Studies of Some Model Experiments with Simple Cyclopentadienone
Corresponding Author(s) : A. LARKEM
larkem_a@yahoo.fr
Asian Journal of Chemistry,
Vol. 19 No. 7 (2007): Vol 19 Issue 7
Abstract
Diels-Alder cycloaddition of hemicyclone (5) to fumarylchloride, dimethyl fumarate and fumaronitrite was carried out and thermal decarboxylation of the resulting carboxnyl-bridged adducts (7), (13) was studied of these only 8 lost carbon monoxide to give the cyclohexa-1,3-diene product. The diene-diester (9) was hydrolyzed to the diacid (10) but attempts to cycloadd dimethyl acetylenedicarboxylate to 11 failed. During the course of this work a few Diels-Alder reactions of the cyclone (20) and (16) were also examined.
Keywords
Cyclopentadienone
Carbonyl-bridges
LARKEM, H., & LARKEM, A. (2010). Studies of Some Model Experiments with Simple Cyclopentadienone. Asian Journal of Chemistry, 19(7), 5443–5449. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/13152
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