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Synthesis and Characterization of Some Thiadiazole Compounds as New Corrosion Inhibitors for Mild Steel in Cooling Water
Corresponding Author(s) : Munther Abduljaleel M.A.
Asian Journal of Chemistry,
Vol. 29 No. 11 (2017): Vol 29 Issue 11
Abstract
In present work, five 1,3,4-thiadiazole compounds were synthesized. The prepared compounds were identified by CHNS analysis, FT-IR and 1H NMR spectroscopy. The corrosion rates in the presence of thiadiazole as a steel corrosion inhibitor in the cooling water system which taken from South Fertilizer Company, Basra, Iraq were measured by the weight loss method and potentiodynamic polarization measurements. The weight loss method was studied in different times (1-5 h) and in 303 to 333 K temperature range. Results obtained revealed that thiadiazole compounds performed as a corrosion inhibitor for mild steel in this medium and its efficiency attains to 86.55 % at 5 × 10-3 M at 303 K and by potentiodynamic polarization measurements its efficiency attains to 85.35 % in the same conditions. The apparent activation energies, enthalpies and entropies of the dissolution process and the free energies were determined and discussed.
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- M.M. Antonijevic, S.M. Milic and M.B. Petrovic, Corros. Sci., 51, 1228 (2009); https://doi.org/10.1016/j.corsci.2009.03.026.
- F.M. Al-Kharafi, B.G. Ateya and R.M.A. Allah, J. Appl. Electrochem., 34, 47 (2004); https://doi.org/10.1023/B:JACH.0000005616.41240.d0.
- M.M. Antonijevic, S.M. Milic, M.B. Radovanovic, M.B. Petrovic and A.T. Stamenkovic, Int. J. Electrochem. Sci., 4, 1719 (2009).
- R. Ravichandran and N. Rajendran, Appl. Surf. Sci., 239, 182 (2005); https://doi.org/10.1016/j.apsusc.2004.05.145.
- T. Murakawa, S. Nagaura and N. Hackerman, Corros. Sci., 7, 79 (1967); https://doi.org/10.1016/S0010-938X(67)80105-7.
- X. Liu, X. Fang, Y. Tang, C. Sun and C. Yao, Mater. Sci. Appl., 2, 1268 (2011); https://doi.org/10.4236/msa.2011.29171.
- Z. Chen, L. Huang, G. Zhang, Y. Qiu and X. Guo, Corros. Sci., 65, 214 (2012); https://doi.org/10.1016/j.corsci.2012.08.019.
- M. Mihit, S. El Issami, M. Bouklah, L. Bazzi, B. Hammouti, E.A. Addi, R. Salghi and S. Kertit, Appl. Surf. Sci., 252, 2389 (2006); https://doi.org/10.1016/j.apsusc.2005.04.009.
- A. Doner, E.A. Sahin, G. Kardas and O. Serindag, Corros. Sci., 66, 278 (2013); https://doi.org/10.1016/j.corsci.2012.09.030.
- M. Palomar-Pardavé, M. Romero-Romo, H. Herrera-Hernandez, M.A. Abreu-Quijano, N.V. Likhanova, J. Uruchurtu and J.M. Juárez-García, Corros. Sci., 54, 231 (2012); https://doi.org/10.1016/j.corsci.2011.09.020.
- S.A. Ali, M.T. Saeed and S.U. Rahman, Corros. Sci., 45, 253 (2003); https://doi.org/10.1016/S0010-938X(02)00099-9.
- S.A. Ali, H.A. Al-Muallem, S.U. Rahman and M.T. Saeed, Corros. Sci., 50, 3070 (2008); https://doi.org/10.1016/j.corsci.2008.08.011.
- M.W. Jawich, G.A. Oweimreen and S.A. Ali, Corros. Sci., 65, 104 (2012); https://doi.org/10.1016/j.corsci.2012.08.001.
- M.K. Bharty, A. Bharti, R.K. Dani, S.K. Kushawaha, R. Dulare and N.K. Singh, Polyhedron, 41, 52 (2012); https://doi.org/10.1016/j.poly.2012.04.025.
- M.A. Mohammed Ali, Ph.D. Thesis, Basrah University, Basrah, Iraq (2008).
- S. Banerjee, V. Srivastava and M.M. Singh, Corros. Sci., 59, 35 (2012); https://doi.org/10.1016/j.corsci.2012.02.009.
- A.S. Abdul-Nabi and A.A. Hussain, J. Basrah Res. (Sci.), 38, 125 (2012).
- A.E.-A. Gaber, M.S. El-Gaby, A.M. El-Dean, H.A. Eyada and A.S. Al-Kamali, J. Chin. Chem. Soc. (Taipei), 51, 1325 (2004); https://doi.org/10.1002/jccs.200400192.
- R.M. Silverstein and F.X. Webster, Spectroscopic Identification of Organic Compounds, John Wiley & Sons, New York, edn 6 (1998).
- M.S. Khan, G. Chawla and M.A. Mueed, Indian J. Chem., 43B, 1302 (2004).
- A. Singh, V.K. Singh and M.A. Quraishi, J. Mater. Environ. Sci., 1, 162 (2010).
- A. Singh, V.K. Singh and M.A. Quraishi, Int. J. Corros., Article ID 275983 (2010); http://dx.doi.org/10.1155/2010/275983.
- M.D. Shah, A.S. Patel, G.V. Mudaliar and N.K. Shah, Portug. Electrochem. Acta, 29, 101 (2011); https://doi.org/10.4152/pea.201102101
References
M.M. Antonijevic, S.M. Milic and M.B. Petrovic, Corros. Sci., 51, 1228 (2009); https://doi.org/10.1016/j.corsci.2009.03.026.
F.M. Al-Kharafi, B.G. Ateya and R.M.A. Allah, J. Appl. Electrochem., 34, 47 (2004); https://doi.org/10.1023/B:JACH.0000005616.41240.d0.
M.M. Antonijevic, S.M. Milic, M.B. Radovanovic, M.B. Petrovic and A.T. Stamenkovic, Int. J. Electrochem. Sci., 4, 1719 (2009).
R. Ravichandran and N. Rajendran, Appl. Surf. Sci., 239, 182 (2005); https://doi.org/10.1016/j.apsusc.2004.05.145.
T. Murakawa, S. Nagaura and N. Hackerman, Corros. Sci., 7, 79 (1967); https://doi.org/10.1016/S0010-938X(67)80105-7.
X. Liu, X. Fang, Y. Tang, C. Sun and C. Yao, Mater. Sci. Appl., 2, 1268 (2011); https://doi.org/10.4236/msa.2011.29171.
Z. Chen, L. Huang, G. Zhang, Y. Qiu and X. Guo, Corros. Sci., 65, 214 (2012); https://doi.org/10.1016/j.corsci.2012.08.019.
M. Mihit, S. El Issami, M. Bouklah, L. Bazzi, B. Hammouti, E.A. Addi, R. Salghi and S. Kertit, Appl. Surf. Sci., 252, 2389 (2006); https://doi.org/10.1016/j.apsusc.2005.04.009.
A. Doner, E.A. Sahin, G. Kardas and O. Serindag, Corros. Sci., 66, 278 (2013); https://doi.org/10.1016/j.corsci.2012.09.030.
M. Palomar-Pardavé, M. Romero-Romo, H. Herrera-Hernandez, M.A. Abreu-Quijano, N.V. Likhanova, J. Uruchurtu and J.M. Juárez-García, Corros. Sci., 54, 231 (2012); https://doi.org/10.1016/j.corsci.2011.09.020.
S.A. Ali, M.T. Saeed and S.U. Rahman, Corros. Sci., 45, 253 (2003); https://doi.org/10.1016/S0010-938X(02)00099-9.
S.A. Ali, H.A. Al-Muallem, S.U. Rahman and M.T. Saeed, Corros. Sci., 50, 3070 (2008); https://doi.org/10.1016/j.corsci.2008.08.011.
M.W. Jawich, G.A. Oweimreen and S.A. Ali, Corros. Sci., 65, 104 (2012); https://doi.org/10.1016/j.corsci.2012.08.001.
M.K. Bharty, A. Bharti, R.K. Dani, S.K. Kushawaha, R. Dulare and N.K. Singh, Polyhedron, 41, 52 (2012); https://doi.org/10.1016/j.poly.2012.04.025.
M.A. Mohammed Ali, Ph.D. Thesis, Basrah University, Basrah, Iraq (2008).
S. Banerjee, V. Srivastava and M.M. Singh, Corros. Sci., 59, 35 (2012); https://doi.org/10.1016/j.corsci.2012.02.009.
A.S. Abdul-Nabi and A.A. Hussain, J. Basrah Res. (Sci.), 38, 125 (2012).
A.E.-A. Gaber, M.S. El-Gaby, A.M. El-Dean, H.A. Eyada and A.S. Al-Kamali, J. Chin. Chem. Soc. (Taipei), 51, 1325 (2004); https://doi.org/10.1002/jccs.200400192.
R.M. Silverstein and F.X. Webster, Spectroscopic Identification of Organic Compounds, John Wiley & Sons, New York, edn 6 (1998).
M.S. Khan, G. Chawla and M.A. Mueed, Indian J. Chem., 43B, 1302 (2004).
A. Singh, V.K. Singh and M.A. Quraishi, J. Mater. Environ. Sci., 1, 162 (2010).
A. Singh, V.K. Singh and M.A. Quraishi, Int. J. Corros., Article ID 275983 (2010); http://dx.doi.org/10.1155/2010/275983.
M.D. Shah, A.S. Patel, G.V. Mudaliar and N.K. Shah, Portug. Electrochem. Acta, 29, 101 (2011); https://doi.org/10.4152/pea.201102101