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Vol. 29 No. 12 (2017): Vol 29 Issue 12

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Modification of Chaetoceros sp. Biomass with Silica-Magnetite Coating and Adsorption Studies towards Cu(II) Ions in Single and Binary System

https://doi.org/10.14233/ajchem.2017.20859
Buhani
Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Lampung, Jl. Soemantri Brojonegoro No. 1, Bandar Lampung, Indonesia
Musrifatun
Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Lampung, Jl. Soemantri Brojonegoro No. 1, Bandar Lampung, Indonesia
D.S. Pratama
Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Lampung, Jl. Soemantri Brojonegoro No. 1, Bandar Lampung, Indonesia
Suharso
Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Lampung, Jl. Soemantri Brojonegoro No. 1, Bandar Lampung, Indonesia
Rinawati
Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Lampung, Jl. Soemantri Brojonegoro No. 1, Bandar Lampung, Indonesia

Corresponding Author(s) : Buhani

buhani_s@yahoo.co.id

Asian Journal of Chemistry, Vol. 29 No. 12 (2017): Vol 29 Issue 12

Abstract

Adsorbent synthesis from Chaetoceros sp. biomass with silica-magnetite coating technique (ASMC) and without magnetite (ASC) has been performed through the sol-gel process. Both adsorbents were characterized by infrared spectrophotometer, X-Ray diffraction and scanning electron microscopy. The adsorption process of Cu(II) ions was performed in a single and binary systems using batch method. The adsorption data of Cu(II) ions on ASC and ASMC within a single system follows the pseudo kinetic model of order 2 with the adsorption rate of Cu(II) ions on ASMC faster than ASC. The adsorption isotherm model of Cu(II) ions on ASC and ASMC tend to follow Langmuir adsorption isotherm model with adsorption capacity of 57.77 and 105.91 mg g-1, respectively. The ASMC material is not selective for Cu(II) ions with the ion pairs such as Ni(II), Zn(II), Cd(II) and Pb(II) ions.

Keywords

Adsorption capacity Chaetoceros sp. Silica-magnetite coating Heavy metals
Buhani, ., Musrifatun, ., Pratama, D., Suharso, ., & Rinawati, . (2017). Modification of Chaetoceros sp. Biomass with Silica-Magnetite Coating and Adsorption Studies towards Cu(II) Ions in Single and Binary System. Asian Journal of Chemistry, 29(12), 2734–2738. https://doi.org/10.14233/ajchem.2017.20859
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References
  1. R. Davarnejad and P. Panahi, J. Ind. Eng. Chem., 33, 270 (2016); https://doi.org/10.1016/j.jiec.2015.10.013.
  2. M.A. Barakat, Arab. J. Chem., 4, 361 (2011); https://doi.org/10.1016/j.arabjc.2010.07.019.
  3. Y.G. Bermüdez, I.L.R. Rico, O.G. Bermüdez and E. Guibal, Chem. Eng. J., 166, 122 (2011); https://doi.org/10.1016/j.cej.2010.10.038.
  4. K. Vijayaraghavan, M. Sathishkumar and R. Balasubramanian, Desalination, 265, 54 (2011); https://doi.org/10.1016/j.desal.2010.07.030.
  5. M.M. Montazer-Rahmati, P. Rabbani, A. Abdolali and A.R. Keshtkar, J. Hazard. Mater., 185, 401 (2011); https://doi.org/10.1016/j.jhazmat.2010.09.047.
  6. P.O. Harris and G.J. Ramelow, Environ. Sci. Technol., 24, 220 (1990); https://doi.org/10.1021/es00072a011.
  7. F. Veglio, F. Beolchini and I. Toro,Ind. Eng. Chem. Res., 37, 1107 (1998); https://doi.org/10.1021/ie9704197.
  8. B. Volesky and Z.R. Holan, Biotechnol. Prog., 11, 235 (1995); https://doi.org/10.1021/bp00033a001.
  9. Buhani and Suharso, Asian J. Chem., 21, 3799 (2009).
  10. Buhani, Suharso and Z. Sembiring, Orient. J. Chem., 28, 271 (2012); https://doi.org/10.13005/ojc/280133.
  11. Buhani, Suharso and Sumadi, Asian J. Chem., 24, 133 (2012).
  12. C. Jeon, J. Ind. Eng. Chem., 17, 321 (2011); https://doi.org/10.1016/j.jiec.2011.02.033.
  13. Q. Peng, Y. Liu, G. Zeng, W. Xu, C. Yang and J. Zhang, J. Hazard. Mater., 177, 676 (2010); https://doi.org/10.1016/j.jhazmat.2009.12.084.
  14. M.F. Desimone, C. Hélary, G. Mosser, M.-M. Giraud-Guille, J. Livage and T. Coradin, J. Mater. Chem., 20, 666 (2010); https://doi.org/10.1039/B921572G.
  15. M.V. Tuttolomondo, G.S. Alvarez, M.F. Desimone and L.E. Diaz, J. Environ. Chem. Eng., 2, 131 (2014); https://doi.org/10.1016/j.jece.2013.12.003.
  16. W. Jiang, X. Chen, Y. Niu and B. Pan, J. Hazard. Mater., 243, 319 (2012); https://doi.org/10.1016/j.jhazmat.2012.10.036.
  17. S. Ghosh, A.Z.M. Badruddoza, K. Hidajat and M.S. Uddin, J. Environ. Chem. Eng., 1, 122 (2013); https://doi.org/10.1016/j.jece.2013.04.004.
  18. M.H.P. Wondracek, A.O. Jorgetto, A.C.P. Silva, J.R. Ivassechen, J.F. Schneider, M.J. Saeki, V.A. Pedrosa, W.K. Yoshito, F. Colauto, W.A. Ortiz and G.R. Castro, Appl. Surf. Sci., 367, 533 (2016); https://doi.org/10.1016/j.apsusc.2016.01.172.
  19. I. Mohmood, C.B. Lopes, I. Lopes, D.S. Tavares, A.M.V.M. Soares, A.C. Duarte, T. Trindade, I. Ahmad and E. Pereira, Sci. Total Environ., 557–558, 712 (2016); https://doi.org/10.1016/j.scitotenv.2016.03.075.
  20. Y. Ren, M. Zhang and D. Zhao, Desalination, 228, 135 (2008); https://doi.org/10.1016/j.desal.2007.08.013.
  21. J. Drbohlavova, R. Hrdy, V. Adam, R. Kizek, O. Schneeweiss and J. Hubalek, Sensors, 9, 2352 (2009); https://doi.org/10.3390/s90402352.
  22. S. Zakhama, H. Dhaouadi and F. M’Henn, Bioresour. Technol., 102, 786 (2011); https://doi.org/10.1016/j.biortech.2010.08.107.
  23. D. Bulgariu and L. Bulgariu, Bioresour. Technol., 103, 489 (2012); https://doi.org/10.1016/j.biortech.2011.10.016.
  24. Y. Xiong, J. Xu, W. Shan, Z. Lou, D. Fang, S. Zang and G. Han, Bioresour. Technol., 127, 464 (2013); https://doi.org/10.1016/j.biortech.2012.09.099.
  25. V.K. Gupta and A. Rastogi, J. Hazard. Mater., 152, 407 (2008); https://doi.org/10.1016/j.jhazmat.2007.07.028.
  26. Y. Lin, H. Chen, K. Lin, B. Chen and C. Chiou, J. Environ. Sci., 23, 44 (2011); https://doi.org/10.1016/S1001-0742(10)60371-3.
  27. Y.S. Ho, J.F. Porter and G. McKay, Water Air Soil Pollut., 141, 1 (2002); https://doi.org/10.1023/A:1021304828010.
  28. X. Xin, Q. Wei, J. Yang, L. Yan, R. Feng, G. Chen, B. Du and H. Li, Chem. Eng. J., 184, 132 (2012); https://doi.org/10.1016/j.cej.2012.01.016.
  29. I. Larraza, M. López-Gónzalez, T. Corrales and G. Marcelo, J. Colloid Interface Sci., 385, 24 (2012); https://doi.org/10.1016/j.jcis.2012.06.050.
  30. J.E. Huheey, E.A. Keiter and R.L. Keitler, Inorganic Chemistry: Principles of Structure as and Reactivity, Harper, Collins Collage Publisher, edn 4 (1993).
  31. Buhani, Narsito, Nuryono, E.S. Kunarti and Suharso, Desalin. Water Treat., 55, 1240 (2015); https://doi.org/10.1080/19443994.2014.924880.
  32. Buhani, Suharso and L. Aprilia, Indo. J. Chem., 12, 94 (2012).
  33. Buhani, Suharso and Z. Sembiring, Indo. J. Chem., 6, 245 (2006).
  34. Buhani, Rinawati, Suharso, D.P. Yuliasari and S.D. Yuwono, Desalin. Water Treat., 80, 203 (2017); https://doi.org/10.5004/dwt.2017.20932.
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