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Adsorption-Desorption Behaviour of Boron in Soils of Assam
Corresponding Author(s) : Babita Tamuli
Asian Journal of Chemistry,
Vol. 29 No. 5 (2017): Vol 29 Issue 5
Abstract
Batch studies were conducted to investigate the adsorption and desorption behaviour of boron in four soils of Assam viz. entisol, inceptisol, alfisol and ultisol, which had wide variations in physico-chemical properties. The adsorption isotherms indicated that the adsorption of boron increased with its increasing concentration in the equilibrium solution. The Langmuir adsorption isotherm was curvilinear and it was significant when the curves were resolved into two linear parts. The maximum value of the adsorption maxima (b1) was observed to be 2.657 μg g-1 in ultisol and the bonding energy (k) constant was maximum at 2.073 mL μg-1 in inceptisol. The Langmuir isotherm best explains the adsorption phenomenon at low concentration of the adsorbent, which was different for different soils. There was significant correlation between b1 and organic carbon (r = 0.916**), clay content (r = 0.739*) and free Al2O3 (r = 0.791*) of the soils. A linear relationship was observed between log C and log x/m in all soils and at the whole concentration range from 0.1 to 10 μg B mL-1 which indicated that B adsorption data also conform to the Freundlich equation. Soils that had higher affinity for B adsorption (S4), tended to desorb less amount of B (37.92 %) and that had lower affinity for B adsorption (S3) showed greater desorption (53.78 %) of adsorbed B. Boron desorption by these soils showed a significant positive correlation with sand content (r = 0.801*) and significant negative correlation with organic carbon (r = –0.709*), CEC (r = –0.834**) and free Al2O3 (r = –0.785*) of the soils. The maximum value of desorption maxima (DmB) (56.497 μg g-1) and B mobility (KdB) (0.061 mL μg-1) was observed in ultisol (S4).
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- D.R. Chaudhary, L.M. Shukla and A. Gupta, Agric. Rev., 26, 288 (2005).
- U.C. Gupta, Y.W. Jame, C.A. Campbell, A.J. Leyshon and W. Nicholaichuk, Can. J. Soil Sci., 65, 381 (1985); https://doi.org/10.4141/cjss85-044.
- J.T. Hatcher and C.A. Bower, Soil Sci., 85, 319 (1958); https://doi.org/10.1097/00010694-195806000-00005.
- S. Arora and D.S. Chahal, Commun. Soil Sci. Plant Anal., 41, 2532 (2010); https://doi.org/10.1080/00103624.2010.514372.
- E. Okazaki and T.T. Chao, Soil Sci., 105, 255 (1968); https://doi.org/10.1097/00010694-196804000-00009.
- R.S. Bhatnagar, S.C. Attri, G.S. Mather and R.S. Chaudhary, Ann. Arid Zone, 18, 86 (1979).
- S. Goldberg and H.S. Forster, Soil Sci., 152, 304 (1991); https://doi.org/10.1097/00010694-199110000-00009.
- A.K. Mondal, B. Mandal and L.N. Mandal, Commun. Soil Sci. Plant Anal., 24, 2553 (1993); https://doi.org/10.1080/00103629309368977.
- S.P. Datta and P.B.S. Bhadoria, J. Plant Nutr. Soil Sci., 162, 183 (1999); https://doi.org/10.1002/(SICI)1522-2624(199903)162:2<183::AIDJPLN183>3.0.CO;2-A.
- S. Goldberg and R.A. Glaubig, Soil Sci. Soc. Am. J., 50, 1173 (1986); https://doi.org/10.2136/sssaj1986.03615995005000050016x.
- S. Arora and D.S. Chahal, Agropedol., 18, 44 (2007).
- S. Nazir and M.S. Wani, Commun. Soil Sci. Plant Anal., 46, 683 (2015); https://doi.org/10.1080/00103624.2014.1003936.
- D. Bhattacharyya, Int. J. Trop. Agric., 9, 1 (1991).
- M.L. Jackson, Soil Chemical Analysis, Prentice Hall of India Pvt. Ltd., New Delhi (1973).
- C.S. Piper, Soil and Plant Analysis, Hans Publishers, Bombay, pp. 368 (1966).
- H.D. Chapman, in ed.: C.A. Black, Cation-Exchange Capacity, In: Methods of Soil Analysis-Chemical and Microbiological Properties. American Society of Agronomy, vol. 9, p. 891 (1965).
- G.S.R. Krishna Murti, A.V. Moharir and V.A.K. Sarma, Microchem. J., 15, 585 (1970); https://doi.org/10.1016/0026-265X(70)90101-3.
- G.S.R. Krishnamurthy, V.A.K. Sarma and P. Rengasamy, Indian J. Technol., 12, 270 (1974).
- B. Wolf, Commun. Soil Sci. Plant Anal., 5, 39 (1974); https://doi.org/10.1080/00103627409366478.
- K.N. Sharma, H. Singh and A.C. Vig, Fert. Res., 40, 121 (1995); https://doi.org/10.1007/BF00750096.
- J. Sarkar and B. Das, Ann. Agric. Res., 12, 322 (1991).
- R. Sakal, S.P. Singh, A.P. Singh and N.S. Bhogal, Ann. Agric. Res., 15, 14 (1994).
- M.A. Elrashidi and G.A. O’Connor, Soil Sci. Soc. Am. J., 46, 27 (1982); https://doi.org/10.2136/sssaj1982.03615995004600010005x.
- R.N. Singh, H. Sinha and H.K. Roy, Ann. Agric. Res., 8, 252 (1987).
- B. Dekamedhi, M.N. Das and D.N. Medhi, J. Indian Soc. Soil Sci., 46, 691 (1998).
- K. Borkakti, Ph.D Thesis, Adsorption, Movement and Forms of Occurrence of Boron in Major Soil Groups of Assam, Punjab Agricultural University, Ludhiana, India (1988).
- M. Singh, Geoderma, 5, 209 (1971); https://doi.org/10.1016/0016-7061(71)90010-3.
- R. Krishnasamy, J. Jaisankar and M. Suresh, in eds.: R.W. Bell and B. Rerkasem, Characterization of Boron Adsorption in Soils of Tamil Nadu, India, In: Boron in Soils and Plants, Kluwer Academic Publishers: Dordrecht, Netherlands, p. 255 (1997).
- J.K. Saha and M.V. Singh, J. Indian Soc. Soil Sci., 45, 271 (1997).
- J. Garcia-Miragaya and A.L. Page, Water Air Soil Pollut., 9, 289 (1978); https://doi.org/10.1007/BF00280677.
- J. Garcia-Miragaya, Commun. Soil Sci. Sci. Plant Anal., 11, 1157 (1980); https://doi.org/10.1080/00103628009367112.
References
D.R. Chaudhary, L.M. Shukla and A. Gupta, Agric. Rev., 26, 288 (2005).
U.C. Gupta, Y.W. Jame, C.A. Campbell, A.J. Leyshon and W. Nicholaichuk, Can. J. Soil Sci., 65, 381 (1985); https://doi.org/10.4141/cjss85-044.
J.T. Hatcher and C.A. Bower, Soil Sci., 85, 319 (1958); https://doi.org/10.1097/00010694-195806000-00005.
S. Arora and D.S. Chahal, Commun. Soil Sci. Plant Anal., 41, 2532 (2010); https://doi.org/10.1080/00103624.2010.514372.
E. Okazaki and T.T. Chao, Soil Sci., 105, 255 (1968); https://doi.org/10.1097/00010694-196804000-00009.
R.S. Bhatnagar, S.C. Attri, G.S. Mather and R.S. Chaudhary, Ann. Arid Zone, 18, 86 (1979).
S. Goldberg and H.S. Forster, Soil Sci., 152, 304 (1991); https://doi.org/10.1097/00010694-199110000-00009.
A.K. Mondal, B. Mandal and L.N. Mandal, Commun. Soil Sci. Plant Anal., 24, 2553 (1993); https://doi.org/10.1080/00103629309368977.
S.P. Datta and P.B.S. Bhadoria, J. Plant Nutr. Soil Sci., 162, 183 (1999); https://doi.org/10.1002/(SICI)1522-2624(199903)162:2<183::AIDJPLN183>3.0.CO;2-A.
S. Goldberg and R.A. Glaubig, Soil Sci. Soc. Am. J., 50, 1173 (1986); https://doi.org/10.2136/sssaj1986.03615995005000050016x.
S. Arora and D.S. Chahal, Agropedol., 18, 44 (2007).
S. Nazir and M.S. Wani, Commun. Soil Sci. Plant Anal., 46, 683 (2015); https://doi.org/10.1080/00103624.2014.1003936.
D. Bhattacharyya, Int. J. Trop. Agric., 9, 1 (1991).
M.L. Jackson, Soil Chemical Analysis, Prentice Hall of India Pvt. Ltd., New Delhi (1973).
C.S. Piper, Soil and Plant Analysis, Hans Publishers, Bombay, pp. 368 (1966).
H.D. Chapman, in ed.: C.A. Black, Cation-Exchange Capacity, In: Methods of Soil Analysis-Chemical and Microbiological Properties. American Society of Agronomy, vol. 9, p. 891 (1965).
G.S.R. Krishna Murti, A.V. Moharir and V.A.K. Sarma, Microchem. J., 15, 585 (1970); https://doi.org/10.1016/0026-265X(70)90101-3.
G.S.R. Krishnamurthy, V.A.K. Sarma and P. Rengasamy, Indian J. Technol., 12, 270 (1974).
B. Wolf, Commun. Soil Sci. Plant Anal., 5, 39 (1974); https://doi.org/10.1080/00103627409366478.
K.N. Sharma, H. Singh and A.C. Vig, Fert. Res., 40, 121 (1995); https://doi.org/10.1007/BF00750096.
J. Sarkar and B. Das, Ann. Agric. Res., 12, 322 (1991).
R. Sakal, S.P. Singh, A.P. Singh and N.S. Bhogal, Ann. Agric. Res., 15, 14 (1994).
M.A. Elrashidi and G.A. O’Connor, Soil Sci. Soc. Am. J., 46, 27 (1982); https://doi.org/10.2136/sssaj1982.03615995004600010005x.
R.N. Singh, H. Sinha and H.K. Roy, Ann. Agric. Res., 8, 252 (1987).
B. Dekamedhi, M.N. Das and D.N. Medhi, J. Indian Soc. Soil Sci., 46, 691 (1998).
K. Borkakti, Ph.D Thesis, Adsorption, Movement and Forms of Occurrence of Boron in Major Soil Groups of Assam, Punjab Agricultural University, Ludhiana, India (1988).
M. Singh, Geoderma, 5, 209 (1971); https://doi.org/10.1016/0016-7061(71)90010-3.
R. Krishnasamy, J. Jaisankar and M. Suresh, in eds.: R.W. Bell and B. Rerkasem, Characterization of Boron Adsorption in Soils of Tamil Nadu, India, In: Boron in Soils and Plants, Kluwer Academic Publishers: Dordrecht, Netherlands, p. 255 (1997).
J.K. Saha and M.V. Singh, J. Indian Soc. Soil Sci., 45, 271 (1997).
J. Garcia-Miragaya and A.L. Page, Water Air Soil Pollut., 9, 289 (1978); https://doi.org/10.1007/BF00280677.
J. Garcia-Miragaya, Commun. Soil Sci. Sci. Plant Anal., 11, 1157 (1980); https://doi.org/10.1080/00103628009367112.