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Vol. 29 No. 5 (2017): Vol 29 Issue 5

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Synthesis, TGA, Luminescent and Antifungal Activity Studies of Nickel(II) Complexes of 1,1-Dithiolate

https://doi.org/10.14233/ajchem.2017.20393
Mahesh K. Singh
Department of Chemistry, Tripura University, Suryamaninagar-799 022, India
Sanjit Sutradhar
Department of Chemistry, Tripura University, Suryamaninagar-799 022, India
Arijit Das
Department of Chemistry, Ramthakur College, Agartala-799 003, India
Sandeep Acharya
Department of Botany, R.K. Mahavidyalaya, Kailashahar-799277, India

Corresponding Author(s) : Mahesh K. Singh

mkchem.singh@gmail.com

Asian Journal of Chemistry, Vol. 29 No. 5 (2017): Vol 29 Issue 5

Abstract

Mixed ligand complexes of nickel(II) with 1,8-diaminonaphthalene (dan) and 1,1-dicyanoethylene-2,2-dithiolate (i-MNT2-) of the composition, Ni(dan)X(i-MNT)·yH2O [ x = 1, y = 2; x = 2, 3, y = 0] and Ni(dan)(i-MNT)L2.zH2O [ L = a-picoline (a-pic), b-picoline (b-pic), z = 0; L = g-picoline (g-pic), z = 2] have been synthesized and characterized by elemental analysis, molar conductance, magnetic susceptibility measurement, TGA, infrared, fluorescence and UV-visible spectral studies. The antifungal property of these complexes have also been studied using different fungi. IR spectral study suggest bidentate chelating behaviour of 1,8-diaminonaphthalene and 1,1-dicyanoethylene-2,2-dithiolate ion. The electronic spectral study suggests distorted octahedral stereochemistry around nickel(II) ion in these complexes.

Keywords

1,8-Diaminonaphthalene 1,1-Dicyanoethylene-2,2-dithiolate Mixed ligand complexes Nickel(II) TGA Luminescent Antifungal
Singh, M. K., Sutradhar, S., Das, A., & Acharya, S. (2017). Synthesis, TGA, Luminescent and Antifungal Activity Studies of Nickel(II) Complexes of 1,1-Dithiolate. Asian Journal of Chemistry, 29(5), 1023–1028. https://doi.org/10.14233/ajchem.2017.20393
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