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Vol. 21 No. 8 (2009): Vol 21 Issue 8

Synthesis and Crystal Structure of a Tetaraazamacrocyclic Compound

Jian-Hong Bi
Department of Chemistry and Chemical Engineering, Hefei Teachers College 230061, P.R. China
Wen-Tao Bi
School of Chemistry and Chemical Engineering, Anhui University, Hefei-230039, P.R. China.
Zi-Xian Huang
Fujian Institute of Research on the Structure of Matter, Chinese Academy of Science, Fuzhou 350002, P.R. China
Nai-Liang Hu
School of Chemistry and Chemical Engineering, Anhui University, Hefei-230039, P.R. China.

Corresponding Author(s) : Jian-Hong Bi

bi010101@126.com

Asian Journal of Chemistry, Vol. 21 No. 8 (2009): Vol 21 Issue 8

Abstract

The tetaraazamacrocyclic compound of iron, {L·[Fe(CN)5NO]} (L = 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene) has been synthesized and determined by X-ray diffraction. The crystal is triclinic, space group P-1 with unit cell parameters: a = 8.167(3) Å, b = 9.345(2) Å, c = 9.702(3)A, α = 63.823(12)º, β = 73.863(14)º, γ = 73.877 (14)º, V = 627.9(3)Å3, Z = 1, Mr = 496.42, Dc = 1.313 Mg/m3, μ = 0.634 mm-1, F(000) = 262, T = 293(2) K, R = 0.0790, wR = 0.1513 for 4885 reflections with I > 2σ(I).

Keywords

Crystal structure Tetaraazamacrocyclic compound
(1)
Bi, J.-H.; Bi, W.-T.; Huang, Z.-X.; Hu, N.-L. Synthesis and Crystal Structure of a Tetaraazamacrocyclic Compound. ajc 2010, 21, 6619-6621.
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