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Vol. 29 No. 5 (2017): Vol 29 Issue 5

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Synthesis and Spectroscopic Characterization of Ruthenium Polypyridyl Complexes Containing 1,6-bis(Benzylidene)hexanediamine as Ligand

https://doi.org/10.14233/ajchem.2017.20351
Archana Choubey
Department of Chemistry, Sagar Institute of Science Technology & Research, Sikandrabad, Ratibad, Bhopal-462 044, India
Satyendra N. Shukla
Coordination Chemistry Research Lab, Department of Chemistry, Government Model Science College, Jabalpur-482 001, India
Pratiksha Gaur
Coordination Chemistry Research Lab, Department of Chemistry, Government Model Science College, Jabalpur-482 001, India
Chetna Acharya
Department of Chemistry, Sagar Institute of Science Technology & Research, Sikandrabad, Ratibad, Bhopal-462 044, India

Corresponding Author(s) : Archana Choubey

choubey.a64@gmail.com

Asian Journal of Chemistry, Vol. 29 No. 5 (2017): Vol 29 Issue 5

Abstract

A novel bidentate ligand 1,6-bis(benzylidene)hexanediamine was synthesized and its eight ruthenium bis(bypyridine)sulphoxide complexes with the general formula [cis/trans-RuCl2(SO)2(N-N)](L); were SO = dimethyl sulphoxide (DMSO)/tetramethylene sulphoxide (TMSO), (N-N) = 1,10-phenanthroline/2,2'-bipyridyl, (L) = bridging ligand were synthesized. These complexes were characterized by elemental analysis, IR, UV/visible, 1H NMR, 13C NMR and 2D NMR spectroscopy. All complexes were found to show antibacterial property against E. coli and the pyridal ligands co-ordinate through a Ru–N bond in all cases.

Keywords

Ruthenium bypyridine Hexanediamine Sulphoxide Phenanthroline
Choubey, A., Shukla, S. N., Gaur, P., & Acharya, C. (2017). Synthesis and Spectroscopic Characterization of Ruthenium Polypyridyl Complexes Containing 1,6-bis(Benzylidene)hexanediamine as Ligand. Asian Journal of Chemistry, 29(5), 975–982. https://doi.org/10.14233/ajchem.2017.20351
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