Synthesis and Crystal Structure of MnL3&middot;(ClO4)2(L = Diacetyl dihydrazone).

JIAN-HONG BI; Zi- Xian-Huang; MENG LI

Issue

Vol. 21 No. 8 (2009): Vol 21 Issue 8

Issue Published : June 13, 2009

Synthesis and Crystal Structure of MnL3·(ClO4)2(L = Diacetyl dihydrazone).

JIAN-HONG BI

Department of Chemistry and Chemical Engineering, Hefei Teachers College, Hefei 230061, P.R. China

Zi- Xian-Huang

Fujian Institute of Research on the Structure of Matter, Chinese Academy of Science, Fuzhou 350002, P.R. China

MENG LI

School of Chemistry and Chemical Engineering, Anhui University, Hefei 230039, P.R. China

Corresponding Author(s) : JIAN-HONG BI

bi010101@126.com

Asian Journal of Chemistry, Vol. 21 No. 8 (2009): Vol 21 Issue 8
Article Published : June 9, 2010

Abstract

A new complex MnL₃·(ClO₄)₂ (L = diacetyl dihydrazone) has been
synthesized and characterized by IR spectra, elemental analysis and
single-crystal X-ray. The crystal is trigonal, space P-3c1 with unit cell
parameters: a = 9.6546(4)Å, b = 9.6546(4)Å, c = 15.3525 (11)A, α =
90º, β = 90º, γ = 120º, V = 1239.30(11)Å³, Z = 2, Mr = 596.32, Dc =
1.598 Mg/cm³, μ = 0.811 mm^-1, F(000) = 618, T = 293(2) K, R = 0.0481,
wR = 0.1627 for 3899 reflections with I > 2σ(I).

Keywords

Manganese(II) complex Diacetyl dihydrazone Crystal structure

BI, J.-H., Xian-Huang, Z.-., & LI, M. (2010). Synthesis and Crystal Structure of MnL3·(ClO4)2(L = Diacetyl dihydrazone). Asian Journal of Chemistry, 21(8), 6613–6615. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/12376

Issue

Vol. 21 No. 8 (2009): Vol 21 Issue 8

Synthesis and Crystal Structure of MnL3·(ClO4)2(L = Diacetyl dihydrazone).

Corresponding Author(s) : JIAN-HONG BI

Abstract

Keywords

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