidation of p-Bromoaniline in Acetone-water medium: A Kinetic Mechanistic Study. Asian Journal of Chemistry, 16(2), 831–836. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/14584
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