Synthesis and Spectroscopic Properties of [VO(aspa/gluta)H2O] and [VO(aspa/gluta)ImH]
Corresponding Author(s) : P.K. Singh
Asian Journal of Chemistry,
Vol. 16 No. 3 (2004): Vol 16 Issue 3
Abstract
Reaction of the tridentate amino acids, viz., aspartic acid and glutamic acid with VO2+ ion in 1 : 1 molar ratio in aqueous solution yields [VO(aspa/gluta)H2O], (dimeric), while reaction with VO2+ ion, amino acid and imidazole in 1 : 1 : 1 molar ratio in aqueous solution yields [VO(aspa/gluta)ImH], (monomer). In addition to synthesis, we report the magnetic IR, EPR and optical absorption data of these compounds.
Keywords
Oxovanadium(IV)
Aspartic acid
Glutamic acid
Imidazole
IR
EPR
(1)
Singh, P. Synthesis and Spectroscopic Properties of [VO(aspa gluta)H2O] and [VO(aspa Gluta)ImH]. ajc 2016, 16, 1483-1488.
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