Preparation of Heterotricyclic Chlorides via Intramolecular Diels-Alder Reaction of Furans
Corresponding Author(s) : AYDIN DEMIRCAN
ademircan@nigde.edu.tr ademircan@gmail.com; a_demircan@hotmail.com
Asian Journal of Chemistry,
Vol. 19 No. 4 (2007): Vol 19 Issue 4
Abstract
A variety of key precursors to the intramolecular Diels-Alder (IMDA) reaction of furan diene have been prepared via facile alkylation. Subsequently, rigid heterotricyclic chlorides 5a-e possessing oxygen, nitrogen and sulfur have been synthesized by employing a thermal IMDA reactions. Use of bulky protecting group on nitrogen 5a-b, such as t-butoxy group, can be utilized to encourage cycloaddition reactions that otherwise does not proceed.
Keywords
Intramolecular Diels-Alder
Cycloaddition
Furfurylchloroalkenes
KARAARSLAN, M., & DEMIRCAN, A. (2010). Preparation of Heterotricyclic Chlorides via Intramolecular Diels-Alder Reaction of Furans. Asian Journal of Chemistry, 19(4), 2999–3006. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/13410
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