Effectiveness of Ceric Naphthalene Sulfonate on Controlled Indirect Electrooxidation of Aromatic Side Chain at Platinum
Corresponding Author(s) : D. ABIRAMI
abbi_aroma@yahoo.co.in
Asian Journal of Chemistry,
Vol. 19 No. 5 (2007): Vol 19 Issue 5
Abstract
The effect of complexation of Ce(IV) as ceric naphthalene sulfonate, on the oxidation of side chain in hydroxy-, amino- and nitro-toluenes at platinum electrode is explored. Partial oxidation due to complexation could be achieved. The products, characterized by IR and PMR, are identified to be aldehydes in acidic range and dimer in the alkaline medium. Mechanisms for these anodic conversions are proposed.
Keywords
Electrooxidation
Toluenes
Ce(IV)
ABIRAMI, D., & KRISHNAMOORTHY, T. (2010). Effectiveness of Ceric Naphthalene Sulfonate on Controlled Indirect Electrooxidation of Aromatic Side Chain at Platinum. Asian Journal of Chemistry, 19(5), 3549–3553. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/13245
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