Hydrothermal Synthesis and Structure of a 3D-Supramolecular Complex: phen-Cu-C2O4
Corresponding Author(s) : Jian-Hong Bi
hxx010101@126.com
Asian Journal of Chemistry,
Vol. 20 No. 7 (2008): Vol 20 Issue 7
Abstract
The complex Cu[(phen)(C2O4)(H2O)]·H2O, where phen
= 1,10-phenanthroline, has been synthesized and its crystal
structure were determined by X-ray diffraction. Crystal data:
monoclinic, space group P2(1)/n, a = 8.457 Å, b = 9.70580(10)
Å, c = 17.45100(10) Å, α = 90º, β = 103.8190(10)º, γ = 90º,
V = 1391.016(16)Å3, Z = 4, Mr = 367.80, Dc = 1.756 Mg/cm3,
μ = 1.605 mm-1, F(000) = 748, T = 273(2) K, R = 0.0292, wR
= 0.0735 for 2460 observed reflections (I > 2σ(I)). The center
Cu(II) ion is coordinated by five atoms in a slightly distorted
square pyramidal geometry. The compound is in 3D supramolecular
state.
= 1,10-phenanthroline, has been synthesized and its crystal
structure were determined by X-ray diffraction. Crystal data:
monoclinic, space group P2(1)/n, a = 8.457 Å, b = 9.70580(10)
Å, c = 17.45100(10) Å, α = 90º, β = 103.8190(10)º, γ = 90º,
V = 1391.016(16)Å3, Z = 4, Mr = 367.80, Dc = 1.756 Mg/cm3,
μ = 1.605 mm-1, F(000) = 748, T = 273(2) K, R = 0.0292, wR
= 0.0735 for 2460 observed reflections (I > 2σ(I)). The center
Cu(II) ion is coordinated by five atoms in a slightly distorted
square pyramidal geometry. The compound is in 3D supramolecular
state.
Keywords
Copper(II) complex
Crystal structure
Phenanthroline
Oxalate
Superamolecular.
Bi, J.-H. (2010). Hydrothermal Synthesis and Structure of a 3D-Supramolecular Complex: phen-Cu-C2O4. Asian Journal of Chemistry, 20(7), 5794–5796. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/12928
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