Copyright (c) 2017 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Synthesis, Spectral and Biological Studies of Cu(II), Ni(II), Fe(III), Co(II), Mn(II) and Cd(II) Complexes of 3-Acetyl-4-hydroxy-6-methyl-2H-pyran- 2-one Schiff Base Derived from 3-Amino-1,2,4-triazole
Corresponding Author(s) : S.D. Salunke
Asian Journal of Chemistry,
Vol. 29 No. 10 (2017): Vol 29 Issue 10
Abstract
The solid metal complexes of Cu(II), Ni(II), Fe(III), Co(II) Mn(II) and Cd(II) with novel Schiff base ligand derived from 3-acetyl-4-hydroxy-6-methyl-2H-pyran-2-one and aromatic primary amine, 3-amino-1,2,4-triazole were synthesized and characterized by elemental analysis, FTIR, UV-visible, 1H NMR and XRD spectroscopic techniques. The signals of 1H NMR spectra and important bands in IR spectra are considered and discussed in relation to molecular structure of ligand. The UV-visible absorption bands are assigned to corresponding electronic transitions, which are also studied by magnetic study. The biological (antibacterial and antifungal) activity of ligand and its metal complexes have been screened in vitro against Bacillus subtilis, Staphylococcus aureus, Aspergillus niger and Candida albicans. Schiff base ligand as well as all metal complexes have shown significant biological activities.
Keywords
Download Citation
Endnote/Zotero/Mendeley (RIS)BibTeX
- A.I. Vogel, Text Book of Practical Organic Chemistry, Longman, London, edn 5, pp. 400-401 (1989).
- W. Rahman, Z. Hassan, U. Rashid, F. Rahim, U.R.A. Obaid and M. Waseem, Med. Chem. Res., 23, 2207 (2014); https://doi.org/10.1007/s00044-013-0828-5.
- G. Reddelien, Ber., 46, 2712 (1913); https://doi.org/10.1002/cber.19130460340.
- K. Namkamoto, Infrared Spectra of Inorganic and Coordination Compounds, Wiley Interscience, New York, edn. 3 p. 159, 167 and 714 (1970).
- B.N. Faiggis, Introduction to Ligand Fields; Interscience, London (1966).
- K.M. Reddy, M.B. Halli and A.C. Hiremath, J. Indian Chem. Soc., 71, 118 (1994).
- R.N. Patel, V.L.N. Gundla and D.K. Patel, Indian J. Chem., 47A, 353 (2008).
- A.B.P. Lever, Inorganic Electronic Spectroscopy, Elsevier, Amsterdom (1968).
- P.S. Mane, S.D. Salunke, S.G. Shirodkar and T.K. Chondhekar, Asian J. Chem., 13, 1573 (2001).
- P.S. Mane, S.D. Salunke, S.G. Shirodkar and T.K. Chondhekar, J. Indian Chem. Soc., 79, 1 (2002).
- P.S. Mane, S.M. Salunke, B.S. More and Chondhekar, Asian J. Chem., 24, 2235 (2012).
- P.S. Mane, S.M. Salunke and B.S. More, E-J. Chem., 8(s1), S245 (2011); https://doi.org/10.1155/2011/763915.
- T. Roisnel and J.R. Carvajal, WinPLOTR, A Graphic Toolfor Powder Diffraction, Laboratoire Leon Brillouin (CEA/CNRS), Cedex France (2004).
- D.P. Shomaker and C.W. Garland, Experiment in Physical Chemistry, McGraw-Hill International Edition, New York, edn 5 (1989).
- A.S.Munde, V.A. Shelke, S.M. Jadhav, A.S. Kirdant, S.R. Vaidya, S.G. Shankarwar, T.K. Chondhekar, Adv. Appl. Sci. Res., 3, 178 (2012).
- D.C. Dash and A.K. Panda, J. Indian Chem. Soc., 79, 48 (2002).
- A.S. Munde, J. Korean Chem. Soc., 53, 407 (2009); https://doi.org/10.5012/jkcs.2009.53.4.407.
- S.M. Jadhav, V.A. Shelke, S.G. Shankarwar, A.S. Munde and T.K. Chondhekar, J. Saudi Chem. Soc., 18, 27 (2014); https://doi.org/10.1016/j.jscs.2011.05.010.
- S. Saini, R. Pal, A.K. Gupta and V. Beniwal, Der Pharma Chemica, 6, 330 (2014).
- S. Saini, R. Pal, A.K. Gupta and V. Beniwal, World J. Pharm. Pharm. Sci., 3, 1621 (2014).
References
A.I. Vogel, Text Book of Practical Organic Chemistry, Longman, London, edn 5, pp. 400-401 (1989).
W. Rahman, Z. Hassan, U. Rashid, F. Rahim, U.R.A. Obaid and M. Waseem, Med. Chem. Res., 23, 2207 (2014); https://doi.org/10.1007/s00044-013-0828-5.
G. Reddelien, Ber., 46, 2712 (1913); https://doi.org/10.1002/cber.19130460340.
K. Namkamoto, Infrared Spectra of Inorganic and Coordination Compounds, Wiley Interscience, New York, edn. 3 p. 159, 167 and 714 (1970).
B.N. Faiggis, Introduction to Ligand Fields; Interscience, London (1966).
K.M. Reddy, M.B. Halli and A.C. Hiremath, J. Indian Chem. Soc., 71, 118 (1994).
R.N. Patel, V.L.N. Gundla and D.K. Patel, Indian J. Chem., 47A, 353 (2008).
A.B.P. Lever, Inorganic Electronic Spectroscopy, Elsevier, Amsterdom (1968).
P.S. Mane, S.D. Salunke, S.G. Shirodkar and T.K. Chondhekar, Asian J. Chem., 13, 1573 (2001).
P.S. Mane, S.D. Salunke, S.G. Shirodkar and T.K. Chondhekar, J. Indian Chem. Soc., 79, 1 (2002).
P.S. Mane, S.M. Salunke, B.S. More and Chondhekar, Asian J. Chem., 24, 2235 (2012).
P.S. Mane, S.M. Salunke and B.S. More, E-J. Chem., 8(s1), S245 (2011); https://doi.org/10.1155/2011/763915.
T. Roisnel and J.R. Carvajal, WinPLOTR, A Graphic Toolfor Powder Diffraction, Laboratoire Leon Brillouin (CEA/CNRS), Cedex France (2004).
D.P. Shomaker and C.W. Garland, Experiment in Physical Chemistry, McGraw-Hill International Edition, New York, edn 5 (1989).
A.S.Munde, V.A. Shelke, S.M. Jadhav, A.S. Kirdant, S.R. Vaidya, S.G. Shankarwar, T.K. Chondhekar, Adv. Appl. Sci. Res., 3, 178 (2012).
D.C. Dash and A.K. Panda, J. Indian Chem. Soc., 79, 48 (2002).
A.S. Munde, J. Korean Chem. Soc., 53, 407 (2009); https://doi.org/10.5012/jkcs.2009.53.4.407.
S.M. Jadhav, V.A. Shelke, S.G. Shankarwar, A.S. Munde and T.K. Chondhekar, J. Saudi Chem. Soc., 18, 27 (2014); https://doi.org/10.1016/j.jscs.2011.05.010.
S. Saini, R. Pal, A.K. Gupta and V. Beniwal, Der Pharma Chemica, 6, 330 (2014).
S. Saini, R. Pal, A.K. Gupta and V. Beniwal, World J. Pharm. Pharm. Sci., 3, 1621 (2014).