Synthesis and Crystal Structure of Stable Oxyphosphoranes

Luo Mei; Lu Shao Feng

Issue

Vol. 16 No. 2 (2004): Vol 16 Issue 2

Issue Published : 2 April 2004

Synthesis and Crystal Structure of Stable Oxyphosphoranes

Luo Mei

Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China

Lu Shao Feng

Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China

Corresponding Author(s) : Luo Mei

luomeihuahua@sohu.com

Asian Journal of Chemistry, Vol. 16 No. 2 (2004): Vol 16 Issue 2
Article Published : 2 September 2016

Abstract

Exceptionally stable spiro cyclicoxyphosphoanes were prepared by potassium permanganate oxidation of bis(o-tolyl) phenylphosphine oxide followed by acidification probably involving nucleophilic attack by phosphine oxygen atom on a carboxylic carbonyl group. And its structure was determined by single-crystal X-ray diffraction.

Keywords

Spiro cyclicoxyphosphoanes Nuclephilic attack Crystal structure

(1)

Mei, L.; Shao Feng, L. Synthesis and Crystal Structure of Stable Oxyphosphoranes. ajc 2016, 16, 1124-1128.

Issue

Vol. 16 No. 2 (2004): Vol 16 Issue 2

Synthesis and Crystal Structure of Stable Oxyphosphoranes

Corresponding Author(s) : Luo Mei

Abstract

Keywords

Full Article

Download Citation

Table Of Contents