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Characterization and Magnetic Behaviour of Nanosized Binary Spinel Ferrites Synthesized by Low Temperature Hydrothermal Method and their Stability in Aqueous Suspensions
Corresponding Author(s) : V. Beula Shanthi Ammani Ammal
Asian Journal of Chemistry,
Vol. 29 No. 12 (2017): Vol 29 Issue 12
Abstract
Cobalt ferrite, nickel ferrite and zinc ferrite spinel oxides are synthesized by low temperature hydrothermal method using ethylenediamine tetracetic acid (EDTA) as complexing agent. FTIR and XRD studies show the formation of pure and single spinel phase. The average crystalline size was determined from X-ray diffraction line broadening using Scherrer equation. FE-SEM studies revealed that all the synthesized ferrites are having nearly octahedron crystals with an average particle size of 20 to 40 nm. Magnetic behavior of cobalt ferrite, nickel ferrite and zinc ferrite spinels studied by vibrating sample magnetometer at room temperature shows ferromagnetic behaviour of cobalt ferrite, super paramagnetic nature of nickel ferrite and non-magnetic behaviour of zinc ferrite. Zeta potential measured at various pH conditions shows that cobalt ferrite and nickel ferrite can be used for the preparation of magnetic nanofluids with stable colloidal dispersion at 4.5 > pH < 7.5 and 3.5 > pH < 9.5, respectively.
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References
M. Pardavi-Horvath, J. Magn. Magn. Mater., 215-216, 171 (2000); https://doi.org/10.1016/S0304-8853(00)00106-2.
N.A. Hill, J. Chem. Phys. B, 104, 6694 (2000); https://doi.org/10.1021/jp000114x.
J.E.W. Verwey, Nature, 144, 327 (1939); https://doi.org/10.1038/144327b0.
T. Goto, T. Kimura, G. Lawes, A.P. Ramirez and Y. Tokura, Phys. Rev. Lett., 92, 257201 (2004); https://doi.org/10.1103/PhysRevLett.92.257201.
M.H. Sousa, F.A. Tourinho, J. Depeyrot, G.H. da Silva and M.C.F.L. Lara, J. Phys. Chem. B, 105, 1168 (2001); https://doi.org/10.1021/jp0039161.
F.H. Chen, L.M. Zhang, Q.T. Chen, Y. Zhang and Z.J. Zhang, Chem. Commun., 46, 8633 (2010); https://doi.org/10.1039/c0cc02577a.
Z. Zi, Y. Sun, X. Zhu, Z. Yang, J. Dai and W. Song, J. Magn. Magn. Mater., 321, 1251 (2009); https://doi.org/10.1016/j.jmmm.2008.11.004.
C. Liu, A.J. Rondinone and Z.J. Zhang, Pure Appl. Chem., 72, 37 (2000); https://doi.org/10.1351/pac200072010037.
A.B. Rajput, S. Hazra and N.N. Ghosh, J. Exp. Nanosci., 8, 629 (2013); https://doi.org/10.1080/17458080.2011.582170.
H.T. Rahal, R. Awad, A.M. Abdel-Gaber and D. El-Said Bakeer, J. Nanomater., Article ID 7460323 (2017); https://doi.org/10.1155/2017/7460323.
M. Sheikholeslami, Eur. Phys. J. Plus, 131, 413 (2016); https://doi.org/10.1140/epjp/i2016-16413-y.
H. Xiang, Y. Mu, C. Hu and X. Luo, J. Nanomater., Article ID 5429063 (2017); https://doi.org/10.1155/2017/5429063.
X. Sun and S. Sun, Methods Mol. Biol., 1570, 73 (2017); https://doi.org/10.1007/978-1-4939-6840-4_5.
H. Chang and H.-T. Su, Rev. Adv. Mater. Sci., 18, 667 (2008).
R. Patil, S. Kakatkar, A. Sanlepal and S. Sawant, J. Pure Appl. Phys., 2, 193 (1994).
N.J. Jebarathinam, M. Eswaramoorthy and V. Krishnasamy, Appl. Catal. A Gen., 145, 57 (1996); https://doi.org/10.1016/0926-860X(96)00149-4.
K. Nejati and R. Zabihi, Chem. Cent. J., 6, 394 (2012); https://doi.org/10.1186/1752-153X-6-23.
A.S. Eggeman,A.K. Petford-Long, P.J. Dobson, J. Wiggins, T. Bromwich, R. Dunin-Borkowski and T. Kasama, J. Magn. Magn. Mater., 301, 336 (2006); https://doi.org/10.1016/j.jmmm.2005.07.022.
J.D. Byrne, T. Betancourt and L. Brannon-Peppas, Adv. Drug Deliv. Rev., 60, 1615 (2008); https://doi.org/10.1016/j.addr.2008.08.005.
Y. Obata, S. Tajima and S. Takeoka, J. Control. Rel.e, 142, 267 (2010); https://doi.org/10.1016/j.jconrel.2009.10.023.