Kinetics and Mechanism of Ru(III) Catalyzed Oxidation of Cyclopentanol and Cyclohexanol by Chloramine-T in Perchloric Acid Medium
Corresponding Author(s) : R.A. Singh
rasinghtdc@rediffmail.com
Asian Journal of Chemistry,
Vol. 17 No. 3 (2005): Vol 17 Issue 3
Abstract
The kinetics of Ru(III) chloride catalysed oxidation of cyclopentanol and cyclohexanol by acidic solution of chloramine-T (CAT) has been investigated. The result indicates first order kinetics with respect to each of CAT, cycloalcohols, Ru(III) and (H+). Negligible effect of [Cl–] and ionic strength variations on reaction rate was observed. Insignificant effect of addition of p-toluene sulphonamide, a reduction product of CAT, was observed. A suitable mechanism consistent with kinetic results has been proposed.
Keywords
Kinetics
Ru(III)
Oxidation
Cyclopentanol
Cyclohexanol
Chloramine-T
Perchloric acid
Mishra, S., Singh, A., Verma, J., Srivastava, V., & Singh, R. (2016). Kinetics and Mechanism of Ru(III) Catalyzed Oxidation of Cyclopentanol and Cyclohexanol by Chloramine-T in Perchloric Acid Medium. Asian Journal of Chemistry, 17(3), 1415–1422. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/14117
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