Kinetics of Oxidation of Aldehydes in Absence and Presence of Surfactants
Corresponding Author(s) : Firoz Ahmad
Asian Journal of Chemistry,
Vol. 16 No. 2 (2004): Vol 16 Issue 2
Abstract
The kinetics of oxidation of aldehydes by bromate in the absence of any surfactant has been studied and compared with the kinetic parameters observed in the presence of anionic surfactant of sodium dodecylsulphate (SDS) and cationic surfactant of cetylpyridinium chloride (CPC). The observed rate law is
–d[BrO3–]/dt = k' [Aldehyde][BrO3–]
where k' is a complex function of hydrogen ion concentration and surfactant concentration.
Keywords
Kinetics
Aldehydes
Surfactants
(1)
Ahmad, F.; Abbas Siddiqui, M. Kinetics of Oxidation of Aldehydes in Absence and Presence of Surfactants. ajc 2016, 16, 581-609.
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