Synthesis and Crystal Structure of [(phen)3Co]2?Ni(SCN)6
Corresponding Author(s) : Jian-Hong Bi
bi010101@126.com
Asian Journal of Chemistry,
Vol. 21 No. 8 (2009): Vol 21 Issue 8
Abstract
A novel compound [(phen)3Co]2.Ni(SCN)6 where phen = 1,10-phenanthroline, was synthesized and characterized by IR spectra, elemental analysis and single-crystal X-ray. The crystal is monoclinic, space group P2(1)/n with unit cell parameters: a = 10.2295(19)Å, b = 19.413(4)Å, c = 18.951(4)Å, α = 90º, β = 95.157(3)º, γ = 90º, V = 3748.3 (12)Å3, Z = 2, Mr = 1722.43, Dc = 1.526 Mg/cm3, μ = 0.970 mm-1, F(000) = 1756, T = 293(2) K, R = 0.0459, wR = 0.1239 for 28699 reflections with I > 2s(I).
Keywords
Cobalt(II) compound
Crystal structure
1,10-Phenanthroline
Bi, J.-H., Bi, W.-T., Huang, Z.-X., & Hu, N.-L. (2010). Synthesis and Crystal Structure of [(phen)3Co]2?Ni(SCN)6. Asian Journal of Chemistry, 21(8), 6622–6624. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/12374
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