Voltammetric Behaviour of m-Nitroaniline in Aqueous Methanol Medium at Various Electrodes

Sangita Gupta; Renu Bala; Manish Gupta; Nidhi Jain; P.S. Verma

Issue

Vol. 21 No. 8 (2009): Vol 21 Issue 8

Issue Published : 13 June 2009

Voltammetric Behaviour of m-Nitroaniline in Aqueous Methanol Medium at Various Electrodes

Sangita Gupta

Department of Chemistry, University of Rajasthan, Jaipur-302 004, India

Renu Bala

Department of Chemistry, Government College, Kaladera-303 801, India.

Manish Gupta

RCEE, Shiksha Sankul, J.L.N.Marg, Jaipur-302 017, India

Nidhi Jain

Department of Chemistry, University of Rajasthan, Jaipur-302 004, India

P.S. Verma

Department of Chemistry, University of Rajasthan, Jaipur-302 004, India

Asian Journal of Chemistry, Vol. 21 No. 8 (2009): Vol 21 Issue 8
Article Published : 30 March 2010

Abstract

Voltammetric curves of m-nitroaniline in aqueous-methanol medium for acidic, basic and neutral ranges using B.R. Buffer for various concentrations (0.05, 0.1, 0.15, 0.2 mM) and scan rates were obtained. Constant current electrolysis of 0.02 mM m-nitroaniline in basic medium gives m-azoxyaniline (3,3'-diamino-azoxybenzene), respectively as a major product which were confirmed by TLC and IR spectra.

Keywords

m-Nitroaniline Cyclic voltammetry Constant current electrolysis SS cathode Electrochemical reduction

(1)

Gupta, S.; Bala, R.; Gupta, M.; Jain, N.; Verma, P. Voltammetric Behaviour of M-Nitroaniline in Aqueous Methanol Medium at Various Electrodes. ajc 2010, 21, 6085-6090.

Issue

Vol. 21 No. 8 (2009): Vol 21 Issue 8

Voltammetric Behaviour of m-Nitroaniline in Aqueous Methanol Medium at Various Electrodes

Abstract

Keywords

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