Synthesis of a Novel Sandwich Copper Complex [(TACN)2Cu](ClO4)2&middot;H2O

Nai-Liang Hu; Hua-Ze Dong; Zi-Xiang Huang; Fu-Xin Xie

Issue

Vol. 17 No. 2 (2005): Vol 17 Issue 2

Issue Published : 30 December 2004

Synthesis of a Novel Sandwich Copper Complex [(TACN)2Cu](ClO4)2·H2O

Nai-Liang Hu

Department of Chemistry, Anhui University, Hefei-230 039, PR China

Hua-Ze Dong

Key Lab of Material Physics, Institute of Solid State Physics, Academia Sinica, Hefei 230031, PR China

Zi-Xiang Huang

Fujian Institute of Research on the Structure of Matter, Chinese Academy of Science, Fuzhou 350002, PR China

Fu-Xin Xie

Department of Chemistry, Anhui University, Hefei-230 039, PR China

Corresponding Author(s) : Nai-Liang Hu

bijianghong@ahieedu.net.cn

Asian Journal of Chemistry, Vol. 17 No. 2 (2005): Vol 17 Issue 2
Article Published : 31 January 2016

Abstract

A novel sandwiched copper(II) complex with the ligand 1,4,7-triazacyclononane has been synthesized and characterized by using X-ray diffraction analysis. The results indicate that its crystallographic structure is monoclinic, possessing parameters: P2(1)/c, a = 9.5896(3) Å, b = 13.5820(10) Å, c = 9.5850(3) Å, a = 90.00º, b = 119.3850(10)º, g = 90.00º, n = 1087.79(5) Å³, Z = 2, Dx = 1.627 mg cm^–3, R = 0.0560, wR = 0.1548, F(000) = 550.

Keywords

Copper(II) complex Triazacyclononane Sandwich structure

(1)

Hu, N.-L.; Dong, H.-Z.; Huang, Z.-X.; Xie, F.-X. Synthesis of a Novel Sandwich Copper Complex [(TACN)2Cu](ClO4)2&Middot;H2O. ajc 2016, 17, 1276-1280.

Issue

Vol. 17 No. 2 (2005): Vol 17 Issue 2

Synthesis of a Novel Sandwich Copper Complex [(TACN)2Cu](ClO4)2·H2O

Corresponding Author(s) : Nai-Liang Hu

Abstract

Keywords

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