Copyright (c) 2017 AJC
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Green Synthesis of Silver Nanoparticles by Mint Leaves: A Suitable Catalyst for Oxidation of Metronidazole
Corresponding Author(s) : Ajaya Kumar Singh
Asian Journal of Chemistry,
Vol. 29 No. 11 (2017): Vol 29 Issue 11
Abstract
Synthesis of silver nanoparticles via an eco-friendly route is an active area of research because of its unique properties. Present work deals with green synthesis of silver nanoparticles using mint leaves and its catalytic behaviour was explored for the oxidation of metronidazole (MTZ) by hexacyanoferrate (HCF) as an oxidant. Firstly, synthesized nanoparticles were characterized by UV-visible, scanning electron microscopy and Fourier transform infrared analysis. The degradation of metronidazole by hexacyanoferrate was studied spectrophometrically, both in the absence and presence of silver nanoparticles catalyst in basic medium under pseudo first order condition. It was observed that the silver nanoparticles as catalyst significantly increases the reaction rate and overall thermodynamic activation parameters were also calculated.
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- V.L. Colvin, M.C. Schlamp and A.P. Alivisatos, Nature, 370, 354 (1994); https://doi.org/10.1038/370354a0.
- G. Schmid, Chem. Rev., 92, 1709 (1992); https://doi.org/10.1021/cr00016a002.
- Y. Wang and N. Herron, J. Phys. Chem, 95, 525 (1991); https://doi.org/10.1021/j100155a009.
- V. Joseph, C. Engelbrekt, J. Zhang, U. Gernert, J. Ulstrup and J. Kneipp, Angew. Chem. Int. Ed., 51, 7592 (2012); https://doi.org/10.1002/anie.201203526.
- S. Iravani, H. Korbekandi, S.V. Mirmohammadi and B. Zolfaghari, Res. Pharma. Sci., 9, 385 (2014).
- X.Y. Dong, Z.W. Gao, K.F. Yang, W.Q. Zhang and L.W. Xu, Catal. Sci. Technol., 5, 2554 (2015); https://doi.org/10.1039/C5CY00285K.
- I.M. Chung, I. Park, K. Seung-Hyun, M. Thiruvengadam and G. Rajakumar, Nanoscale Res. Lett., 11, 40 (2016); https://doi.org/10.1186/s11671-016-1257-4.
- Y. Park, Toxicol. Res., 30, 169 (2014); https://doi.org/10.5487/TR.2014.30.3.169.
- S. Ahmed, M. Ahmad, B.L. Swami and S. Ikram, J. Adv. Res., 7, 17 (2016); https://doi.org/10.1016/j.jare.2015.02.007.
- J. Huang, G. Zhan, B. Zheng, D. Sun, F. Lu, Y. Lin, H. Chen, Z. Zheng, Y. Zheng and Q. Li, Ind. Eng. Chem., 50, 9095 (2011); https://doi.org/10.1021/ie200858y.
- M. Sathish Kumar, K. Sneha, S.W. Won, C.W. Cho, S. Kim and Y.S. Yun, Colloids Surf. B Biointerfaces, 73, 332 (2009); https://doi.org/10.1016/j.colsurfb.2009.06.005.
- C.G. Daughton and T. Ternes, Environ. Health Perspect., 107(Suppl 6), 907 (1999); https://doi.org/10.1289/ehp.99107s6907.
- K.N. Mohana and P.M. Ramdas Bhandarkar, J. Iran. Chem. Soc., 6, 277 (2009); https://doi.org/10.1007/BF03245835.
- R.V. Puttaswamy, R.V. Jagadeesh and N.M.M. Gowda, Int. J. Chem. Kinet., 37, 700 (2005); https://doi.org/10.1002/kin.20118.
- M.B. Johnson and M. Mehrvar, Ind. Eng. Chem. Res., 47, 6525 (2008); https://doi.org/10.1021/ie071637v.
- M. Vertzoni, A. Carlsson, B. Abrahamsson, K. Goumas and C. Reppas, Int. J. Pharm., 413, 81 (2011); https://doi.org/10.1016/j.ijpharm.2011.04.028.
- A. Bendesky, D. Menendez and P.O. Wegman, Mutat. Res., 511, 133 (2002); https://doi.org/10.1016/S1383-5742(02)00007-8.
- Z. Fang, J. Chen, X. Qiu, X. Qiu, W. Cheng and L. Zhu, Desalination, 268, 60 (2011); https://doi.org/10.1016/j.desal.2010.09.051.
- J. Rivera-Utrilla, G. Prados-Joya, M. Sánchez-Polo, M.A. Ferro-García and I. Bautista-Toledo, J. Hazard. Mater., 170, 298 (2009); https://doi.org/10.1016/j.jhazmat.2009.04.096.
- M. Mohajerani, M. Mehrvar and F. Ein-Mozaffari, Ind. Eng. Chem. Res., 49, 5367 (2010); https://doi.org/10.1021/ie900906e.
- C. Han, J. Chen, X. Wu, Y.W. Huang and Y. Zhao, Talanta, 128, 293 (2014); https://doi.org/10.1016/j.talanta.2014.04.083.
- A.A.P. Khan, A.M. Asiri, A. Khan, N. Azum, M.A. Rub, M.M. Rahman, S.B. Khan, K.S. Siddiqi and K.A. Alamry, J. Ind. Eng. Chem., 19, 595 (2013); https://doi.org/10.1016/j.jiec.2012.09.025.
- R.M. Hassan, S.M. Ibrahim, I.A. Zaafarany, A. Fawzy and H.D. Takagi, J. Mol. Catal. A Chem., 344, 93 (2011); https://doi.org/10.1016/j.molcata.2011.05.006.
- K. Sharanabasamma, M.A. Angadi, M.S. Salunke and S.M. Tuwar, Ind. Eng. Chem. Res., 48, 10381 (2009); https://doi.org/10.1021/ie901049p.
- J.M. Pushparaj, S. Kannan, L. Vikram, L.S. Kumar and K.S. Rangappa, J. Phys. Org. Chem., 18, 1042 (2005); https://doi.org/10.1002/poc.968.
- K. Sharma and R.N. Mehrotra, Polyhedron, 27, 3425 (2008); https://doi.org/10.1016/j.poly.2008.08.002.
- B. García, R. Ruiz and J.M. Leal, J. Phys. Chem. A, 112, 4921 (2008); https://doi.org/10.1021/jp800208s.
- T.P. Jose, M.A. Angadi, M.S. Salunke and S.M. Tuwar, J. Mol. Struct., 892, 121 (2008); https://doi.org/10.1016/j.molstruc.2008.05.006.
- P.J. Babu, P. Sharma, B.B. Borthakur, R.K. Das, P. Nahar and U. Bora, Int. J. Green Nanotech.: Phy. and Chem., 2, 62 (2010); https://doi.org/10.1080/19430876.2010.532443.
- A. Rafey, K.B.L. Shrivastavaa, S.A. Iqbal and Z. Khan, J. Colloid Interface Sci., 354, 190 (2011); https://doi.org/10.1016/j.jcis.2010.10.046.
- D.W. Kim, S.I. Shin, S.G. Ohin, K.L. Mittal and D.O. Shah, Surface Science Series, Marcel Dekker, New York, vol. 109, p. 255 (2003).
- A.I. Vogel, Text Book of Practical Organic Chemistry, 5th ed., ELBS & Longman, London, edn 5 p. 1332 (1989).
References
V.L. Colvin, M.C. Schlamp and A.P. Alivisatos, Nature, 370, 354 (1994); https://doi.org/10.1038/370354a0.
G. Schmid, Chem. Rev., 92, 1709 (1992); https://doi.org/10.1021/cr00016a002.
Y. Wang and N. Herron, J. Phys. Chem, 95, 525 (1991); https://doi.org/10.1021/j100155a009.
V. Joseph, C. Engelbrekt, J. Zhang, U. Gernert, J. Ulstrup and J. Kneipp, Angew. Chem. Int. Ed., 51, 7592 (2012); https://doi.org/10.1002/anie.201203526.
S. Iravani, H. Korbekandi, S.V. Mirmohammadi and B. Zolfaghari, Res. Pharma. Sci., 9, 385 (2014).
X.Y. Dong, Z.W. Gao, K.F. Yang, W.Q. Zhang and L.W. Xu, Catal. Sci. Technol., 5, 2554 (2015); https://doi.org/10.1039/C5CY00285K.
I.M. Chung, I. Park, K. Seung-Hyun, M. Thiruvengadam and G. Rajakumar, Nanoscale Res. Lett., 11, 40 (2016); https://doi.org/10.1186/s11671-016-1257-4.
Y. Park, Toxicol. Res., 30, 169 (2014); https://doi.org/10.5487/TR.2014.30.3.169.
S. Ahmed, M. Ahmad, B.L. Swami and S. Ikram, J. Adv. Res., 7, 17 (2016); https://doi.org/10.1016/j.jare.2015.02.007.
J. Huang, G. Zhan, B. Zheng, D. Sun, F. Lu, Y. Lin, H. Chen, Z. Zheng, Y. Zheng and Q. Li, Ind. Eng. Chem., 50, 9095 (2011); https://doi.org/10.1021/ie200858y.
M. Sathish Kumar, K. Sneha, S.W. Won, C.W. Cho, S. Kim and Y.S. Yun, Colloids Surf. B Biointerfaces, 73, 332 (2009); https://doi.org/10.1016/j.colsurfb.2009.06.005.
C.G. Daughton and T. Ternes, Environ. Health Perspect., 107(Suppl 6), 907 (1999); https://doi.org/10.1289/ehp.99107s6907.
K.N. Mohana and P.M. Ramdas Bhandarkar, J. Iran. Chem. Soc., 6, 277 (2009); https://doi.org/10.1007/BF03245835.
R.V. Puttaswamy, R.V. Jagadeesh and N.M.M. Gowda, Int. J. Chem. Kinet., 37, 700 (2005); https://doi.org/10.1002/kin.20118.
M.B. Johnson and M. Mehrvar, Ind. Eng. Chem. Res., 47, 6525 (2008); https://doi.org/10.1021/ie071637v.
M. Vertzoni, A. Carlsson, B. Abrahamsson, K. Goumas and C. Reppas, Int. J. Pharm., 413, 81 (2011); https://doi.org/10.1016/j.ijpharm.2011.04.028.
A. Bendesky, D. Menendez and P.O. Wegman, Mutat. Res., 511, 133 (2002); https://doi.org/10.1016/S1383-5742(02)00007-8.
Z. Fang, J. Chen, X. Qiu, X. Qiu, W. Cheng and L. Zhu, Desalination, 268, 60 (2011); https://doi.org/10.1016/j.desal.2010.09.051.
J. Rivera-Utrilla, G. Prados-Joya, M. Sánchez-Polo, M.A. Ferro-García and I. Bautista-Toledo, J. Hazard. Mater., 170, 298 (2009); https://doi.org/10.1016/j.jhazmat.2009.04.096.
M. Mohajerani, M. Mehrvar and F. Ein-Mozaffari, Ind. Eng. Chem. Res., 49, 5367 (2010); https://doi.org/10.1021/ie900906e.
C. Han, J. Chen, X. Wu, Y.W. Huang and Y. Zhao, Talanta, 128, 293 (2014); https://doi.org/10.1016/j.talanta.2014.04.083.
A.A.P. Khan, A.M. Asiri, A. Khan, N. Azum, M.A. Rub, M.M. Rahman, S.B. Khan, K.S. Siddiqi and K.A. Alamry, J. Ind. Eng. Chem., 19, 595 (2013); https://doi.org/10.1016/j.jiec.2012.09.025.
R.M. Hassan, S.M. Ibrahim, I.A. Zaafarany, A. Fawzy and H.D. Takagi, J. Mol. Catal. A Chem., 344, 93 (2011); https://doi.org/10.1016/j.molcata.2011.05.006.
K. Sharanabasamma, M.A. Angadi, M.S. Salunke and S.M. Tuwar, Ind. Eng. Chem. Res., 48, 10381 (2009); https://doi.org/10.1021/ie901049p.
J.M. Pushparaj, S. Kannan, L. Vikram, L.S. Kumar and K.S. Rangappa, J. Phys. Org. Chem., 18, 1042 (2005); https://doi.org/10.1002/poc.968.
K. Sharma and R.N. Mehrotra, Polyhedron, 27, 3425 (2008); https://doi.org/10.1016/j.poly.2008.08.002.
B. García, R. Ruiz and J.M. Leal, J. Phys. Chem. A, 112, 4921 (2008); https://doi.org/10.1021/jp800208s.
T.P. Jose, M.A. Angadi, M.S. Salunke and S.M. Tuwar, J. Mol. Struct., 892, 121 (2008); https://doi.org/10.1016/j.molstruc.2008.05.006.
P.J. Babu, P. Sharma, B.B. Borthakur, R.K. Das, P. Nahar and U. Bora, Int. J. Green Nanotech.: Phy. and Chem., 2, 62 (2010); https://doi.org/10.1080/19430876.2010.532443.
A. Rafey, K.B.L. Shrivastavaa, S.A. Iqbal and Z. Khan, J. Colloid Interface Sci., 354, 190 (2011); https://doi.org/10.1016/j.jcis.2010.10.046.
D.W. Kim, S.I. Shin, S.G. Ohin, K.L. Mittal and D.O. Shah, Surface Science Series, Marcel Dekker, New York, vol. 109, p. 255 (2003).
A.I. Vogel, Text Book of Practical Organic Chemistry, 5th ed., ELBS & Longman, London, edn 5 p. 1332 (1989).