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Isothermal Study on Removal of Methyl Red from Aqueous Solution Using Aloe vera Leaves Powder
Corresponding Author(s) : Sapna Sharma
Asian Journal of Chemistry,
Vol. 29 No. 12 (2017): Vol 29 Issue 12
Abstract
The potentiality of Aloe vera leaves powder (ALP) a low cost and eco-friendly adsorbent was characterized and investigated for the removal of methyl red dye from an aqueous solution using a green approach by the process of adsorption. The adsorption behaviour of the biosorbent was investigated by performing both kinetic and equilibrium isothermal studies in batch conditions at 34 ºC. Adsorption experiments were performed by changing different experimental parameters i.e., contact time, initial dye concentration, adsorbent dose, particle size and pH of the solution. The adsorption studies were best fitted with Langmuir isotherm and it gives monolayer adsorption capacity of 51.49 mg/g at pH 4.2 at 34 ºC. The correlation coefficient values indicate a moderate fit for monolayer Langmuir model (R2 = 0.99). The experimental and calculated values for amount of adsorbed dye per unit mass of sorbent (qe) for pseudo-second-order kinetic model were in good agreement as compared to that by pseudo first order kinetics. The structural characterization of Aloe vera leaves powder was performed by SEM, FTIR and by GC-MS.
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G.S. Gupta, S.P. Shukla, G. Prasad and V.N. Singh, Environ. Technol., 13, 925 (1992); https://doi.org/10.1080/09593339209385228.
E. Forgacs, T. Cserháti and G. Oros, Environ. Int., 30, 953 (2004); https://doi.org/10.1016/j.envint.2004.02.001.
P.K. Sinha, R.V. Amalraj and V. Krishnasamy, Radiochim. Acta, 65, 125 (1994); https://doi.org/10.1524/ract.1994.65.2.125.
A.F. Nechaev, V. Projaev and V.P. Kapranchik, Radioactive Waste Management and Environmental Remediation, Int. Conference, American Society of Mechanical Engineers, New York, p. 1145 (1995).
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S.M. Ghoreishi and R. Haghighi, Chem. Eng. J., 95, 163 (2003); https://doi.org/10.1016/S1385-8947(03)00100-1.
Z. Aksu, Process Biochem., 40, 997 (2005); https://doi.org/10.1016/j.procbio.2004.04.008.
A. Gurses, C. Dogar, M. Yalcin, M. Acikyildiz, R. Bayrak and S. Karaca, J. Hazard. Mater., 131, 217 (2006); https://doi.org/10.1016/j.jhazmat.2005.09.036.
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S.J.T. Pollard, G.D. Fowler, C.J. Sollars and R. Perry, Sci. Total Environ., 116, 31 (1992); https://doi.org/10.1016/0048-9697(92)90363-W.
A.J. Varma, S.V. Deshpande and J.F. Kennedy, Carbohydr. Polym., 55, 77 (2004); https://doi.org/10.1016/j.carbpol.2003.08.005.
Y.S. Ho and G. McKay, Process Biochem., 38, 1047 (2003); https://doi.org/10.1016/S0032-9592(02)00239-X.
V.K. Garg, M. Amita, R. Kumar and R. Gupta, Dyes Pigments, 63, 243 (2004); https://doi.org/10.1016/j.dyepig.2004.03.005.
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L.C. Morais, O.M. Freitas, E.P. Gonçalves, L.T. Vasconcelos and C.G. González Beça, Water Res., 33, 979 (1999); https://doi.org/10.1016/S0043-1354(98)00294-2.
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S. Aygün, S. Yenisoy-Karakas and I. Duman, Micropor. Mesopor. Mater., 66, 189 (2003); https://doi.org/10.1016/j.micromeso.2003.08.028.
K. Eshun and Q. He, Crit. Rev. Food Sci. Nutr., 44, 91 (2004); https://doi.org/10.1080/10408690490424694.
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A. Bozzi, C. Perrin, S. Austin and F.A. Vera, Food Chem., 103, 22 (2007); https://doi.org/10.1016/j.foodchem.2006.05.061.
M.Z. Haque, M.B. Islam, M.A. Jalil and M.Z. Shafique, IOSR J. Appl. Chem., 7, 36 (2014); https://doi.org/10.9790/5736-07613640.
G.R. Waller, S. Mangiafico and C.R. Ritchey, Proc. Okla. Acad. Sci., 58, 69 (1978).
A. Femenia, P. García-Pascual, S. Simal and C. Rosselló, Carbohydr. Polym., 51, 397 (2003); https://doi.org/10.1016/S0144-8617(02)00209-6.
J. Eastoe and J.S. Dalton, Adv. J. Colloid Interface Sci., 85, 103 (2000); https://doi.org/10.1016/S0001-8686(99)00017-2.
H. Freundlich, Z. Phys. Chem., 57U, 385 (1907); https://doi.org/10.1515/zpch-1907-5723.
V.J.P. Poots, G. McKay and J.J. Healy, J. Water Pollut. Contr., 50, 926 (1978).
S. Lagergren, K. Sven. Vetenskapsakad. Handl., 24, 1 (1898).
Y.S. Ho and G. McKay, Chem. Eng. J., 70, 115 (1998); https://doi.org/10.1016/S0923-0467(98)00076-1.
T. Santhi, S. Manonmani and T. Smitha, Chem. Eng. Res. Bull., 14, 11 (2010); https://doi.org/10.3329/cerb.v14i1.3767.
K. Boudouara, M. Ghelamallah and H.N. Khemliche, Adsorption of Methyl Red from Aqueous Solutions by Algerian Bentonite Clay, 2nd International Congress on Energy Efficiency and Energy Related Materials (ENEFM2014), Springer, Springer Proceedings in Energy, p. 203 (2014).
R. Zein, A.W. Astuti, D. Wahyuni and F. Furqani, Res. J. Pharm. Biol. Chem. Sci., 6, 86 (2015).
M. Rosemal, H.M. Haris and K. Sathasivam, Arch. Appl. Sci. Res., 2, 209 (2010).
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