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Synthesis of Polyacrylate Binder by Emulsion Polymerization and Application on Cotton
Corresponding Author(s) : Madan Sahil
Asian Journal of Chemistry,
Vol. 29 No. 5 (2017): Vol 29 Issue 5
Abstract
Present research explores the synthesis of poly-acrylate binder via emulsion polymerization to produces high molecular weight polymers. There is no or negligible content of volatile organic compounds where alcohol polyethylene glycol ether (AEO9), K12 were used as emulsifiers and ammonium persulphate used as an initiator and pigment printing on cotton by simple screen-printing technique. The polymerizing monomers and their charge ratio and their effects on reaction conversion rate, gel fraction rate, crocking fastness properties, solid content, emulsion stability and water resistance of samples were examined. Results showed that binder performance on these parameters were satisfactory. In addition, significantly improvement was observed on water resistant and stability parameters. The chemical structures of resulting copolymers were characterized by Fourier transform infrared spectroscopy and morphological changes of cotton fabric have been studied with the scanning electron microscope and no consequential differences were observed after characterization.
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- S.R. Karmakar, Chemical Technology in the Pre-treatment Processes of Textiles, Elsevier, p. 12 (1999).
- R. Eisenlohr and V. Giesen, Inter. Dyer., 12, 180 (1995).
- M. Galgali, Colourant, 45, 20 (1998).
- M. El-Molla, Dyes Pigmments, 74, 371 (2007); https://doi.org/10.1016/j.dyepig.2006.02.021.
- S. Bahmani, G. East and I. Holme, Color. Technol., 116, 94 (2000); https://doi.org/10.1111/j.1478-4408.2000.tb00027.x.
- M. El-Molla and R. Schneider, Dyes Pigmments, 71, 130 (2006); https://doi.org/10.1016/j.dyepig.2005.06.017.
- R.M. El-Shishtawy and S.H. Nassar, Color. Technol., 118, 115 (2002); https://doi.org/10.1111/j.1478-4408.2002.tb00367.x.
- S. Mahmud, M.A. Habib, M.N. Pervez and A. Islam, Am. J. Polym. Sci. Eng., 3, 119 (2015).
- D.C. Patel, Synthetic Binders for Pigment Printing, Pigment Printing Handbook, pp. 63-95 (1995).
- M. Iqbal, J. Mughal, M. Sohail, A. Moiz, K. Ahmed and K. Ahmed, J. Anal. Sci. Meth. Instrum., 2, 87 (2012); https://doi.org/10.4236/jasmi.2012.22016.
- C.Y. Kan, X.Z. Kong, Q. Yuan and D.S. Liu, J. Appl. Polym. Sci., 80, 2251 (2001); https://doi.org/10.1002/app.1329.
- Y. Meng, Z. Weng, G. Shan, Z. Huang and Z. Pan, Acta Polym. Sinica, 367 (2004).
- J. Zhao, H.-S. Chen and Z.-Y. Hu, China Adhes., 3, 018 (2011).
- N. Ibrahim, M.R. El-Zairy, S. Zaky and H.A. Borham, Polymer Plast. Technol. Eng., 44, 111 (2005); https://doi.org/10.1081/PTE-200046103.
- A. Johnson, The Theory of Coloration of Textiles, Society of Dyers and Colourists, Bradford (1989).
- V.A. Shenai, Chemistry of Textile Auxiliaries, Sevak Publications (1976).
- H.B. Yamak, in ed.: F. Yilmaz, Emulsion Polymerization: Effects of Polymerization Variables on the Properties of Vinyl Acetate Based Emulsion Polymers, In: Polymer Science, Intech Open Access Publisher, Chap. 2, (2013); https://doi.org/10.5772/51498.
- A. Khan and M.N. Pervez, Int. J. Text. Sci., 4, 53 (2015); https://doi.org/10.5923/j.textile.20150403.01.
- M.N. Pervez, A. Khan and I.A. Khan, Am. J. Polym. Sci. Eng, 3, 90 (2015).
- M.N. Pervez and M.A. Rahman, Int. J. Sci. Eng. Res., 6, 19 (2015).
- P. Zhang and Q. Heng, Adv. Mater. Res., 557-559, 1588 (2012); https://doi.org/10.4028/www.scientific.net/AMR.557-559.1588.
- L. Chen and F. Wu, J. Wuhan Univ. Technol.-Mater. Sci. Ed., 27, 134 (2012); https://doi.org/10.1007/s11595-012-0423-5.
References
S.R. Karmakar, Chemical Technology in the Pre-treatment Processes of Textiles, Elsevier, p. 12 (1999).
R. Eisenlohr and V. Giesen, Inter. Dyer., 12, 180 (1995).
M. Galgali, Colourant, 45, 20 (1998).
M. El-Molla, Dyes Pigmments, 74, 371 (2007); https://doi.org/10.1016/j.dyepig.2006.02.021.
S. Bahmani, G. East and I. Holme, Color. Technol., 116, 94 (2000); https://doi.org/10.1111/j.1478-4408.2000.tb00027.x.
M. El-Molla and R. Schneider, Dyes Pigmments, 71, 130 (2006); https://doi.org/10.1016/j.dyepig.2005.06.017.
R.M. El-Shishtawy and S.H. Nassar, Color. Technol., 118, 115 (2002); https://doi.org/10.1111/j.1478-4408.2002.tb00367.x.
S. Mahmud, M.A. Habib, M.N. Pervez and A. Islam, Am. J. Polym. Sci. Eng., 3, 119 (2015).
D.C. Patel, Synthetic Binders for Pigment Printing, Pigment Printing Handbook, pp. 63-95 (1995).
M. Iqbal, J. Mughal, M. Sohail, A. Moiz, K. Ahmed and K. Ahmed, J. Anal. Sci. Meth. Instrum., 2, 87 (2012); https://doi.org/10.4236/jasmi.2012.22016.
C.Y. Kan, X.Z. Kong, Q. Yuan and D.S. Liu, J. Appl. Polym. Sci., 80, 2251 (2001); https://doi.org/10.1002/app.1329.
Y. Meng, Z. Weng, G. Shan, Z. Huang and Z. Pan, Acta Polym. Sinica, 367 (2004).
J. Zhao, H.-S. Chen and Z.-Y. Hu, China Adhes., 3, 018 (2011).
N. Ibrahim, M.R. El-Zairy, S. Zaky and H.A. Borham, Polymer Plast. Technol. Eng., 44, 111 (2005); https://doi.org/10.1081/PTE-200046103.
A. Johnson, The Theory of Coloration of Textiles, Society of Dyers and Colourists, Bradford (1989).
V.A. Shenai, Chemistry of Textile Auxiliaries, Sevak Publications (1976).
H.B. Yamak, in ed.: F. Yilmaz, Emulsion Polymerization: Effects of Polymerization Variables on the Properties of Vinyl Acetate Based Emulsion Polymers, In: Polymer Science, Intech Open Access Publisher, Chap. 2, (2013); https://doi.org/10.5772/51498.
A. Khan and M.N. Pervez, Int. J. Text. Sci., 4, 53 (2015); https://doi.org/10.5923/j.textile.20150403.01.
M.N. Pervez, A. Khan and I.A. Khan, Am. J. Polym. Sci. Eng, 3, 90 (2015).
M.N. Pervez and M.A. Rahman, Int. J. Sci. Eng. Res., 6, 19 (2015).
P. Zhang and Q. Heng, Adv. Mater. Res., 557-559, 1588 (2012); https://doi.org/10.4028/www.scientific.net/AMR.557-559.1588.
L. Chen and F. Wu, J. Wuhan Univ. Technol.-Mater. Sci. Ed., 27, 134 (2012); https://doi.org/10.1007/s11595-012-0423-5.