A New Versatile Tool for Isomerization: Synthesis and Characterization of Lanthanide Chloride Tridendate Schiff base Derivatives

Sadaf ul Hassan; Faiza Kazmi; Rashid Abro; Muhammad Ammar

doi:10.14233/ajchem.2017.20359

Issue

Vol. 29 No. 6 (2017): Vol 29 Issue 6

Issue Published : April 10, 2017

This work is licensed under a Creative Commons Attribution 4.0 International License.

A New Versatile Tool for Isomerization: Synthesis and Characterization of Lanthanide Chloride Tridendate Schiff base Derivatives

https://doi.org/10.14233/ajchem.2017.20359

Sadaf ul Hassan

Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P.R. China

Faiza Kazmi

Institute of Chemistry, University of Punjab, Lahore, Pakistan

Rashid Abro

Beijing Key Laboratory of Membrane Science & Technology, College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, P. R. China

Muhammad Ammar

Beijing Key Laboratory of Membrane Science & Technology, College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, P. R. China

Corresponding Author(s) : Sadaf ul Hassan

sadafulhassan@pku.edu.cn

Asian Journal of Chemistry, Vol. 29 No. 6 (2017): Vol 29 Issue 6
Article Published : April 9, 2017

Abstract

The different types of the tridentate Schiff base N-(2-methoxyphenyl) salicylideneamine derivative of lanthanideindenyl chloride complexes [Ind·Ln·Schiff base·Cl·2THF (Ln = Sm, Eu, Gd and Er)] along with NaH are proved to be a versatile tool for the isomerization of 1,5-hexadiene. The isomerization resulted in a mixture of hexa-1, 4-diene, hexa-2,4-diene, methylenecyclopentane and methylcyclopentene. Hexa-1,4-diene and methylenecyclopentane were the major products while hexa-2,4-diene and methylcyclopentene were the minor ones. The results showed that ligand size and radius of the metal are important factors in determining the catalytic efficiency of the complexes.

Keywords

Schiff base Indene Lanthanocene Hexa-1,5-diene Isomerization

Hassan, S. ul, Kazmi, F., Abro, R., & Ammar, M. (2017). A New Versatile Tool for Isomerization: Synthesis and Characterization of Lanthanide Chloride Tridendate Schiff base Derivatives. Asian Journal of Chemistry, 29(6), 1194–1198. https://doi.org/10.14233/ajchem.2017.20359

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References

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D. Cui, T. Tang, W. Bi, J. Cheng, W. Chen and B. Huang, J. Polym. Sci. A Polym. Chem., 41, 2667 (2003); https://doi.org/10.1002/pola.10814.

K. Hultzsch, T. Spaniol and J. Okuda, Angew. Chem. Int. Ed., 38, 227 (1999); https://doi.org/10.1002/(SICI)1521-3773(19990115)38:1/2<227::AIDANIE227>3.0.CO;2-M.

M. Nishiura, Z. Hou, T. Koizumi, T. Imamoto and Y. Wakatsuki, Macromolecules, 32, 8245 (1999); https://doi.org/10.1021/ma990101l.

C. Schaverien, J. Mol. Catal., 90, 177 (1994); https://doi.org/10.1016/0304-5102(94)00008-5.

W.M. Mueller, Metal Hydrides, Academic Press, New York, edn 4 (1968).

P.G. Cozzi, Chem. Soc. Rev., 33, 410 (2004); https://doi.org/10.1039/B307853C.

R.D. Jones, D.A. Summerville and F. Basolo, Chem. Rev., 79, 139 (1979); https://doi.org/10.1021/cr60318a002.

H.O. Gisela, The Chemistry of the Catalyzed Hydrogenation of Carbon Monoxide, Springer Verlag, Berlin, Germany, edn 3 (1984).

V.H. Dugas and C. Penny, Bioorganic Chemistry-A Chemical Approach to Enzyme Action, Springer-Verlag, Berlin, pp. 508 (1981).

J.D. Margerum and L.J. Miller, Photochromism, Wiley-Interscience, New York USA, edn 3 (1971).

W. Sawodny and M. Riederer, Angew. Chem. Int. Ed. Engl., 16, 859 (1977); https://doi.org/10.1002/anie.197708591.

M. Yousaf, J.U. Huang, Z.F. Feng, Y.L. Qian, J.Q. Sun and Z.D. Pan, Chin. J. Chem., 18, 759 (2000); https://doi.org/10.1002/cjoc.20000180519.

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M. Szypa, M. Urbala, Z. Rozwadowski and T. Dziembowska, Transition Met. Chem., 33, 855 (2008); https://doi.org/10.1007/s11243-008-9122-7.

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R. Drozdzak, B. Allaert, N. Ledoux, I. Dragutan, V. Dragutan and F. Verpoort, Adv. Synth. Catal., 347, 1721 (2005); https://doi.org/10.1002/adsc.200404389.

M. Yousaf, Q. Liu, J. Huang and Y. Qian, Chin. J. Chem., 18, 740 (2000); https://doi.org/10.1002/cjoc.20000180515.

R.E. Maginn, S. Manastyrskyj and M. Dubeck, J. Am. Chem. Soc., 85, 672 (1963); https://doi.org/10.1021/ja00889a007.

Q. Liu, M. Ding, Y. Lin and Y. Xing, Polyhedron, 17, 555 (1998); https://doi.org/10.1016/S0277-5387(97)00335-5.

Issue

Vol. 29 No. 6 (2017): Vol 29 Issue 6

A New Versatile Tool for Isomerization: Synthesis and Characterization of Lanthanide Chloride Tridendate Schiff base Derivatives

Corresponding Author(s) : Sadaf ul Hassan

Abstract

Keywords

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