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Vol. 17 No. 3 (2005): Vol 17 Issue 3

Kinetics and Mechanism of Ru(III) Catalyzed Oxidation of Cyclopentanol and Cyclohexanol by Chloramine-T in Perchloric Acid Medium

S.P. Mishra
Chemical Kinetics Research Laboratory, Department of Chemistry, T.D.P.G. College, Jaunpur-222 002, India
Anju Singh
Chemical Kinetics Research Laboratory, Department of Chemistry, T.D.P.G. College, Jaunpur-222 002, India
Jyoti Verma
Chemical Kinetics Research Laboratory, Department of Chemistry, T.D.P.G. College, Jaunpur-222 002, India
V.K. Srivastava
Chemical Kinetics Research Laboratory, Department of Chemistry, T.D.P.G. College, Jaunpur-222 002, India
R.A. Singh
Chemical Kinetics Research Laboratory, Department of Chemistry, T.D.P.G. College, Jaunpur-222 002, India

Corresponding Author(s) : R.A. Singh

rasinghtdc@rediffmail.com

Asian Journal of Chemistry, Vol. 17 No. 3 (2005): Vol 17 Issue 3

Abstract

The kinetics of Ru(III) chloride catalysed oxidation of cyclopentanol and cyclohexanol by acidic solution of chloramine-T (CAT) has been investigated. The result indicates first order kinetics with respect to each of CAT, cycloalcohols, Ru(III) and (H+). Negligible effect of [Cl–] and ionic strength variations on reaction rate was observed. Insignificant effect of addition of p-toluene sulphonamide, a reduction product of CAT, was observed. A suitable mechanism consistent with kinetic results has been proposed.

Keywords

Kinetics Ru(III) Oxidation Cyclopentanol Cyclohexanol Chloramine-T Perchloric acid
(1)
Mishra, S.; Singh, A.; Verma, J.; Srivastava, V.; Singh, R. Kinetics and Mechanism of Ru(III) Catalyzed Oxidation of Cyclopentanol and Cyclohexanol by Chloramine-T in Perchloric Acid Medium. ajc 2016, 17, 1415-1422.
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