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Vol. 29 No. 10 (2017): Vol 29 Issue 10

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Di-μ-oxidovanadium(V) Complex with N'-[(Z)-Phenyl(pyridin-2-yl)methylidene]pyridine-4-carbohydrazide: Synthesis, Structural Characterization and in vitro Antidiabetic Inhibition Study

https://doi.org/10.14233/ajchem.2017.20921
R.N. Patel
Department of Chemistry, A.P.S. University, Rewa-486 003, India
Yogendra Pratap Singh
Department of Chemistry, A.P.S. University, Rewa-486 003, India

Corresponding Author(s) : R.N. Patel

rnp64@ymail.com

Asian Journal of Chemistry, Vol. 29 No. 10 (2017): Vol 29 Issue 10

Abstract

Schiff base and its one di-μ-oxidovanadium(V) complex have been synthesized by the reaction of vanadyl sulphate pentahydrate and N’-[(Z)-phenyl(pyridin-2-yl)methylidene]pyridine-4-carbohydrazide (HL). The HL and its complex [(L)VO(μ-O)2VO(L)] have been characterized by micro-analysis, UV-visible and electrochemical techniques. The ligand and its complex have also been characterized by single crystal X-ray technique. The ligand crystallizes in triclinic crystal system with P`1 space group while, complex crystallizes in monoclinic crystal system with P21/c space group. The electronic spectrum is as expected for vanadium(V) in an octahedral environment in each vanadium centers. The electronic structures of the ligand and the complex have been explained by density functional theory (DFT) calculations. In addition, in vitro insulin mimetic activity of the complex has also been evaluated.

Keywords

Hydrazone Schiff base Vanadium(V) complex Crystal structures Electrochemistry UV-visible spectra
Patel, R., & Singh, Y. P. (2017). Di-μ-oxidovanadium(V) Complex with N’-[(Z)-Phenyl(pyridin-2-yl)methylidene]pyridine-4-carbohydrazide: Synthesis, Structural Characterization and in vitro Antidiabetic Inhibition Study. Asian Journal of Chemistry, 29(10), 2327–2332. https://doi.org/10.14233/ajchem.2017.20921
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