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Vol. 31 No. 12 (2019): Vol 31 Issue 12

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Thermoacoustic Parameters Determination of Intermolecular Free-Length of 1-Butyl-2,3-dimethylimidazolium Chloride in Mixed Solvents at T = (298.15 to 313.15) K

https://doi.org/10.14233/ajchem.2019.22124
Sailaja Muchipali
Department of Chemistry, Veer Surendra Sai University of Technology, Burla-768018, India
Ranjan Kumar Pradhan
P.G. Department of Chemistry, Vikram Deb Autonomous College, Jeypore-764001, India
Priyaranjan Mohapatra
Department of Chemistry, Veer Surendra Sai University of Technology, Burla-768018, India
Braja B. Nanda
P.G. Department of Chemistry, Vikram Deb Autonomous College, Jeypore-764001, India

Corresponding Author(s) : Priyaranjan Mohapatra

priya_chem@vssut.ac.in

Asian Journal of Chemistry, Vol. 31 No. 12 (2019): Vol 31 Issue 12

Abstract

The intermolecular free-length of 1-butyl-2,3-dimethylimidazolium chloride [bdmim]Cl in pure water as well as in tetra-n-butyl ammonium bromide (TBAB) + water at different concentrations of solute and at T = (298.15 to 313.15) K have been evaluated by making use of ultrasonic and thermoacoustical parameters followed by a comparative study. To accomplish this objective, thermoacoustical parameters for the above said solutions have been calculated. These parameters have been used to determine intermolecular free-length (Lf) for the solutions under study. The values of Lf obtained by thermoacoustical approach were tallied with the values obtained by well-known ultrasonic method (Schaaffs method). To the best of our understanding, this study is an innovative attempt in the determination of inter-molecular free-length present in the investigated solutions by making use of ultrasonic approach.

Keywords

Intermolecular free-length Thermoacoustical parameter 1-Butyl-2,3-dimethyl imidazolium chloride Schaffs method
Muchipali, S., Pradhan, R. K., Mohapatra, P., & Nanda, B. B. (2019). Thermoacoustic Parameters Determination of Intermolecular Free-Length of 1-Butyl-2,3-dimethylimidazolium Chloride in Mixed Solvents at T = (298.15 to 313.15) K. Asian Journal of Chemistry, 31(12), 2719–2724. https://doi.org/10.14233/ajchem.2019.22124
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