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Ion-Exchange Applications of Newly Synthesized of Aminoacetophenone, Biuret, Formaldehyde Derivative as New Chelating Terpolymer Resin
Corresponding Author(s) : Azhar Kamil Rashid
Asian Journal of Chemistry,
Vol. 29 No. 11 (2017): Vol 29 Issue 11
Abstract
A new chelating terpolymer resin (o-AABF) was synthesized through copolymerization of o-amino acetophenone, biuret, formaldehyde in (1:1:3) mol ratio in acidic medium (HCl) by condensation reaction. The synthesized copolymer resin was characterized by UV-visible, FTIR and 1H NMR techniques. The empirical structure and molecular weight of the resin were analyzed by elemental analysis. Morphological structure of the synthesized resin was studied by scanning electron microscopy. Thermal properties and stability of the resin was determined by DSC and TGA. The intrinsic viscosity and the viscosity average molecular weight were calculated. Selectivity and binding capacity of the terpolymer resin studied by batch equilibrium method toward Ni2+, Co2+, Cd2+, Cu2+, Zn2+ and Cr3+ in different pH and treatment time.
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- A.A. Atia, A.M. Donia and K.Z. Elwakeel, React. Funct. Polym., 65, 267 (2005); https://doi.org/10.1016/j.reactfunctpolym.2005.07.001.
- D. Prabhakaran and M.S. Subramanian, Talanta, 59, 1227 (2003); https://doi.org/10.1016/S0039-9140(03)00030-4.
- S. Nabi, A. Alim, A. Islam and M. Amjad, J. Sep. Sci., 28, 2463 (2005); https://doi.org/10.1002/jssc.200500170.
- R.A. Beauvais and S.D. Alexandratos, React. Funct. Polym., 36, 113 (1998); https://doi.org/10.1016/S1381-5148(98)00016-9.
- S.A. Patel, B.S. Shah, R.M. Patel and P.M. Patel, Iran. Polym. J., 13, 445 (2004).
- M. Karunakaran and C. Magesh, Arabian J. Chem., 4, 339 (2011); https://doi.org/10.1016/j.arabjc.2010.06.057.
- M. Karunakaran and A. Burkanudeen, Orient. J. Chem., 19, 225 (2003).
- B.A. Shah, A.V. Shah, B.N. Bhandari and R.R. Bhatt, Iran. Polym. J., 16, 173 (2007).
- R.S. Azarudeen, M.A. Riswan, D. Jeyakumar and A.R. Burkanudeen, Iran. Polym. J., 18, 821 (2009).
- M.A. Riswan, R.S. Azarudeen, M. Karunakaran and A.R. Burkanudeen, Iran. Polym. J., 19, 635 (2010).
- W.B. Gurnul, H.D. Junej and L.J. Paliwal, React. Funct. Polym., 50, 95 (2002); https://doi.org/10.1016/S1381-5148(01)00072-4.
- W.B. Gurnule, P.K. Rahangdale, L.J. Paliwal and R.B. Kharat, Synth. React. Inorg. Met.-Org. Chem., 33, 1187 (2003); https://doi.org/10.1081/SIM-120023486.
- E. Bowers, Water Quality and Treatment, American Water Association Inc., p. 20 (1971).
- A. Deratani and B. Sebille, Anal. Chem., 53, 1742 (1981); https://doi.org/10.1021/ac00235a007.
- T.H. Al-Bayati and M. Sc, Thesis, University of Tikrit, pp. 64-67 (2008).
- A.R. Burkanudeen, R.S. Azarudeen, M.A.R. Ahamed and W.B. Gurnule, Polym. Bull., 67, 1553 (2011); https://doi.org/10.1007/s00289-011-0497-9.
- A.I. Vogel, Text Book of Practical Organic Chemistry, Longman Scientific and Technical, London, UK (1989).
- R.M. Silverstein and F.X. Webster, Spectrometric Identification of Organic Compounds, John Wiley & Sons, New York (1998).
- M. Karunakaran, C.T. Vijayakumar, C. Magesh and T. Amudha, Int. J. Eng. Sci. Technol., 1, 3 (2011).
- J.C. Bevington and T.N. Huckerby, Eur. Polym. J., 42, 1433 (2006); https://doi.org/10.1016/j.eurpolymj.2005.12.011.
- C. Wu, D. Cao, Y. Cao, Y. Gao and W. Guo, e-Polymers, 8, 123 (2008); https://doi.org/10.1515/epoly.2008.8.1.1416
References
A.A. Atia, A.M. Donia and K.Z. Elwakeel, React. Funct. Polym., 65, 267 (2005); https://doi.org/10.1016/j.reactfunctpolym.2005.07.001.
D. Prabhakaran and M.S. Subramanian, Talanta, 59, 1227 (2003); https://doi.org/10.1016/S0039-9140(03)00030-4.
S. Nabi, A. Alim, A. Islam and M. Amjad, J. Sep. Sci., 28, 2463 (2005); https://doi.org/10.1002/jssc.200500170.
R.A. Beauvais and S.D. Alexandratos, React. Funct. Polym., 36, 113 (1998); https://doi.org/10.1016/S1381-5148(98)00016-9.
S.A. Patel, B.S. Shah, R.M. Patel and P.M. Patel, Iran. Polym. J., 13, 445 (2004).
M. Karunakaran and C. Magesh, Arabian J. Chem., 4, 339 (2011); https://doi.org/10.1016/j.arabjc.2010.06.057.
M. Karunakaran and A. Burkanudeen, Orient. J. Chem., 19, 225 (2003).
B.A. Shah, A.V. Shah, B.N. Bhandari and R.R. Bhatt, Iran. Polym. J., 16, 173 (2007).
R.S. Azarudeen, M.A. Riswan, D. Jeyakumar and A.R. Burkanudeen, Iran. Polym. J., 18, 821 (2009).
M.A. Riswan, R.S. Azarudeen, M. Karunakaran and A.R. Burkanudeen, Iran. Polym. J., 19, 635 (2010).
W.B. Gurnul, H.D. Junej and L.J. Paliwal, React. Funct. Polym., 50, 95 (2002); https://doi.org/10.1016/S1381-5148(01)00072-4.
W.B. Gurnule, P.K. Rahangdale, L.J. Paliwal and R.B. Kharat, Synth. React. Inorg. Met.-Org. Chem., 33, 1187 (2003); https://doi.org/10.1081/SIM-120023486.
E. Bowers, Water Quality and Treatment, American Water Association Inc., p. 20 (1971).
A. Deratani and B. Sebille, Anal. Chem., 53, 1742 (1981); https://doi.org/10.1021/ac00235a007.
T.H. Al-Bayati and M. Sc, Thesis, University of Tikrit, pp. 64-67 (2008).
A.R. Burkanudeen, R.S. Azarudeen, M.A.R. Ahamed and W.B. Gurnule, Polym. Bull., 67, 1553 (2011); https://doi.org/10.1007/s00289-011-0497-9.
A.I. Vogel, Text Book of Practical Organic Chemistry, Longman Scientific and Technical, London, UK (1989).
R.M. Silverstein and F.X. Webster, Spectrometric Identification of Organic Compounds, John Wiley & Sons, New York (1998).
M. Karunakaran, C.T. Vijayakumar, C. Magesh and T. Amudha, Int. J. Eng. Sci. Technol., 1, 3 (2011).
J.C. Bevington and T.N. Huckerby, Eur. Polym. J., 42, 1433 (2006); https://doi.org/10.1016/j.eurpolymj.2005.12.011.
C. Wu, D. Cao, Y. Cao, Y. Gao and W. Guo, e-Polymers, 8, 123 (2008); https://doi.org/10.1515/epoly.2008.8.1.1416