Synthesis and Characterization of Cd(II), Zn(II) and Hg(II) Chloride Adducts of (2Z,3Z)-1,4,7- Trithiononane-2,3-dionedioxime
Corresponding Author(s) : ALI KAKANEJADIFARD
kakanejadi.a@lu.ac.ir, alikakanejadifard@yahoo.com
Asian Journal of Chemistry,
Vol. 20 No. 2 (2008): Vol 20 Issue 2
Abstract
A New vic-dioxime, (2Z,3Z)-1,4,7-trithiononane-2,3- dionedioxime (H2L) was prepared from reaction of 2-[2- mercaptoethyl)thio]ethanethiol with dichloroglyoxime. Mononuclear complexes of H2L with Zn(II), Hg(II) and Cd(II) were also prepared and their structures were determined by means of NMR, IR and mass spectroscopy. The Hg(II), Cd(II) and Zn(II) form 1:1 tetrahedral complexes with a N,N-chelation.
Keywords
vic-Dioxime
Zn(II)
Cd(II)
Hg(II)
1,4,7-Trithionane-2,3-dionedioxime
N,NChelation
(1)
KAKANEJADIFARD, A.; ZABARDASTI, A.; GHASEMIAN, M.; TOOSI-JAMALI, H. Synthesis and Characterization of Cd(II), Zn(II) and Hg(II) Chloride Adducts of (2Z,3Z)-1,4,7- Trithiononane-2,3-Dionedioxime. ajc 2010, 20, 1473-1476.
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