Synthesis and Characterization of 2-{[(6-{[(2-Hydroxyphenyl)-methylidene]amino}-2- pyridyl)imino]methyl}phenol and Its Zn(II) Complex
Fahmideh Shabani
Department of Chemistry, Islamic Azad University, Ardabil Branch, Ardabil, Iran
Khayroallah Mehrani
Department of Chemistry, Faculty of Science, Imam Khomeini International University, Qazvin, Iran Fax: (98)(281)3780040; Tel: (98)(281)3780040 E-mail: shghamami@yahoo.com; shghamami@ikiu.ac.ir;
Shahriar Ghammamy
Department of Chemistry, Faculty of Science, Imam Khomeini International University, Qazvin, Iran
Mohammad. R. Rezakhani
Department of Chemistry, Faculty of Science, Imam Khomeini International University, Qazvin, Iran
Seyed Abolfazl Seyed sadjadi
Faculty of Chemistry, Industry and Science University, Tehran, Iran.
Rahmattollah Rahimi
Faculty of Chemistry, Iran University of Science and Technology, Tehran, Iran.
Sina Asili
Babasafari Student Research Center, Ardabil Branch, Ardabil, Iran.
Alireza Hematimoghadam
Department of Food Industries, Islamic Azad University, Tabriz Branch, Tabriz, Iran
2-{[(6-{[(2-Hydroxyphenyl)methylidene]amino}-2-pyridyl)imino]- methyl}phenol (HMA) were synthesized and characterized. Zn(II) metal complex of this ligand prepared by reaction of Zn(II) acetate with HMA in dry acetonitrle. Characterization of the ligand and its zinc(II) complex was made by microanalyses, FT-IR, 1H NMR, 13C NMR and UV-visible spectroscopy. In the light of these results, it was suggested that one ligand coordinate to each metal atom to form octahedral complex of Zn(II). The zinc(II) complex was characterized by elemental analysis (C, H, N), FT-IR, electronic spectra and molar conductance measurements. The elemental analysis data suggest the stoichiometry to be 1:1 [M:L] ratio formation. The molar conductance measurements reveal the presence of 1:1 electrolytic nature complex.
Shabani, F., Mehrani, K., Ghammamy, S., R. Rezakhani, M., Abolfazl Seyed sadjadi, S., Rahimi, R., … Hematimoghadam, A. (2010). Synthesis and Characterization of 2-{[(6-{[(2-Hydroxyphenyl)-methylidene]amino}-2- pyridyl)imino]methyl}phenol and Its Zn(II) Complex. Asian Journal of Chemistry, 21(8), 6587–6589. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/12366
