Mechanistic Aspects of Ru(III) Catalyzed Oxidation of Cyclopentanol by Chloramine-T in Acidic Medium
Corresponding Author(s) : R.A. Singh
rasinghtdc@rediffmail.com
Asian Journal of Chemistry,
Vol. 17 No. 2 (2005): Vol 17 Issue 2
Abstract
The kinetics of Ru(III) catalyzed oxidation of cyclopentanol by chloramine-T has been investigated in acidic medium. The reaction shows first order kinetics with respect to cyclopentanol, chloramine-T, H+ and Ru(III). There is insignificant effect of ionic strength, PTS and KCl on the reaction rate. The dielectric constant of the medium has positive effect. Elevation of temperature increases the rate of reaction in oxidation of cyclopentanol. A mechanism consistent with the above kinetic results has been suggested.
Keywords
Kinetics
Ru(III)
Oxidation
Cyclopentanol
Chloramine-T
Singh, R., Mishra, S., Srivastava, V., & Verma, J. (2016). Mechanistic Aspects of Ru(III) Catalyzed Oxidation of Cyclopentanol by Chloramine-T in Acidic Medium. Asian Journal of Chemistry, 17(2), 849–854. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/14328
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