Copyright (c) 2017 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Synthesis of Polyaniline Based Nanocomposite Graphite Paste Electrode Modified with and Without Rice Husk for Sensor Application: A Comparative Study
Corresponding Author(s) : K.S. Paithankar
Asian Journal of Chemistry,
Vol. 29 No. 11 (2017): Vol 29 Issue 11
Abstract
Polyaniline based nanocomposite graphite paste electrode modified with rice husk (PANI/Gr/RH) and without rice husk (PANI/Grph) to compare the amperometric response caused by the addition of rice husk in conventional sensor. Organized materials were characterized by analytical techniques such as UV-visible, XRD and FE-SEM analyses. The performance of the developed sensor was evaluated and the obtained urea biosensor exhibited shorter response time (3 s), wider range 1 × 10-9 to 9 × 10-9 M and the detection limit were found to be 1 × 10-9. About 90 % of the enzyme activity is retained for about 40 days. Modified rice husk sensor gives better result than sensor without rice husk.
Keywords
Download Citation
Endnote/Zotero/Mendeley (RIS)BibTeX
- I. Svancara, K. Vytras, K. Kalcher, A. Walcarius and J. Wang, Electroanalysis, 21, 7 (2009); https://doi.org/10.1002/elan.200804340.
- N.S. Gadhari, B.J. Sanghavi and A.K. Srivastava, Anal. Chim. Acta, 703, 31 (2011); https://doi.org/10.1016/j.aca.2011.07.017.
- B. Lakard, G. Herlem, S. Lakard, A. Antoniou and B. Fahys, Biosens. Bioelectron., 19, 1641 (2004); https://doi.org/10.1016/j.bios.2003.12.035.
- A. Sehitogullari and A.H. Uslan, Talanta, 57, 1039 (2002); https://doi.org/10.1016/S0039-9140(02)00149-2.
- S.B. Adeloju, S.J. Shaw and G.G. Wallace, Anal. Chim. Acta, 281, 621 (1993); https://doi.org/10.1016/0003-2670(93)85023-D.
- A. Sassolas, B. Prieto-Simón and J.-L. Marty, Am. J. Anal. Chem., 3, 210 (2012); https://doi.org/10.4236/ajac.2012.33030.
- G.G. Guilbault and J.G. Montalvo, J. Am. Chem. Soc., 92, 2533 (1970); https://doi.org/10.1021/ja00711a052.
- E. Bakker and M.E. Meyerhoff, eds.: A.J. Bard, M. Stratmann and G.S. Wilson, Ion-Selective Electrodes for Measurements in Biological Fluids, In: Encyclopedia of Electrochemistry, Wiley-VCH, Weinheim, vol. 9 (2002).
- S. Uchiyama, M. Kobayashi and Y. Hasebe, Electroanalysis, 14, 1644 (2002); https://doi.org/10.1002/elan.200290005.
- R. Sahney, B.K. Puri and S. Anand, Anal. Chim. Acta, 542, 157 (2005); https://doi.org/10.1016/j.aca.2005.03.069.
- P. Bertocchi, D. Compagnone and G. Palleschi, Biosens. Bioelectron., 11, 1 (1996); https://doi.org/10.1016/0956-5663(96)83708-0.
- M. Senda and Y. Yamamoto, Electroanalysis, 5, 775 (1993); https://doi.org/10.1002/elan.1140050910.
- K. Yoneyama, Y. Fujino, T. Osaka and I. Satoh, Sens. Actuators B Chem., 76, 152 (2001); https://doi.org/10.1016/S0925-4005(01)00613-X.
- W.J. Cho and H.J. Huang, Anal. Chem., 70, 3946 (1998); https://doi.org/10.1021/ac980004a.
- V. Rajesh, W. Bisht, W. Takashima and K. Kaneto, Biomaterials, 26, 3683 (2005). https://doi.org/10.1016/j.biomaterials.2004.09.024.
- M. Trojanowicz, A. Lewenstam, T.K.V. Krawczyk, I. Lahdesmaki and W. Szczepek, Electroanalysis, 8, 233 (1996); https://doi.org/10.1002/elan.1140080307.
- P.C. Pandey and A.P. Mishra, Analyst, 113, 329 (1988); https://doi.org/10.1039/an9881300329.
- B.E.Y. Yon Hin, R.S. Sethi and C.R. Lowe, Sens. Actuators, 1, 550 (1990); https://doi.org/10.1016/0925-4005(90)80271-Z.
- S.B. Adeloju, S.J. Shaw and G.G. Wallace, Anal. Chim. Acta, 341, 155 (1997); https://doi.org/10.1016/S0003-2670(96)00502-8.
- S.B. Adeloju, S.J. Shaw and G.G. Wallace, Anal. Chim. Acta, 323, 107 (1996); https://doi.org/10.1016/0003-2670(95)00562-5.
- I. Vostiar, J. Tkac, E. Sturdik and P. Gemeiner, Bioelectrochemistry, 56, 113 (2002); https://doi.org/10.1016/S1567-5394(02)00042-7.
- D. Kirstein, L. Kirstein and F. Scheller, Biosensors, 1, 117 (1985); https://doi.org/10.1016/0265-928X(85)85007-0.
- D. Kirstein, F. Scheller, B. Olsson and G. Johansson, Anal. Chim. Acta, 171, 345 (1985); https://doi.org/10.1016/S0003-2670(00)84213-0.
- S. Uchiyama, H. Watanabe, H. Yamazaki, A. Kanazawa, H. Hamana and Y. Okabe, J. Electrochem. Soc., 154, F31 (2007); https://doi.org/10.1149/1.2402127.
- D.K. Bandgar, G.D. Khuspe, R.C. Pawar, C.S. Lee and V.B. Patil, Appl. Nanosci., 4, 27 (2014); https://doi.org/10.1007/s13204-012-0175-8.
- S.K. Shukla, A. Bharadvaja, A. Tiwari, G.K. Parashar and G.C. Dubey, Adv. Mater. Letts., 1, 129 (2010). https://doi.org/10.5185/amlett.2010.3105.
- V.K. Gade, D.J. Shirale, P.D. Gaikwad, P.A. Savale, K.P. Kakde, H.J. Kharat and M.D. Shirsat, React. Funct. Polym., 66, 1420 (2006); https://doi.org/10.1016/j.reactfunctpolym.2006.04.005.
References
I. Svancara, K. Vytras, K. Kalcher, A. Walcarius and J. Wang, Electroanalysis, 21, 7 (2009); https://doi.org/10.1002/elan.200804340.
N.S. Gadhari, B.J. Sanghavi and A.K. Srivastava, Anal. Chim. Acta, 703, 31 (2011); https://doi.org/10.1016/j.aca.2011.07.017.
B. Lakard, G. Herlem, S. Lakard, A. Antoniou and B. Fahys, Biosens. Bioelectron., 19, 1641 (2004); https://doi.org/10.1016/j.bios.2003.12.035.
A. Sehitogullari and A.H. Uslan, Talanta, 57, 1039 (2002); https://doi.org/10.1016/S0039-9140(02)00149-2.
S.B. Adeloju, S.J. Shaw and G.G. Wallace, Anal. Chim. Acta, 281, 621 (1993); https://doi.org/10.1016/0003-2670(93)85023-D.
A. Sassolas, B. Prieto-Simón and J.-L. Marty, Am. J. Anal. Chem., 3, 210 (2012); https://doi.org/10.4236/ajac.2012.33030.
G.G. Guilbault and J.G. Montalvo, J. Am. Chem. Soc., 92, 2533 (1970); https://doi.org/10.1021/ja00711a052.
E. Bakker and M.E. Meyerhoff, eds.: A.J. Bard, M. Stratmann and G.S. Wilson, Ion-Selective Electrodes for Measurements in Biological Fluids, In: Encyclopedia of Electrochemistry, Wiley-VCH, Weinheim, vol. 9 (2002).
S. Uchiyama, M. Kobayashi and Y. Hasebe, Electroanalysis, 14, 1644 (2002); https://doi.org/10.1002/elan.200290005.
R. Sahney, B.K. Puri and S. Anand, Anal. Chim. Acta, 542, 157 (2005); https://doi.org/10.1016/j.aca.2005.03.069.
P. Bertocchi, D. Compagnone and G. Palleschi, Biosens. Bioelectron., 11, 1 (1996); https://doi.org/10.1016/0956-5663(96)83708-0.
M. Senda and Y. Yamamoto, Electroanalysis, 5, 775 (1993); https://doi.org/10.1002/elan.1140050910.
K. Yoneyama, Y. Fujino, T. Osaka and I. Satoh, Sens. Actuators B Chem., 76, 152 (2001); https://doi.org/10.1016/S0925-4005(01)00613-X.
W.J. Cho and H.J. Huang, Anal. Chem., 70, 3946 (1998); https://doi.org/10.1021/ac980004a.
V. Rajesh, W. Bisht, W. Takashima and K. Kaneto, Biomaterials, 26, 3683 (2005). https://doi.org/10.1016/j.biomaterials.2004.09.024.
M. Trojanowicz, A. Lewenstam, T.K.V. Krawczyk, I. Lahdesmaki and W. Szczepek, Electroanalysis, 8, 233 (1996); https://doi.org/10.1002/elan.1140080307.
P.C. Pandey and A.P. Mishra, Analyst, 113, 329 (1988); https://doi.org/10.1039/an9881300329.
B.E.Y. Yon Hin, R.S. Sethi and C.R. Lowe, Sens. Actuators, 1, 550 (1990); https://doi.org/10.1016/0925-4005(90)80271-Z.
S.B. Adeloju, S.J. Shaw and G.G. Wallace, Anal. Chim. Acta, 341, 155 (1997); https://doi.org/10.1016/S0003-2670(96)00502-8.
S.B. Adeloju, S.J. Shaw and G.G. Wallace, Anal. Chim. Acta, 323, 107 (1996); https://doi.org/10.1016/0003-2670(95)00562-5.
I. Vostiar, J. Tkac, E. Sturdik and P. Gemeiner, Bioelectrochemistry, 56, 113 (2002); https://doi.org/10.1016/S1567-5394(02)00042-7.
D. Kirstein, L. Kirstein and F. Scheller, Biosensors, 1, 117 (1985); https://doi.org/10.1016/0265-928X(85)85007-0.
D. Kirstein, F. Scheller, B. Olsson and G. Johansson, Anal. Chim. Acta, 171, 345 (1985); https://doi.org/10.1016/S0003-2670(00)84213-0.
S. Uchiyama, H. Watanabe, H. Yamazaki, A. Kanazawa, H. Hamana and Y. Okabe, J. Electrochem. Soc., 154, F31 (2007); https://doi.org/10.1149/1.2402127.
D.K. Bandgar, G.D. Khuspe, R.C. Pawar, C.S. Lee and V.B. Patil, Appl. Nanosci., 4, 27 (2014); https://doi.org/10.1007/s13204-012-0175-8.
S.K. Shukla, A. Bharadvaja, A. Tiwari, G.K. Parashar and G.C. Dubey, Adv. Mater. Letts., 1, 129 (2010). https://doi.org/10.5185/amlett.2010.3105.
V.K. Gade, D.J. Shirale, P.D. Gaikwad, P.A. Savale, K.P. Kakde, H.J. Kharat and M.D. Shirsat, React. Funct. Polym., 66, 1420 (2006); https://doi.org/10.1016/j.reactfunctpolym.2006.04.005.