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Vol. 17 No. 2 (2005): Vol 17 Issue 2

Effect of Ring Size on PFC Oxidation of Alicyclic Ketoximes – A Kinetic Study

T.S. Jani Bai
Post Graduate and Research Department of Chemistry, Seethalakshmi Ramaswami College (Autonomous), Trichirapalli-620 002, India
R. Subbalakshmi
Post Graduate and Research Department of Chemistry, Seethalakshmi Ramaswami College (Autonomous), Trichirapalli-620 002, India
V. Usha
Post Graduate and Research Department of Chemistry, Seethalakshmi Ramaswami College (Autonomous), Trichirapalli-620 002, India

Corresponding Author(s) : T.S. Jani Bai

jani18_src@yahoo.com

Asian Journal of Chemistry, Vol. 17 No. 2 (2005): Vol 17 Issue 2

Abstract

The oxidation of alicyclic oximes of cyclopentanone, cyclohexanone and cycloheptanone by pyridinium fluorochromate (PFC) has been studied. The reaction follows first order each in [PFC] and [Oxime]. The reactivity sequence observed is cyclohexanone oxime (CHexO) > cyclopentanone oxime (CPO) > cycloheptanone oxime (CHepO) which has been rationalized on the basis of I-strain.

Keywords

Kinetic Oxidation Alicyclic ketoximes
(1)
Jani Bai, T.; Subbalakshmi, R.; Usha, V. Effect of Ring Size on PFC Oxidation of Alicyclic Ketoximes &Ndash; A Kinetic Study. ajc 2016, 17, 1240-1244.
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