Synthesis of a Novel Sandwich Copper Complex [(TACN)2Cu](ClO4)2·H2O
Corresponding Author(s) : Nai-Liang Hu
bijianghong@ahieedu.net.cn
Asian Journal of Chemistry,
Vol. 17 No. 2 (2005): Vol 17 Issue 2
Abstract
A novel sandwiched copper(II) complex with the ligand 1,4,7-triazacyclononane has been synthesized and characterized by using X-ray diffraction analysis. The results indicate that its crystallographic structure is monoclinic, possessing parameters: P2(1)/c, a = 9.5896(3) Å, b = 13.5820(10) Å, c = 9.5850(3) Å, a = 90.00º, b = 119.3850(10)º, g = 90.00º, n = 1087.79(5) Å3, Z = 2, Dx = 1.627 mg cm–3, R = 0.0560, wR = 0.1548, F(000) = 550.
Keywords
Copper(II) complex
Triazacyclononane
Sandwich structure
Hu, N.-L., Dong, H.-Z., Huang, Z.-X., & Xie, F.-X. (2016). Synthesis of a Novel Sandwich Copper Complex [(TACN)2Cu](ClO4)2·H2O. Asian Journal of Chemistry, 17(2), 1276–1280. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/14339
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