Copyright (c) 2017 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Preparation and Comparison of Magnetic Nanoparticles and Magnetic Nanoparticles Doped with Cobalt for Photodegradation of Methyl Orange
Corresponding Author(s) : Eman Alzahrani
Asian Journal of Chemistry,
Vol. 29 No. 12 (2017): Vol 29 Issue 12
Abstract
This paper describes a study in which magnetic nanoparticles were fabricated via co-precipitation approach. These nanoparticles were then coated with cobalt as a means of enhancing their photocatalytic activity. A variety of different instruments were used to characterize the magnetic nanoparticles including transmission electron microscopy, X-ray diffraction analysis, and scanning electron microscope. They were then tested to determine the extent to which they could effectively degrade harmful dyes in the form of was methyl orange under UV lamp irradiation (365 nm). The performance of standard magnetic nanoparticles was compared with those coated with cobalt in terms of removal of methyl orange to determine the extent to which Co-doped magnetic nanoparticles can more effectively facilitate the photocatalytic degradation of methyl orange in comparison to standard magnetic nanoparticles.
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- E. Gurr, Synthetic Dyes in Biology, Medicine and Chemistry, Elsevier (2012).
- Shahid-ul-Islam and F. Mohammad, Ind. Eng. Chem. Res., 54, 3727 (2015); https://doi.org/10.1021/acs.iecr.5b00524.
- X. Zhang, F. Wu and N. Deng, J. Hazard. Mater., 185, 117 (2011); https://doi.org/10.1016/j.jhazmat.2010.09.005.
- M.B. Hasan, Master of Science Thesis, Adsorption of Reactive Azo Dyes on Chitosan/Oil Palm Ash Composite Adsorbent: Batch and Continuous Studies, Universiti Sains Malaysia (2008).
- I. Tan, A. Ahmad and B. Hameed, J. Hazard. Mater., 153, 709 (2008); https://doi.org/10.1016/j.jhazmat.2007.09.014.
- I. Tan,A.L. Ahmad and B. Hameed, J. Hazard. Mater., 154, 337 (2008); https://doi.org/10.1016/j.jhazmat.2007.10.031.
- R. Gong, Y. Sun, J. Chen, H. Liu and C. Yang, Dyes Pigments, 67, 175 (2005); https://doi.org/10.1016/j.dyepig.2004.12.003.
- C. Namasivayam and D. Kavitha, Dyes Pigments, 54, 47 (2014); https://doi.org/10.1016/S0143-7208(02)00025-6.
- F. Shakeel, N. Haq, F.K. Alanazi and I.A. Alsarra, Ind. Eng. Chem. Res., 53, 1179 (2013); https://doi.org/10.1021/ie403271t.
- A.K. Verma, R.R. Dash and P. Bhunia, J. Environ. Manage., 93, 154 (2012); https://doi.org/10.1016/j.jenvman.2011.09.012.
- H. Kim, S. Lee, S. Ryu and H.T. Choi, Appl. Biochem. Biotechnol., 166, 159 (2012); https://doi.org/10.1007/s12010-011-9412-y.
- Y. Patel and A. Gupte, Water Environ. Res., 87, 242 (2015); https://doi.org/10.2175/106143015X14212658613190.
- S. Mondal, Environ. Eng. Sci., 25, 383 (2008); https://doi.org/10.1089/ees.2007.0049.
- G. Crini, Bioresour. Technol., 97, 1061 (2006); https://doi.org/10.1016/j.biortech.2005.05.001.
- S. Khattri and M. Singh, J. Hazard. Mater., 167, 1089 (2009); https://doi.org/10.1016/j.jhazmat.2009.01.101.
- A. Srinivasan and T. Viraraghavan, J. Environ. Manage., 91, 1915 (2010); https://doi.org/10.1016/j.jenvman.2010.05.003.
- A. Mittal, V. Thakur, J. Mittal and H. Vardhan, Desalination Water Treat., 52, 227 (2014); https://doi.org/10.1080/19443994.2013.785030.
- U. Rott, J. Environ. Sci. Health A, 38, 1629 (2003); https://doi.org/10.1081/ESE-120021485.
- Z. Houshyar, A.B. Khoshfetrat and E. Fatehifar, Chem. Eng. J., 191, 59 (2012); https://doi.org/10.1016/j.cej.2012.02.053.
- D. Ghernaout, C. Benblidia and F. Khemici, Desalination Water Treat., 54, 3328 (2014); https://doi.org/10.1080/19443994.2014.90774.
- A. Maljaei, M. Arami and N.M. Mahmoodi, Desalination, 249, 1074 (2009); https://doi.org/10.1016/j.desal.2009.05.016.
- A. Aouni, C. Fersi, M. Ben Sik Ali and M. Dhahbi, J. Hazard. Mater., 168, 868 (2009); https://doi.org/10.1016/j.jhazmat.2009.02.112.
- M. Rafatullah, O. Sulaiman, R. Hashim and A. Ahmad, J. Hazard. Mater., 177, 70 (2010); https://doi.org/10.1016/j.jhazmat.2009.12.047.
- M. Purkait, A. Maiti, S. DasGupta and S. De, J. Hazard. Mater., 145, 287 (2007); https://doi.org/10.1016/j.jhazmat.2006.11.021.
- P. Malik, J. Hazard. Mater., 113, 81 (2004); https://doi.org/10.1016/j.jhazmat.2004.05.022.
- V. Gupta, B. Gupta, A. Rastogi, S. Agarwal and A. Nayak, J. Hazard. Mater., 186, 891 (2011); https://doi.org/10.1016/j.jhazmat.2010.11.091.
- A. Ahmad, A. Idris and B. Hameed, Desalination Water Treat., 52, 248 (2014); https://doi.org/10.1080/19443994.2013.794012.
- W. Chu, Water Res., 35, 3147 (2001); https://doi.org/10.1016/S0043-1354(01)00015-X.
- T. Robinson, G. McMullan, R. Marchant and P. Nigam, Bioresour. Technol., 77, 247 (2001); https://doi.org/10.1016/S0960-8524(00)00080-8.
- V.K. Gupta, I. Ali, Suhas and D. Mohan, J. Colloid Interface Sci., 265, 257 (2003); https://doi.org/10.1016/S0021-9797(03)00467-3.
- X. Cai, B. Han, S. Deng, Y. Wang, C. Dong, Y. Wang and I. Djerdj, CrystEngComm, 16, 7761 (2014); https://doi.org/10.1039/C4CE00899E.
- Y. Li and G.A. Somorjai, Nano Lett., 10, 2289 (2010); https://doi.org/10.1021/nl101807g.
- Y. Zhang and C. Erkey, J. Supercrit. Fluids, 38, 252 (2006); https://doi.org/10.1016/j.supflu.2006.03.021.
- E. Alzahrani, World J. Nano Sci. Eng., 5, 10 (2015); https://doi.org/10.4236/wjnse.2015.51002.
- E. Alzahrani and K. Welham, Int. J. Basic Appl. Sci., 3, 392 (2014); https://doi.org/10.14419/ijbas.v3i4.3358.
- M. Wierucka and M. Biziuk, Trends Analyt. Chem., 59, 50 (2014); https://doi.org/10.1016/j.trac.2014.04.007.
- M.M. El-Hammadi and J.L. Arias, Expert Opin. Ther. Pat., 25, 691 (2015); https://doi.org/10.1517/13543776.2015.1028358.
- S. Majidi, F.Z. Sehrig, M. Samiei, M. Milani, E. Abbasi, K. Dadashzadeh and A. Akbarzadeh, Artif. Cells Nanomed. Biotechnol., Article ID 1014093 (2015); https://doi.org/10.3109/21691401.2015.1014093.
- C. Sun, J.S. Lee and M. Zhang, Adv. Drug Deliv. Rev., 60, 1252 (2008); https://doi.org/10.1016/j.addr.2008.03.018.
- V.I. Shubayev, T.R. Pisanic II and S. Jin, Adv. Drug Deliv. Rev., 61, 467 (2009); https://doi.org/10.1016/j.addr.2009.03.007.
- E. Alzahrani, A. Sharfalddin and M. Alamodi, Adv. Nanoparticles, 4, 53 (2015); https://doi.org/10.4236/anp.2015.42007.
- E. Alzahrani, Int. J. Adv. Sci. Technical Res., 4, 755 (2014).
- W. Yantasee, C.L. Warner, T. Sangvanich, R.S. Addleman, T.G. Carter, R.J. Wiacek, G.E. Fryxell, C. Timchalk and M.G. Warner, Environ. Sci. Technol., 41, 5114 (2007); https://doi.org/10.1021/es0705238.
- Y. Cedeño-Mattei, O. Perales-Perez, M. Tomar, F. Roman, P. Voyles and W. Stratton, J. Appl. Phys., 103, 1 (2008); https://doi.org/10.1063/1.2838215.
- C. Yang, J. Xing, Y. Guan, J. Liu and H. Liu, J. Alloys Comp., 385, 283 (2004); https://doi.org/10.1016/j.jallcom.2004.03.137.
- D. Wang and D. Astruc, Chem. Rev., 114, 6949 (2014); https://doi.org/10.1021/cr500134h.
- A.H. Lu, E.L. Salabas and F. Schüth, Angew. Chem. Int. Ed., 46, 1222 (2007); https://doi.org/10.1002/anie.200602866.
- S. Laurent, D. Forge, M. Port, A. Roch, C. Robic, L. Vander Elst and R.N. Muller, Chem. Rev., 108, 2064 (2008); https://doi.org/10.1021/cr068445e.
- K. Woo, J. Hong, S. Choi, H.-W. Lee, J.-P. Ahn, C.S. Kim and S.W. Lee, Chem. Mater., 16, 2814 (2004); https://doi.org/10.1021/cm049552x.
- A.S. Teja and P.-Y. Koh, Prog. Cryst. Growth Charact. Mater., 55, 22 (2009); https://doi.org/10.1016/j.pcrysgrow.2008.08.003.
- M.H. Ramezanzadeh, M. Seifi, H. Hekmatara, Z. Zarnegar and M.H. Loghmani, Synth. React. Inorg. Met.-Org. Nano-Met. Chem., 45, 392 (2015); https://doi.org/10.1080/15533174.2013.790432.
- W. Wu, Q. He and C. Jiang, Nanoscale Res. Lett., 3, 397 (2008); https://doi.org/10.1007/s11671-008-9174-9.
- S. Mallakpour and M. Madani, Prog. Org. Coat., 86, 194 (2015); https://doi.org/10.1016/j.porgcoat.2015.05.023.
- A. Sclafani and J.-M. Herrmann, J. Photochem. Photobiol. Chem., 113, 181 (1998); https://doi.org/10.1016/S1010-6030(97)00319-5.
- M.J. Kale, T. Avanesian and P. Christopher, ACS Catal., 4, 116 (2014); https://doi.org/10.1021/cs400993w.
- E. Alzahrani, Am. J. Anal. Chem., 8, 95 (2017); https://doi.org/10.4236/ajac.2017.81008.
- X.C. Song, Y.F. Zheng and H.Y. Yin, J. Nanopart. Res., 15, 1 (2013).
- E. Alzahrani, Curr. Anal. Chem., 12, 465 (2016); https://doi.org/10.2174/1573412912666160104234348.
- A. Sharfalddin, E. Alzahrani and M. Alamoudi, Am. Chem. Sci. J, 13, 1 (2016); https://doi.org/10.9734/ACSJ/2016/23648.
- E. Alzahrani, Int. J. Anal. Chem., Article ID 797606 (2015); https://doi.org/10.1155/2015/797606.
- J. Fan, Y. Guo, J. Wang and M. Fan, J. Hazard. Mater., 166, 904 (2009); https://doi.org/10.1016/j.jhazmat.2008.11.091.
- A.A. Jalil, S. Triwahyono, S.H. Adam, N.D. Rahim, M.A.A. Aziz, N.H.H. Hairom, N.A.M. Razali, M.A. Abidin and M.K.A. Mohamadiah, J. Hazard. Mater., 181, 755 (2010); https://doi.org/10.1016/j.jhazmat.2010.05.078.
- M.C. Das, H. Xu, Z. Wang, G. Srinivas, W. Zhou, Y.-F. Yue, V.N. Nesterov, G. Qian and B. Chen, Chem. Commun., 47, 11715 (2011); https://doi.org/10.1039/c1cc12802g.
- R. Kumar, G. Kumar and A. Umar, Mater. Lett., 97, 100 (2013); https://doi.org/10.1016/j.matlet.2013.01.044.
- S. Al-Qaradawi and S.R. Salman, J. Photochem. Photobiol. Chem., 148, 161 (2002); https://doi.org/10.1016/S1010-6030(02)00086-2.
- I. Arabatzis, T. Stergiopoulos, M. Bernard, D. Labou, S. Neophytides and P. Falaras, Appl. Catal. B, 42, 187 (2003); https://doi.org/10.1016/S0926-3373(02)00233-3.
References
E. Gurr, Synthetic Dyes in Biology, Medicine and Chemistry, Elsevier (2012).
Shahid-ul-Islam and F. Mohammad, Ind. Eng. Chem. Res., 54, 3727 (2015); https://doi.org/10.1021/acs.iecr.5b00524.
X. Zhang, F. Wu and N. Deng, J. Hazard. Mater., 185, 117 (2011); https://doi.org/10.1016/j.jhazmat.2010.09.005.
M.B. Hasan, Master of Science Thesis, Adsorption of Reactive Azo Dyes on Chitosan/Oil Palm Ash Composite Adsorbent: Batch and Continuous Studies, Universiti Sains Malaysia (2008).
I. Tan, A. Ahmad and B. Hameed, J. Hazard. Mater., 153, 709 (2008); https://doi.org/10.1016/j.jhazmat.2007.09.014.
I. Tan,A.L. Ahmad and B. Hameed, J. Hazard. Mater., 154, 337 (2008); https://doi.org/10.1016/j.jhazmat.2007.10.031.
R. Gong, Y. Sun, J. Chen, H. Liu and C. Yang, Dyes Pigments, 67, 175 (2005); https://doi.org/10.1016/j.dyepig.2004.12.003.
C. Namasivayam and D. Kavitha, Dyes Pigments, 54, 47 (2014); https://doi.org/10.1016/S0143-7208(02)00025-6.
F. Shakeel, N. Haq, F.K. Alanazi and I.A. Alsarra, Ind. Eng. Chem. Res., 53, 1179 (2013); https://doi.org/10.1021/ie403271t.
A.K. Verma, R.R. Dash and P. Bhunia, J. Environ. Manage., 93, 154 (2012); https://doi.org/10.1016/j.jenvman.2011.09.012.
H. Kim, S. Lee, S. Ryu and H.T. Choi, Appl. Biochem. Biotechnol., 166, 159 (2012); https://doi.org/10.1007/s12010-011-9412-y.
Y. Patel and A. Gupte, Water Environ. Res., 87, 242 (2015); https://doi.org/10.2175/106143015X14212658613190.
S. Mondal, Environ. Eng. Sci., 25, 383 (2008); https://doi.org/10.1089/ees.2007.0049.
G. Crini, Bioresour. Technol., 97, 1061 (2006); https://doi.org/10.1016/j.biortech.2005.05.001.
S. Khattri and M. Singh, J. Hazard. Mater., 167, 1089 (2009); https://doi.org/10.1016/j.jhazmat.2009.01.101.
A. Srinivasan and T. Viraraghavan, J. Environ. Manage., 91, 1915 (2010); https://doi.org/10.1016/j.jenvman.2010.05.003.
A. Mittal, V. Thakur, J. Mittal and H. Vardhan, Desalination Water Treat., 52, 227 (2014); https://doi.org/10.1080/19443994.2013.785030.
U. Rott, J. Environ. Sci. Health A, 38, 1629 (2003); https://doi.org/10.1081/ESE-120021485.
Z. Houshyar, A.B. Khoshfetrat and E. Fatehifar, Chem. Eng. J., 191, 59 (2012); https://doi.org/10.1016/j.cej.2012.02.053.
D. Ghernaout, C. Benblidia and F. Khemici, Desalination Water Treat., 54, 3328 (2014); https://doi.org/10.1080/19443994.2014.90774.
A. Maljaei, M. Arami and N.M. Mahmoodi, Desalination, 249, 1074 (2009); https://doi.org/10.1016/j.desal.2009.05.016.
A. Aouni, C. Fersi, M. Ben Sik Ali and M. Dhahbi, J. Hazard. Mater., 168, 868 (2009); https://doi.org/10.1016/j.jhazmat.2009.02.112.
M. Rafatullah, O. Sulaiman, R. Hashim and A. Ahmad, J. Hazard. Mater., 177, 70 (2010); https://doi.org/10.1016/j.jhazmat.2009.12.047.
M. Purkait, A. Maiti, S. DasGupta and S. De, J. Hazard. Mater., 145, 287 (2007); https://doi.org/10.1016/j.jhazmat.2006.11.021.
P. Malik, J. Hazard. Mater., 113, 81 (2004); https://doi.org/10.1016/j.jhazmat.2004.05.022.
V. Gupta, B. Gupta, A. Rastogi, S. Agarwal and A. Nayak, J. Hazard. Mater., 186, 891 (2011); https://doi.org/10.1016/j.jhazmat.2010.11.091.
A. Ahmad, A. Idris and B. Hameed, Desalination Water Treat., 52, 248 (2014); https://doi.org/10.1080/19443994.2013.794012.
W. Chu, Water Res., 35, 3147 (2001); https://doi.org/10.1016/S0043-1354(01)00015-X.
T. Robinson, G. McMullan, R. Marchant and P. Nigam, Bioresour. Technol., 77, 247 (2001); https://doi.org/10.1016/S0960-8524(00)00080-8.
V.K. Gupta, I. Ali, Suhas and D. Mohan, J. Colloid Interface Sci., 265, 257 (2003); https://doi.org/10.1016/S0021-9797(03)00467-3.
X. Cai, B. Han, S. Deng, Y. Wang, C. Dong, Y. Wang and I. Djerdj, CrystEngComm, 16, 7761 (2014); https://doi.org/10.1039/C4CE00899E.
Y. Li and G.A. Somorjai, Nano Lett., 10, 2289 (2010); https://doi.org/10.1021/nl101807g.
Y. Zhang and C. Erkey, J. Supercrit. Fluids, 38, 252 (2006); https://doi.org/10.1016/j.supflu.2006.03.021.
E. Alzahrani, World J. Nano Sci. Eng., 5, 10 (2015); https://doi.org/10.4236/wjnse.2015.51002.
E. Alzahrani and K. Welham, Int. J. Basic Appl. Sci., 3, 392 (2014); https://doi.org/10.14419/ijbas.v3i4.3358.
M. Wierucka and M. Biziuk, Trends Analyt. Chem., 59, 50 (2014); https://doi.org/10.1016/j.trac.2014.04.007.
M.M. El-Hammadi and J.L. Arias, Expert Opin. Ther. Pat., 25, 691 (2015); https://doi.org/10.1517/13543776.2015.1028358.
S. Majidi, F.Z. Sehrig, M. Samiei, M. Milani, E. Abbasi, K. Dadashzadeh and A. Akbarzadeh, Artif. Cells Nanomed. Biotechnol., Article ID 1014093 (2015); https://doi.org/10.3109/21691401.2015.1014093.
C. Sun, J.S. Lee and M. Zhang, Adv. Drug Deliv. Rev., 60, 1252 (2008); https://doi.org/10.1016/j.addr.2008.03.018.
V.I. Shubayev, T.R. Pisanic II and S. Jin, Adv. Drug Deliv. Rev., 61, 467 (2009); https://doi.org/10.1016/j.addr.2009.03.007.
E. Alzahrani, A. Sharfalddin and M. Alamodi, Adv. Nanoparticles, 4, 53 (2015); https://doi.org/10.4236/anp.2015.42007.
E. Alzahrani, Int. J. Adv. Sci. Technical Res., 4, 755 (2014).
W. Yantasee, C.L. Warner, T. Sangvanich, R.S. Addleman, T.G. Carter, R.J. Wiacek, G.E. Fryxell, C. Timchalk and M.G. Warner, Environ. Sci. Technol., 41, 5114 (2007); https://doi.org/10.1021/es0705238.
Y. Cedeño-Mattei, O. Perales-Perez, M. Tomar, F. Roman, P. Voyles and W. Stratton, J. Appl. Phys., 103, 1 (2008); https://doi.org/10.1063/1.2838215.
C. Yang, J. Xing, Y. Guan, J. Liu and H. Liu, J. Alloys Comp., 385, 283 (2004); https://doi.org/10.1016/j.jallcom.2004.03.137.
D. Wang and D. Astruc, Chem. Rev., 114, 6949 (2014); https://doi.org/10.1021/cr500134h.
A.H. Lu, E.L. Salabas and F. Schüth, Angew. Chem. Int. Ed., 46, 1222 (2007); https://doi.org/10.1002/anie.200602866.
S. Laurent, D. Forge, M. Port, A. Roch, C. Robic, L. Vander Elst and R.N. Muller, Chem. Rev., 108, 2064 (2008); https://doi.org/10.1021/cr068445e.
K. Woo, J. Hong, S. Choi, H.-W. Lee, J.-P. Ahn, C.S. Kim and S.W. Lee, Chem. Mater., 16, 2814 (2004); https://doi.org/10.1021/cm049552x.
A.S. Teja and P.-Y. Koh, Prog. Cryst. Growth Charact. Mater., 55, 22 (2009); https://doi.org/10.1016/j.pcrysgrow.2008.08.003.
M.H. Ramezanzadeh, M. Seifi, H. Hekmatara, Z. Zarnegar and M.H. Loghmani, Synth. React. Inorg. Met.-Org. Nano-Met. Chem., 45, 392 (2015); https://doi.org/10.1080/15533174.2013.790432.
W. Wu, Q. He and C. Jiang, Nanoscale Res. Lett., 3, 397 (2008); https://doi.org/10.1007/s11671-008-9174-9.
S. Mallakpour and M. Madani, Prog. Org. Coat., 86, 194 (2015); https://doi.org/10.1016/j.porgcoat.2015.05.023.
A. Sclafani and J.-M. Herrmann, J. Photochem. Photobiol. Chem., 113, 181 (1998); https://doi.org/10.1016/S1010-6030(97)00319-5.
M.J. Kale, T. Avanesian and P. Christopher, ACS Catal., 4, 116 (2014); https://doi.org/10.1021/cs400993w.
E. Alzahrani, Am. J. Anal. Chem., 8, 95 (2017); https://doi.org/10.4236/ajac.2017.81008.
X.C. Song, Y.F. Zheng and H.Y. Yin, J. Nanopart. Res., 15, 1 (2013).
E. Alzahrani, Curr. Anal. Chem., 12, 465 (2016); https://doi.org/10.2174/1573412912666160104234348.
A. Sharfalddin, E. Alzahrani and M. Alamoudi, Am. Chem. Sci. J, 13, 1 (2016); https://doi.org/10.9734/ACSJ/2016/23648.
E. Alzahrani, Int. J. Anal. Chem., Article ID 797606 (2015); https://doi.org/10.1155/2015/797606.
J. Fan, Y. Guo, J. Wang and M. Fan, J. Hazard. Mater., 166, 904 (2009); https://doi.org/10.1016/j.jhazmat.2008.11.091.
A.A. Jalil, S. Triwahyono, S.H. Adam, N.D. Rahim, M.A.A. Aziz, N.H.H. Hairom, N.A.M. Razali, M.A. Abidin and M.K.A. Mohamadiah, J. Hazard. Mater., 181, 755 (2010); https://doi.org/10.1016/j.jhazmat.2010.05.078.
M.C. Das, H. Xu, Z. Wang, G. Srinivas, W. Zhou, Y.-F. Yue, V.N. Nesterov, G. Qian and B. Chen, Chem. Commun., 47, 11715 (2011); https://doi.org/10.1039/c1cc12802g.
R. Kumar, G. Kumar and A. Umar, Mater. Lett., 97, 100 (2013); https://doi.org/10.1016/j.matlet.2013.01.044.
S. Al-Qaradawi and S.R. Salman, J. Photochem. Photobiol. Chem., 148, 161 (2002); https://doi.org/10.1016/S1010-6030(02)00086-2.
I. Arabatzis, T. Stergiopoulos, M. Bernard, D. Labou, S. Neophytides and P. Falaras, Appl. Catal. B, 42, 187 (2003); https://doi.org/10.1016/S0926-3373(02)00233-3.