Plasmon Enhanced by Ag-Doped S-TiO2/Ti Electrode as Highly Effective Photoelectrocatalyst for Degradation of Methylene Blue

M. Maulidiyah; Dwiprayogo Wibowo; H. Herlin; Meilani L. Andarini; Ruslan; Muhammad Nurdin

doi:10.14233/ajchem.2017.20836

Issue

Vol. 29 No. 11 (2017): Vol 29 Issue 11

Issue Published : September 29, 2017

This work is licensed under a Creative Commons Attribution 4.0 International License.

Plasmon Enhanced by Ag-Doped S-TiO2/Ti Electrode as Highly Effective Photoelectrocatalyst for Degradation of Methylene Blue

https://doi.org/10.14233/ajchem.2017.20836

M. Maulidiyah

Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Halu Oleo, Kendari 93232, Southeast Sulawesi, Indonesia

Dwiprayogo Wibowo

Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Halu Oleo, Kendari 93232, Southeast Sulawesi, Indonesia

H. Herlin

Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Halu Oleo, Kendari 93232, Southeast Sulawesi, Indonesia

Meilani L. Andarini

Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Halu Oleo, Kendari 93232, Southeast Sulawesi, Indonesia

Ruslan

Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Tadulako, Palu 94118, Central Sulawesi, Indonesia

Muhammad Nurdin

Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Halu Oleo, Kendari 93232, Southeast Sulawesi, Indonesia

Corresponding Author(s) : Muhammad Nurdin

mnurdin06@yahoo.com

Asian Journal of Chemistry, Vol. 29 No. 11 (2017): Vol 29 Issue 11
Article Published : October 10, 2017

Abstract

The degradation of methylene blue dye has been conducted by Ag@S-TiO₂/Ti electrode to increase the plasmon effect on visible light. The addition of silver metal was applied using electrodeposition method. While the S-TiO₂ was prepared by sol-gel and immobilization on TiO₂/Ti electrode. The results showed that the X-ray diffraction pattern of TiO₂/Ti electrode was anatase crystal. Fourier transform infrared analysis in the wavenumber of 1120 and 413 cm^-1 indicated the existence of S-O and Ti-O bonds. Supporting by scanning electron microscope and energy dispersive X-ray (SEM-EDX) on Ag@S-TiO₂/Ti electrode, the existence of Ag, Ti and S were 2.9, 4.5 and 2.3 KeV, respectively. The plasmon effect identity was active on visible light irradiation confirmed by the photoelectrocatalyst system using linear sweep voltammetry (LSV). Based on the UV-visible spectrophotometer measurement the efficiency of methylene blue degradation was 81.15 % on 0.5 ppm.

Keywords

TiO2 Silver Sulfur Photoelectrocatalysis Plasmon Methylene blue

Maulidiyah, M., Wibowo, D., Herlin, H., Andarini, M. L., Ruslan, ., & Nurdin, M. (2017). Plasmon Enhanced by Ag-Doped S-TiO2/Ti Electrode as Highly Effective Photoelectrocatalyst for Degradation of Methylene Blue. Asian Journal of Chemistry, 29(11), 2504–2508. https://doi.org/10.14233/ajchem.2017.20836

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References

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References

Maulidiyah, H. Ritonga, R. Salamba, D. Wibowo and M. Nurdin, Int. J. Chemtech Res., 8, 645 (2015).

Maulidiyah, M. Nurdin, D. Wibowo and A. Sani, Int. J. Pharm. Pharm. Sci., 7, 141 (2015).

R.M.S.R. Mohamed and N. Mt Nanyan, Asian J. Appl. Sci. (Faisalabad), 2, 650 (2014).

A.E. Ghaly, R. Ananthashankar, M. Alhattab and V.V. Ramakrishnan, J. Chem. Eng. Process. Technol., 5, 1 (2014).

S. Ameen, M.S. Akhtar, H.-K. Seo and H.-S. Shin, Chem. Eng. J., 247, 193 (2014); https://doi.org/10.1016/j.cej.2014.02.104.

M. Nurdin, M.Z. Muzakkar and Maulidiyah, J. Mater. Environ. Sci., 7, 3334 (2016).

M. Nurdin, Int. J. Pharma Bio. Sci., 5, 360 (2014).

B.R. Babu, A.K. Parande, S. Raghu and T.P. Kumar, J. Cotton Sci., 11, 141 (2007).

P.V. Bakre, P.S. Volvoikar, A.A. Vernekar and S.G. Tilve, J. Colloid Interf. Sci., 474, 58 (2016); https://doi.org/10.1016/j.jcis.2016.04.011.

R.S. Dariani, A. Esmaeili, A. Mortezaali and S. Dehghanpour, Optik, 127, 7143 (2016); https://doi.org/10.1016/j.ijleo.2016.04.026.

Maulidiyah, M. Nurdin, E. Widianingsih, T. Azis and D. Wibowo, ARPN J. Eng. Appl. Sci., 10, 6250 (2015).

A. Fujishima and K. Honda, Nature, 238, 37 (1972); https://doi.org/10.1038/238037a0.

M. Nurdin, A.H. Watoni and M. Maulidiyah, Int. J. Chemtech Res., 9, 483 (2016).

M. Nurdin, A. Zaeni, M. Maulidiyah, M. Natsir, A. Bampe and D. Wibowo, Orient. J. Chem., 32, 2713 (2016); https://doi.org/10.13005/ojc/320545.

M. Nurdin and Maulidiyah, Int. J. Sci. Technol. Res., 3, 122 (2014).

Maulidiyah, M. Nurdin, Erasmus, D. Wibowo, M. Natsir, H. Ritonga and A.H. Watoni, Int. J. Chemtech Res., 8, 416 (2015).

Maulidiyah, D.S. Tribawono, D. Wibowo and M. Nurdin, Anal. Bioanal. Electrochem., 8, 761 (2016).

Maulidiyah, H. Ritonga, C. Faiqoh, D. Wibowo and M. Nurdin, Biosci. Biotechnol. Res. Asia, 12, 1985 (2015); https://doi.org/10.13005/bbra/1865.

M. Maulidiyah, D. Wibowo, H. Hikmawati, R. Salamba and M. Nurdin, Orient. J. Chem., 31, 2337 (2015); https://doi.org/10.13005/ojc/310462.

Z. Arham, M. Nurdin and B. Buchari, Int. J. Chemtech Res., 9, 113 (2016).

Ruslan, M. Mirzan, M. Nurdin and A.W. Wahab, Int. J. Appl. Sci., 12, 399 (2016).

H. Yang, L.-Q. He, Z.-H. Wang, Y.-Y. Zheng, X. Lu, G.-R. Li, P.-P. Fang, J. Chen and Y. Tong, Electrochim. Acta, 209, 591 (2016); https://doi.org/10.1016/j.electacta.2016.05.120.

F. Huang, Q. Li, G.J. Thorogood, Y.-B. Cheng and R.A. Caruso, J. Mater. Chem., 22, 17128 (2012); https://doi.org/10.1039/c2jm32409a.

T.C. Jagadale, S.P. Takale, R.S. Sonawane, H.M. Joshi, S.I. Patil, B.B. Kale and S.B. Ogale, J. Phys. Chem. C, 112, 14595 (2008); https://doi.org/10.1021/jp803567f.

S.-H. Nam, T.K. Kim and J.-H. Boo, Catal. Today, 185, 259 (2012); https://doi.org/10.1016/j.cattod.2011.07.033.

S. Amreetha, S. Dhanuskodi, A. Nithya and K. Jothivenkatachalam, RSC Adv., 6, 7854 (2016); https://doi.org/10.1039/C5RA25017J.

T. Umebayashi, T. Yamaki, H. Itoh and K. Asai, Appl. Phys. Lett., 81, 454 (2002); https://doi.org/10.1063/1.1493647.

Q.-L. Liu, Z.-Y. Zhao and Q.-J. Liu, RSC Adv., 4, 32100 (2014); https://doi.org/10.1039/C4RA03891F.

A.E. Danks, S.R. Hall and Z. Schnepp, Mater. Horiz., 3, 91 (2016); https://doi.org/10.1039/C5MH00260E.

Z. Chen, L. Hao and C. Chen, Colloids Surf. A, 401, 1 (2012); https://doi.org/10.1016/j.colsurfa.2012.02.020.

Issue

Vol. 29 No. 11 (2017): Vol 29 Issue 11

Plasmon Enhanced by Ag-Doped S-TiO2/Ti Electrode as Highly Effective Photoelectrocatalyst for Degradation of Methylene Blue

Corresponding Author(s) : Muhammad Nurdin

Abstract

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